Preparation and characterization of doubly substituted microwave absorbing material by sol-gel technique for super high frequency applications

Rare earth Dy~(3+)and divalent Mn~(2+)elements substituting W-type hexagonal ferrites Ba_(1-x)Dy_xZn_2Fe_(16-y)Mn_yO_(27)(x=0,0.02,0.06,0.1 and y=0,0.1,0.3,0.5)were prepared by sol-gel method.The thermo-gravimetric analysis(TGA)and differential scanning calorimetry(DSC)was carried out to find the temperature at which single phase can be obtained.XRD patterns indicate the presence of the single phase for all the synthesized samples with the absence of any extra peak due to unreacted material and secondary phases.The occurrence of absorption bands at low wave numbers(563 and 446 cm~(-1)),can be assigned to the stretching vibration of metal and oxygen ions in FTIR spectra,which also confirms the single hexagonal phase for prepared material.The grains are of platelet like structure,which enhances the microwave absorption properties of hexagonal ferrites.The synthesized material exhibits the minimum reflection loss of-20.9 dB at 11.8 GHz frequency,which reflects the applications of this material in super high frequency devices.The microwave conductivity of the material increases with frequency.     

新疆富蕴县阿克塔斯金矿找矿靶区主要特征及找矿远景

阿克塔斯找矿靶区位于重要的额尔齐斯Cu-Ni-Mo-Au-Fe成矿带中。区域内主要分布有斜长花岗岩、二长岩,石炭统南明水组为区域上主要的赋矿地层。靶区内的铜金矿化主要分布在斜长花岗斑岩与千枚岩的接触带中。工作成果显示该找矿靶区存在明显的物探激电和磁法异常,物探异常区与化探异常位置套合较好,地表槽探与钻孔中见有明显金铜矿化。综合分析物探化探异常及矿化特征,认为该靶区斜长花岗岩脉是本区金铜矿化的成矿母岩,属于岩浆热液型金矿床,找矿远景较好。     

关于副对称矩阵和副反对称矩阵的讨论

在高等代数中矩阵是研究问题很重要的工具,在讨论矩阵的转置运算时给出了对称矩阵和反对称矩阵的定义及性质。现在我们通过定义矩阵的倒转置运算给出副对称矩阵和副反对称矩阵的定义,然后研究它们的性质,最后研究它们与对称矩阵、反对称矩阵之间的关系。     

斜拉网壳结构的动力特性研究

分析了斜拉网壳这种典型杂交空间结构的自振特性。通过改变网壳厚度、跨度、塔柱刚度和斜拉索刚度等参数,全面探讨了该结构的动力特性,得到一些有规律的结论,可为相关工程设计提供参考。     

外推长度对铁电存储材料BaTiO_3薄膜极化分布的影响

基于朗道-德文希尔（Landau-Devonshire）平均场热力学理论,计算并阐述了在非对称的边界条件下外延生长的铁电存储材料BaTiO3薄膜的极化特性,特别研究了外推长度在薄膜由顺电相到铁电相的相变中所表现出来的重要作用,得出铁电薄膜的极化特性及其分布强烈地依赖于外推长度的取值,揭示了外推长度在铁电薄膜的铁电相变中的物理本质.     

Si基片各向异性腐蚀特性研究

为了制备高性能铁电薄膜红外探测器 ,对Si微桥的湿化学腐蚀工艺进行了研究 .利用Si基片各向异性腐蚀特性 ,在四甲基氢氧化铵 (简称TMAH )水溶液中加入氢氧化钾 (KOH)作为各向异性腐蚀液 (简称KTMAH) ,研究了TMAH与KOH摩尔比、腐蚀浓度、腐蚀温度对Si基片腐蚀特性的影响 .结果表明 :Si(1 0 0 )面的腐蚀速度随着腐蚀液浓度和温度的升高而增大 ,随着TMAH与KOH摩尔比的降低 ,KTMAH腐蚀液对掩膜层的腐蚀程度加剧 .选用 5 g/L的过硫酸盐 (PDS)与TMAH质量分数为 2 5 %、TMAH与KOH摩尔比为2的KTMAH混合液作为腐蚀液 ,并在 80℃× 2 .5h的腐蚀条件下能得到平整的腐蚀面 ,可以制备质量较好的微桥结构     

