不同形核机制下对动态再结晶过程模拟研究

为了研究形核机制对多晶金属材料热加工过程的影响,通过建立动态再结晶的二维元胞自动机模型,模拟了3种形核机制下动态再结晶组织的演化过程,得到了热加工过程中再结晶平均晶粒尺寸的变化规律及生长动力学特征.模拟结果表明,再结晶平均晶粒尺寸的变化规律由形核机制和生长方式共同决定,但稳态时的平均晶粒尺寸只与总的形核数目有关;生长动力学曲线均呈S形,其变化规律符合JMAK理论;Avrami指数的大小取决于晶核的空间分布.     

冷轧低合金高强钢再结晶和析出行为研究

利用热模拟试验机研究了冷轧低合金高强钢的再结晶动力学规律,并基于JMAK方程建立了再结晶动力学模型,为退火过程中铁素体再结晶和析出行为的控制提供了理论依据.结果表明,随退火温度升高,铁素体达到完全再结晶时所用时间大大缩短;冷轧压下量相同时,初始贝氏体组织具有更高的位错密度和储存能;80℃/s快速加热条件下,回复和再结晶过程相应同步提前,且再结晶发生前的剩余变形储能增大,从而使铁素体再结晶快速完成.同时新工艺下实验钢析出粒子尺寸更均匀,体积分数更高,析出强化贡献更明显.     

等温自由锻温度对7085铝合金组织与性能的影响

通过金相组织观察、扫描电镜分析和室温拉伸力学性能及剥落腐蚀实验,分析探讨等温自由锻温度对7085铝合金显微组织、力学性能和剥落腐蚀的影响.研究结果表明:在370℃和400℃等温自由锻时,合金发生严重再结晶,强度较低,伸长率稍高,剥蚀抗力较差;在420℃锻造时,合金出现大量细小且分布均匀的亚晶粒,抗拉强度、屈服强度、伸长率和剥蚀抗力均较好,分别达到533.2 MPa,495 MPa,13.3％和EA.在450℃锻造时,该合金的晶粒开始长大,强度下降,伸长率稍有升高,剥蚀抗力较差.综合考虑显微组织、强度、塑性和剥落腐蚀等因素,确定420℃为合金等温自由锻最佳锻造温度.     

重结晶法制备球形化RDX

为解决以RDX为基的熔铸炸药固态含量低的问题,采用环己酮作为溶剂重结晶的方法,得到了球形化RDX晶体.分析了重结晶工艺条件中结晶温度、搅拌速率、杂质等参数变化对于RDX晶体形状的影响,制备了球形化RDX晶体.测试了球形化RDX的晶体形状、流散性、机械感度和以其为组分的PBX冲击波感度.结果表明,采用环己酮重结晶法制备的球形化RDX晶体形状规则、表面光滑、棱角少、流散性好,撞击感度、摩擦感度比普通RDX略有降低,以球形化RDX为基的PBX相比以普通RDX为基的PBX冲击波感度降低约25%.     

变形温度对动态再结晶行为的影响

用改进的元胞自动机(cellular automata,CA)模型及其参数辨识方法研究变形温度对动态再结晶(dynamic recrystallization,DRX)行为的影响.模型中,以位错密度内变量描述加工硬化、动态回复以及动态再结晶形核和长大等一系列微观组织的演化过程,变形温度通过改变位错密度的累积速率影响DRX形核与长大,形核率与晶粒长大速度都是位错密度的函数,反映了变形储能对DRX行为尤其是形核行为的影响.模拟结果与实验结果吻合良好,表明在不同的变形温度下,改进的CA模型及其参数辨识方法是有效的.     

特厚板温度梯度轧制有限元模拟与实验研究

针对特厚板再结晶型轧制,板坯中心难以变形导致心部晶粒粗大的问题,使用Q345B钢,采用有限元方法建立了特厚板轧制的仿真模型,以研究在特厚板轧制过程中引入厚度方向上的温度梯度对钢板心部应变的影响,并与传统均温轧制进行对比,预测了两种温度场条件下奥氏体再结晶的晶粒尺寸.采用大试样平面应变实验对模拟结果进行验证.研究结果表明,温度梯度轧制有利于增加坯料心部应变量,最大增加了61.35%.计算和实验结果显示温度梯度轧制可以减小特厚板心部晶粒尺寸,晶粒度级别提高了一个等级,说明该工艺对提高特厚板中心区域性能有利.     

