微量添加元素对Al-Zn-Mg合金临界温度的影响(电镜法)

本文利用电镜观察Cu、Mn、Zr和Cr等微量添加元素对快速淬火和直接淬火的Al-Zn-Mg合金临界温度(T'_c、T_c)的影响。结果表明,单独加入一种微量元素,以Cu和Cr对Al-5.08(wt)％Zn-1.75(wt)％Mg合金的丁'_c和T_c的提高影响最大,Mn次之,Zr无影响.     

Comparison of summer thermohaline field and circulation structure of the Bohai Sea between 1958 and 2000

TheBohaiSea(37°07′—41°N,117°35′—121°10′E)isashallowsemi-enclosedsea.SincetheBohaiSeaistheonlyinnerseaofChinaandalsoanimportantstra-tegicsea,itisoneofthemostinvestigatedseasinChina.Alargenumberofstudiesonthetideandthetidalcurrentaswellasnumericalsimulationofcirculationhavebeencarriedout,enhancingourunderstandingoftheBohaiSea.Long-termvariationsoftheseasurfacesalinity(SSS)andseasurfacetemperature(SST)oftheBohaiSeawereanalyzed.Linetal.[1]foundthatthepositivetrendsoftheannualmeanS…     

Synthesis and crystal structure of the trimetallic erbium tetrahydride complex [Li(THF)4][{(ButCp)2Er(μ-H)} 3-(μ3-H)]

Reaction of [(Bu′tCp)2Er(μ-CI)]2 with Bu′Li in 1:1 molar ratio in THF at -78℃, after work-up, afforded the trimetallic erbium tetrahydride complex [Li(THF)4][{(Bu′Cp)2Er(μ-H)}3(μ3-H)] (1) by β-hydrogen elimination reaction. Crystal structure determination reveals that complex 1 has discrete ion pair structure. The anion is composed of three (Bu′Cp)2Er units to form a triangle array connected by three bridged hydrogen atoms, and the fourth hydrogen atom coordinated to three Er^3 ions. The coordination num-ber for each Er^3 ion is 9.     

具有表面活性含氟丙烯酸酯的制备

利用氟碳表面活性剂FSO与丙烯酰氯反应制备了FSO丙烯酸酯,用气相色谱法分析了FSO丙烯酸酯的纯度,用IR光谱对其结构进行了初步表征。考察了物料配比和反应时间对FSO丙烯酸酯收率和纯度的影响。结果表明,在丙烯酰氯过量比为1.05和反应时间为8～10h时,FSO丙烯酸酯的收率和纯度最高。     

广告的效果构成与广告创意及其实施与控制

广告效果由广告的刺激强度、广告价值笼络力和广告购买决策驱动力三个层面构成,沿着这三个方向进行广告创意并进行有效的实施与控制,是保证广告效果的必然途径。其中,把握好广告背景和心理“差补效应”对实现广告创意及其实施与控制的有效性尤为重要。     

一个非线性电路模型的混沌态特性分析

对非线性系统进行分析时,可能出现测量结果为混沌态,以一个非线性电路模型为例。分析混沌态的几率密度并提出“赝温度”的新概念,以表征混沌态的赝随机变化的剧烈程度。从而为非线性系统的混沌态进行“乱中有序”的定量描述提供了一种新方法。     

热轧机轴承系统的热平衡分析

以热连轧机轴承系统的热变形故障作为研究对象,详细分析了轴承系统的内热源和轴承摩擦力矩的两种计算方法,最后采用PALMGREN公式计算了不同转速下的轴承温升.     

一种稠油热采节能方法的理论分析与实践

为提高稠油采集电加热效率,该文着重分析稠油井的垂直温度分布模型和特种加热电缆的电路模型.结合这两种模型和现场数据,提出并证明了提高电源频率可以显著提高电加热效率.在理论分析基础上研制出用于稠油采集的高效电加热设备,在辽河油田实施工业应用.现场测试数据与理论分析相吻合.多次测试证明与现有同类产品相比,该设备取得了相当可观的节能效果.     

Thermodynamic characterization of two novel spin-crossover complexes

Spin-crossover complexes are of great interest to the scientists because of their potential application in molecular-based electronic devices. Some octahedral metal compounds with 3dn (4 ≤ n ≤ 7) configuration can induce a spin state conversion through a fine tuning condition (temperature, pressure, light irradiation, etc.). If the conversion occurs reversibly with a hystersis loop and color change, it will make the system possessing memory effect. The memory effect can be magnified and the …     

Heterogeneous reactions on the surface of fine particles in the atmosphere

Fine particles play an important role in the atmosphere. Research on heterogeneous reactions on the surface of fine particles is one of the frontier areas of atmospheric science. In this paper, physical and chemical characteristics of fine particles in the atmosphere and the interactions between trace gases and fine particles are described, methods used in heterogeneous reactions research are discussed in detail, progress in the study of heterogeneous reactions on the surface of fine particles in the atmosphere is summarized, existing important questions are pointed out and future research directions are suggested.