粉末微注射成形Catamold~ 316L喂料流变性能研究

采用Rosand RH7双柱塞高压毛细管流变仪对BASF Catamold316L奥氏体不锈钢喂料进行流变性能研究.讨论了在口模直径为1mm,长径比为16,Bagley校正条件下不同剪切速率、温度对喂料粘度、非牛顿指数、粘流活化能的影响,同时从理论上分析了粉末装载量及粘结剂选取对喂料流变性能的影响,并且对喂料的流变性能进行综合评价.实验结果表明,Catamold316L喂料呈现假塑性流体特征,200℃时非牛顿指数和粘流活化能最小,可塑性指数最大,更加适合注射成形;随着温度的升高、剪切速率的增大,粘度均逐渐降低,粘度对剪切速率具有很高的敏感性;在相同的剪切速率下,随着温度的升高,喂料综合评价指标呈现先增大后减小的趋势.     

Thermal stability and magnetic properties of Fe–Co–M–Zr–Nb–Ge–B(M=Mo,Cr) bulk metallic glasses

Fe62Co8 xMxZr6Nb4Ge1B19(M=Mo, Cr) bulk metallic glasses were synthesized in the diameter range up to 2 mm by copper mold casting,which exhibit high thermal stability and large glass-forming ability. The super-cooled liquid region diminishes by the dissolution of Mo. The addition of 2 at% Cr leads to the broading of the liquid region remarkably, resulting in the improvement of thermal stability. The crystallization takes place through a single exothermic reaction, accompanying the precipitation of more than three kinds of crystallized phases such as α-Fe,Fe2Zr and ZrB2. The Fe-based alloys show soft ferromagnetic properties. The saturation magnetization(ss) decreases with increasing Mo or Cr content while the saturated magnetostriction increases with raising Mo or Cr content. There is no evident change in the ssand coercive force(Hc)with annealing temperature below the crystallization temperature, which suggests a more relaxed atomic configuration the glasses have. The crystallization causes a substantial enhancement in both ssand Hc. Each soft magnetic property of the glasses containing Cr with higher thermal stability is superior to that of the alloys containing Mo.     

新铁电陶瓷材料PZT热物理性能和相变的研究

采用日本制造的闪光法TLP－18型仪器和线差法的TMA－30型仪器分别测试了PZT（51／49）铁电陶瓷的导温系数和热膨胀系数,并研究了温度,相变,极化处理和晶轴对其物理性能的影响,结果表明,在相变发生时,热物理性能产生了突变;导温系数随着温度而增大,而热膨胀系数却随着温度升高而减小,这为铁电陶瓷材料的相变研究提供了重要的理论依据。     

山东金城地区焦家断裂带下盘隐伏花岗岩类岩石地球化学特征及锆石U-Pb年龄

胶西北金矿集区内中生代花岗岩类分布广泛,与区内金矿成矿关系密切。焦家断裂带深部下盘隐伏的岩体岩性以花岗岩类为主,其成岩时间及成因分类尚存在争议,本次在金城地区采取深部花岗岩类样品,开展了锆石U-Pb测年、主微量元素等测试工作,对花岗岩的岩相学特征、形成时间、岩石地球化学特征等进行了研究。金城地区焦家断裂带下盘深部花岗岩类为中生代侏罗纪玲珑型花岗岩(测得锆石U-Pb年龄值为158.4 Ma和160.4 Ma)和白垩纪郭家岭型花岗岩。本次研究花岗岩样品均表现为I型花岗岩的地球化学特征,说明玲珑型花岗岩重熔物质较复杂,若重熔地壳源岩为火成岩表现为I型花岗岩的特征,重熔的地壳源岩为表壳岩类,则表现为S型花岗岩的特征。区内中生代花岗岩类的形成与太平洋板块俯冲华北板块有关,属大陆弧花岗岩类,为火山弧构造环境。