超临界二氧化碳GAS重结晶制备HMX微细颗粒的研究

比较了ＣＯ２对丙酮，环己酮，二甲基亚砜体积膨胀的影响和ＨＭＸ在上述三种溶剂中ＧＡＳ重结晶时的析晶率。以丙酮为溶剂用ＣＯ２ＧＡＳ重结晶，在一定的条件下可获得２－１３μｇβ－型ＨＭＸ微细颗粒。     

Effect of dislocation configuration on non-equilibrium boron segregation during cooling

Different densities and configurations of crystal defects were obtained in an austenitic Fe-30%Ni alloy and an ultra low carbon bainitic (ULCB) alloy by undergoing different deformations and annealing treatments at high temperatures. Boron segregation on grain boundaries and subgrain boundaries during air-cooling were revealed by means of the particle tracking autoradiography technique. It is found that non-equilibrium segregation is resisted indeformed grains after recovery and polygonization, boron-depleted zones seem to be quite clear inrecrystallized grains than those in deformed original grains during cooling. Subgrain boundaries andpolygonized dislocation cells have a significant effect on non-equilibrium boron segregation duringthe air-cooling. The results implicates that dislocation configuration is a more important factor affecting boron segregation at grain boundaries rather that the density of defects itself in thegrain.     

镁合金AZ31动态再结晶行为的取向成像分析

利用背散射电子衍射(EBSD)取向成像技术分析了具有不同初始织构的镁合金AZ31动态再结晶晶粒的取向特征以及与相邻的形变晶粒的取向关系.结果表明:不同初始织构以及不同应变量下动态再结晶新晶粒与形变晶粒的取向都相近,说明动态再结晶以连续方式进行,即亚晶转动方式.随形变量的增加,不同初始织构试样的晶粒都转向基面取向,但菊池带衬度图像显示大的形变晶粒内部很少有亚晶界存在并且菊池带质量高,说明塑性滑移机制仍在起很大作用但在靠近晶界处发生,形变晶粒是通过平行于压缩面方向剪切晶界而逐渐消失的.动态再结晶晶粒与相邻形变晶粒的取向差表明不同初始织构造成不同的取向差,但总的趋势是相同的.     

Further mechanism of α/β interphase boundary evolution and dynamic globularization of Ti–5Al–2Sn–2Zr–4Mo–4Cr at elevated temperature deformation

The evolution characterization of the α/β interphase boundaries of the isothermally compressed Ti–5Al–2Sn–2Zr–4Mo–4Cr with lamellar microstructure was carried out via electron backscatter diffraction (EBSD) and transmission electron microscope (TEM). The effect of the α/β interphase boundary evolution on the dynamic globularization was discussed, and the nucleation model for the β recrystallized grain at the cusp of α lath in the late stage of deformation in terms of the classic nucleation theory was established. The mean α/β interface deviation angle from Burgers orientation relationship (BOR) increased continuously up to 18.9° with the increasing strain from 0.1 to 0.5, which was dominated by the continuous dynamic recrystallization. Restoration of BOR between α and β phases at the strains of 0.7 and 0.9 occurred due to the occurrence of recrystallized α and β grains following BOR, which was rationalized by a nucleation model considering the stored energy of deformation provided the driving force for nucleation at the cusp of α lath. Loss of coherency of α/β interphase boundaries at a strain about 0.3 was responsible for accelerating the dynamic globularization of α lamellae since the energy of α/β interphase boundaries increased up to the maximum value when the non-coherent α/β interphase boundaries were formed. Restoration of coherency of α/β interphase boundaries due to the recrystallization nucleation in the late stage of deformation did not substantially affect the dynamic globularization since the α/α intraphase high-angle boundaries (HAGBs) were formed and the most α/β interphase boundaries were non-coherent.