分布式异类传感器网异步采样下的航迹起始算法

为解决分布式异类传感器网异步采样下的航迹起始问题,基于模糊集理论,定义了测量集与目标间的模糊综合贴近度。基于模糊综合贴近度提出了分布式异类传感器网航迹起始算法。该算法通过模糊综合贴近度函数全局极值点的检测实现目标的检测,用与目标相关联的测量估计目标的初始状态。算法的特点是不需要掌握目标探测概率、虚警率、杂波密度等诸多信息。仿真实验验证了算法的有效性。     

纳米尺寸Ce1-XCuXOY固溶体的表征和甲醇自热制氢反应的研究

采用溶胶-凝胶法制备了Ce1-XCuXOY 固溶体催化剂,通过XRD, BET, TEM等表征研究了该类催化剂的结构特征,并采用H2-TPR技术考察了其氧化还原行为. 结果表明固溶体的生成使该类催化剂活化和转移氧的能力大大提高. 该类催化剂在甲醇自热制氢反应中表现了较高的催化活性.     

Low molecular weight protein tyrosine phosphatases: small,but smart

Low molecular weight protein tyrosine phosphatases (LMW-PTPs) are a family of 18-kDa enzymes involved in cell growth regulation. Despite very limited sequence similarity to the PTP superfamily, they display a conserved signature motif in the catalytic site. LMW-PTP associates and dephosphorylate many growth factor receptors, such as platelet-derived growth factor receptor (PDGF-r), insulin receptor and ephrin receptor, thus downregulating many of the tyrosine kinase receptor functions that lead to cell division. In particular, LMW-PTP acts on both growth-factor-induced mitosis, through dephosphorylation of activated PDGF-r, and on cytoskeleton rearrangement, through dephosphorylation of p190RhoGAP and the consequent regulation of the small GTPase Rho. LMW-PTP activity is modulated by tyrosine phosphorylation on two specific residues, each of them with specific characteristics. LMW-PTP activity on specific substrates depends also on its localization. Moreover, LMW-PTP is reversibly oxidized during growth factor signaling, leading to inhibition of its enzymatic activity. Recovery of phosphatase activity depends on the availability of reduced glutathione and involves the formation of an S–S bridge between the two catalytic site cysteines. Furthermore, studies on the redox state of LMW-PTP in contact-inhibited cells and in mature myoblasts suggest that LMW-PTP is a general and versatile modulator of growth inhibition. Received 17 January 2002; received after revision 22 March 2002; accepted 26 March 2002     

电爆炸箔起爆系统初始电感的计算模型

回路电感作为电爆炸箔起爆系统（exploding foil initiation system简称EFIS）的重要参数,掌握其规律是将系统进一步上型化的基础,给出了电爆炸箔起爆回路的简化模型,提出了简化推导的3个假设条件,利用拉氏变换推导并验证了利用放电电流曲线确定电爆炸箔起爆系统初始电感的测算公式,利用Quantic的实验曲线验算了该公式结果表明测算公式是准确的,为EFIS进一步小型化提供了设计工具。     

K2S2O8/NaHSO3引发MMA在羟丙基甲基纤维素上的接枝聚合

采用K2S2O8/NaHSO3引发甲基丙烯酸甲酯（MMA）在羟丙基甲基纤维素（HPMC）上接枝聚合,考察了反应条件,如引发剂浓度、温度、反应时间等对接枝率和接枝效率的影响。     

An explanation to the high efficiency ofm-THPC (temporfin) used in photodynamic therapy

Meso-tetrahydroxylphenyl chlorin (m-THPC) is one of the most efficient prospective sensitizers used in photodynamic therapy (PDT). ESR spectroscopy, fluorescence quenching experiments and cyclic voltammogram measurement were used to study its redox properties. The results showed that the ability of m-THPC generating superoxide radical anions was very strong, and the rate constant of m-THPC fluorescence quenching by oxygen k_q (O₂)=1.46×10¹⁰ mol^-1·s^-1. The values of fluorescence quen- ching rate constant of m-THPC by some other electron acceptors, such as methyl viologen (MV²⁺) and anthraquinone (An), were also measured. And they were k_q (MV²⁺)=5.51×10⁹ mol^-1·s^-1, k_q (An)=7.81×10⁹ mol^-1·s^-1. The oxidation potential of m-THPC was examined to be +0.62 V (vs. NHE) in acetonitrile. All these suggested that m-THPC should be a much stronger electron donor than photofrin, the currently used in clinical photodrug, and may react easily through electron transfer with biological matter to yield various radicals. So it seemed reasonable that the type Ⅰ reaction may play an important role in the high activity of m-THPC-PDT.     

自由基聚合氧化还原引发体系的分解速率常数

探讨了过硫酸盐与亚硫酸盐组成的氧化还原引发体系在水溶性单体丙烯酰胺溶液聚合中的引发作用,观察到在相同聚合条件下不同摩尔比时,聚合反应速率有明显差异。实验结果表明:氧化还原引发体系中氧化剂与还原剂的摩尔比对分解速率常数值有明显影响,从而影响聚合速率,在30℃下当SO₃^2-与S₂O₈^2-摩尔比为6.7∶10时,分解速率常数和聚合速率达到最大。从引发速率及分解速率常数方面进行了理论分析,找出了其分解速率常数的变化规律,给出了分解速率常数值的范围,并认为氧化还原引发体系的分解速率常数随其摩尔比的变化而变化,是催化因素的影响。     

基于人工降雨的天津盘龙谷泥石流起动特征

通过泥石流物理模型试验研究了盘龙谷泥石流的起动特征,探讨了其起动方式、物源补给来源以及降雨条件的影响等.实验结果表明,泥石流起动时形成区堆积物源不会整体滑移,而是在其表面形成冲沟并逐渐扩大直至引发泥石流;前期先降小雨使土体达到完全饱和,然后再降中雨或大雨的情形其危险性最高;冲沟两侧的不稳定岩土体构成泥石流物源的主要补给来源.实验现象与盘龙谷泥石流具有较高的一致性,可以为建立泥石流预警系统及防灾减灾提供一定的参考依据.