浅谈七年级生物教学中的理化知识分布与处理

分析初一生物教材(苏教版)中的理化知识分布特点,目的在于运用恰当的处理方法,使生物教学做到“对症下药”,提高教学效果。     

Inorganic chemical composition and source signature of PM2.5 in Beijing during ACE-Asia period

Aerosol samples for PM2.5 were collected in Beijing for 38 consecutive days from March to April 2001 using an IMPROVE Sampler. Concentrations of 20 elements in PM2.5 were determined using a PIXE method. Results show that the average mineral dust concentration of PM2.5 was 14.6 Ilg/m3 during the observation period. On the sand-dust event days of March 21 and April 10, dust PM2.5 mass concentrations were 62.4 and 54.1 μg/m^3, respectively.These demonstrate that fine particle pollution by dust event in Beijing was very severe. The enrichment factors of S and Cu reached minimums on the dusty days and were high on the non-dusty days. It is considered that enrichment factors of elements in PM2.5, which are associated with human activities, can probably provide an effective method to distinguish local sources from external sources of dust. Factor analysis on the chemical composition in PM2.5 shows that sources of crustal matters, anthropogenic emission, and oil combustion contributed to PM2.5 levels in air in the springtime of 2001 in Beijing.     

新型Cu(II)双核配合物的合成、结构表征和量化计算

以二(2-苯并咪唑亚甲基)胺(N3)为配体,合成了一种新型Cu(II)双核配合物作为超氧化物歧化酶(SOD)的模型化合物.采用元素分析、UV和IR光谱进行了表征,应用X射线衍射方法测定了晶体结构,并利用G98W程序在HF/LANL2DZ基组水平上对该双核配合物进行了量子化学计算.晶体结构分析表明,Cu(II)双核配合物的化学式量分子(C42H40N12O17Cl4Cu2)是以4,4′-联吡啶为桥的Cu(II)双核配合物单元,Cu(II)与配位原子形成变形八面体构型,轴向配位氧原子来源于高氯酸根.量化计算所得原子轨道贡献和原子净电荷布居分析结果与晶体结构中的配位情况相符.     

Structural and Chemical Diversity of TI-Based Cuprate Superconductors

The first TI一based euprate supereonduetor,TI一Ba-Cu一(),was diseovered by 2.2.Sheng and A.M.Hermann仁1〕. TI beeomes supereondueting at 2.38 K.NumerousTI eompounds and alloys are supereondueting.TIMo6Ses has the highest transition temperature of1 2.2 K among all non一euprate Tl eontaining alloyand eompound supereonduetors.Before thediseovery of the euprate supereonduetors,some TIeontaining oxide supereonduetors were found,among whieh TI。.3W()3 has the highest transitiontemPerature,2.14 K. Sinee the diseovery of TI euPratesuPereonduetors,two distinet families have beenidentified.Soon after the diseovery of TI一Ba一Cu-(),supereonduetivity was eonfirmed in TI一Ba一Ca-Cu一()samples.The ehemieal eompositions anderystal struetures of those eompounds were workedout as T12BaZCu()6,T12BaZCaCuZ()。,andT12BaZCaZCu3OI。[2〕.This 15 the first family of TIeuPrate supereonduetors,whieh features two TIatoms in eaeh ehemieal formula.     

H6M4(N2H2)3(M=Al,Ga)簇合物的结构、红外光谱和热力学性质研究

采用自洽场方法(HF)和密度泛函(DFT)的B3LYP方法，在6-31G^*水平下，研究了H6M4(N2H2)3(a—M＝Al，b—M＝Ga)簇合物的几何构型、电子结构、红外光谱及热力学性质．结果表明：N—N键比肼中N—N键长，有进一步裂解的趋势．振动频率计算表明：铝、镓的肼簇合物为基态稳定结构．     

大学预科化学课程教学探讨

本针对大学预科班学生的特点，从大学预科化学课程的基本目的和要求出发，讨论大学预科化学课程教学中应注意的问题．     

Oxidative Treatment of Some Reactive Dyes by Fenton Reagent

Nine kinds of reactive dye solutions: Reactive K-2RL, H-E2R, X-6B1Y, HE-4G, X-3B, K-2R,H-E7B, X-4RN and S-F3B were treated by usingFenton reagent. While the concentration of dye is 400mg/L, the FeSO_4 dosage 100-180 mg/L, H_2O_2 240～540 mg/L, that is the stoichiometric numbers of Fe~(2+)and H_2O_2. are between 1: 9～1: 12, pH=3, reaction     

Time-division phase modulated single-photon interference in a Sagnac interferometer

We introduce a stable, long-distance singlephoton Sagnac interferometer, which has a balanced configuration to efficiently compensate phase drift caused by change of the fiber-optic path. By using time-division phase modulation, single-photon interference was realized at 1550nm in a 5-km-long as well as 27-km-long Sagnac fiber loops,with a fringe visibility higher than 90% and long-term stability. The stable performance of the single-photon interference indicated that the time-division phase-modulated Sagnac interferometer might readily lead to practical applications in single-photon routing and quantum cryptography.     

两多模相干态的叠加态光场的等幂N次Y压缩

根据量子力学态叠加原理,构造了由多模复共轭相干态|{zj(a)}>q和多模复共轭相干态的相反态等幂次|{-zj(b)}>q的线性叠加所组成的振幅不等的非对称两态叠加多模叠加态光场|Ψn(2)>q(j=1,2,3,…,q),利用多模压缩态理论研究了态|Ψn(2)>q的等幂次N次方Y压缩特性。结果表明:在各模的平均光子数不相等而对应模的初始相位相等亦即Rj(a)≠Rj(b)且ψj(a)=ψj(b)=ψj的条件下,如果各模的初始相位ψj和态间的初始相位差θpq(R)-θnq(R)=△θ满足一定取值关系,则无论压缩次数N为奇数还是偶数,态|Ψn(2)>q的两个正交相位分量均可分别呈现周期性变化的等幂次N次方Y压缩效应,但N是奇数时的压缩深度大于N是偶数时的压缩深度。     

微孔草种子化学成分的研究

从微孔草 (MicroulasikkimenisHemsl)种子中首次分离出 8个已知化合物 :β 谷甾醇 (1)、羽扇豆醇 (2 )、白桦脂醇 (3 )、豆甾 4 烯 3 酮 (4)、豆甾 4 烯 3 二酮 (5 )、羟基豆甾 4 烯 3酮 (6)、诺米林 (7)、如忒文 (8) .报道了这8个化合物的分离纯化和结构鉴定