脆性颗粒材料的超弹性软化模型及应变局部化模拟

在Volokh软化模型的基础上,考虑颗粒材料的变形和破坏机制,认为颗粒材料以剪切变形和破坏为主,提出了表示软化程度的软化因子概念,发展了两种能够部分表征颗粒材料力学行为特征的软化模式,并基于ABAQUS用户材料子程序(UMAT)开发相应程序.数值算例考察了上述模型模拟颗粒材料应变局部化现象和软化现象的能力.结果表明了所建议模型的有效性和可行性.     

Sonochemical synthesis of nanostructured nickel hydroxide as an electrode material for improved electrochemical energy storage application

A facile and fast approach for the synthesis of a nanostructured nickel hydroxide(Ni(OH)_2) via sonochemical technique is reported in the present study. The X-ray diffraction results confirmed that the synthesized Ni(OH)_2 was oriented in β-phase of hexagonal brucite structure. The nanostructured Ni(OH)_2 electrode exhibited the maximum specific capacitance of 1256 F/g at a current density of 200 mA/g in 1 M KOH_((aq)). Ni(OH)_2 electrodes exhibited the pseudocapacitive behavior due to the presence of redox reaction. It also exhibited long-term cyclic stability of 85% after 2000 cycles, suggesting that the nanostructured Ni(OH)_2 electrode will play a promising role for high performance supercapacitor application.     

Detecting MoS2 and MoSe2 with optical contrast simulation

Optical imaging is a promising method to identify and locate 2D materials efficiently and non-invasively. By putting a 2D material on a substrate, the nanolayer will add to an optical path and create a contrast to the case when the nanolayer is absent. This optical contrast imaging can be used to identify the 2D material and its number of layers. To make the optical imaging process in the laboratories an effective tool, Fresnel Law as a model was used to simulate the optical imaging results of 2D materials(graphene, Mo S2 and MoSe_2) on top of different thickness of SiO_2 and Si wafer in the present investigation. The results provide the details of the optimal conditions(optimal light wavelength and optimal SiO_2 thickness) to identify and locate single to few 2D nanolayers, which can be used directly in laboratories. The optical contrasts of 1–5 layers of molybdenum disulfide(MoS_2) and molybdenum diselenide(MoSe_2) were simulated. To the best of our knowledge, it is the first time that the optical contrast results of MoSe_2 have been reported. In particular, this work highlights the sensitivity of the model on the accuracy of the refractive indices used. It is demonstrated that through computational modeling that optical contrast can allow effective determination of number of layers in few layer 2D materials.     

药用植物白芨块茎挥发油组分的GC-MS分析及成分鉴定

通过分析道地药材白芨块茎中挥发油的化学成分,为进一步揭示其药理作用提供科学依据。采用二氯甲烷为萃取剂提取白芨块茎中的挥发油,利用气相色谱-质谱联用技术(GC-MS)鉴定分析白芨块茎中挥发油的化学成分。结果显示从白芨块茎中共鉴定到 34种主要化学成分,相对含量较高的组分有3-甲基丁醛、乙酸、3-甲基-1-丁醇、4-氨基-3-甲基苯酚和乙偶姻等。该研究将为后续进一步开发利用白芨的食疗保健功效提供了理论参考。     

分子非线性光学性质的量子化学研究

非线性光学是研究介质在强光作用下产生的非线性光学现象及其应用.以有机非线性光学材料苯并噻唑衍生物和花青苷衍生物共6个分子为代表,根据密度泛函理论优化其分子结构,从而得到它们稳定的分子构型,通过分析键长键角、共轭链长度、轨道图像、跃迁能振子其强度以及二阶非线性光学系数Btol值等数据,得出Btol正比于跃迁偶极距,反比于跃迁能,所以增加的跃迁偶极距和红移的光谱吸收峰会导致Btol增大.     

浅谈写作素材的采撷——谈选材

其实写作的素材是发掘不完的,面对“新颖”这个要求,无数同学陷入寻找素材的误区.以为素材的 “新颖”便是别人没有见过的,没写过的.其实,素材“新颖”与否,并不在于是新是旧.关键是要选择一个什么样的角度利用素材、用好素材.     

面向智慧驾驶的道路基础设施功能设计

随着单车智能成本提高以及道路环境复杂性加大，智慧驾驶车辆的发展越来越依靠智慧道路基础设施的进步。目前国内外不同的道路工程建设项目对道路基础设施的智慧化均提出了各具特色的设计思路和功能模块，但是相关研究主要集中在单一的道路功能或特定技术上，尚未系统性地给出智慧道路基础设施的设计理论和应用体系。同时，智慧道路基础设施建设要求路旁设备、路面材料和外部感知设备等全方位朝着信息化、数字化和智能化方向发展。本研究在系统综述国内外智慧公路项目典型案例的基础上，提出了未来智慧道路设施的四大关键技术。     

材料类专业网络实验教学研究与实践

为了建立开放式实验教学体系,提高实验资源利用率及实验教学效果,培养学生创新精神和实践能力,文中针对材料类专业实验教学的特点及传统实验教学模式存在的不足,结合具体课程,提出网络实验教学模式下实验教学的实施方法及效果,并对网络实验教学的实施提出建设性的意见。     

车用材料有害物质管控策略研究

在源头加强车用材料有害物质管控,是促进汽车行业健康持续发展的重要途径。介绍了车用材料有害物质的主要危害、来源及替代趋势,分析了欧盟和中国有关车用材料有害物质标准法规的状况,给出了我国汽车企业管控策略,旨在提升法规应对能力和促进汽车工业优化升级。     

MgFeSiO_4 prepared via a molten salt method as a new cathode material for rechargeable magnesium batteries

Well-crystallized MgFeSiO4 microparticles were synthesized at different temperatures by a simple molten salt method using KCl flux. As a new cathode for rechargeable magnesium batteries,the material shows a reversible Mg2+ intercalation-deintercalation process. In 0.25 mol/L Mg(AlCl2EtBu) 2/THF electrolyte,MgFeSiO4 synthesized at 900°C can deliver a 125.1 mAh/g initial dis-charge capacity and a 91.4% capacity retention on the 20th cycle at a rate of 0.1C(about 15.6 mA/g) . The results show that MgFeSiO4 cou...