脂肪醇的密度与分子结构之间关系的理论探讨

本文用图论方法探讨了脂肪醇的密度与其分子结构之间的关系,提出一个结构基础明确的定量关系式.对脂肪醇的计划结果表明,密度计算值与实验值之间的一致性令人满意.此方法不仅阐明了脂肪醇的密度与其分子结构之间关系的实质,而且提供了一种预测脂肪醇密度的有效方法.     

铜(Ⅱ)-聚乙烯醇络合物形成的证明

制备了铜(Ⅱ)-聚乙烯醇络合物。通过测定溶液的电导率,分析紫外光谱和红外光谱,证明了两者之间存在配位键,提出了可能的配位结构。并且进一步从物质结构理论和熵增原理的角度探讨了形成配位键的可能性。     

硬质聚氯乙烯中空型材冷却定型模的设计

介绍了硬质聚氯乙烯塑料中空异型材冷却定型装置的设计,通过典型实例讨论其设计方法、设计要素和经验体会。     

高纯度PAN基碳纤维及其原丝的研制

对用几种方法制取的高纯度PAN原丝进行了分析对比,选取了以无碱金属引发体系的HNO_3溶液聚合工艺制得原液并纺制了碱金属及碱土金属总含量小于100ppm的高纯级PAN原丝。将其与其余三种一般纯度的PAN纤维以同样氧化、碳化工艺制得了碳纤维,并以密度、质量比电阻、X—光衍射、扫描电子显微镜、热分析及原子吸收光谱等方法研究了高纯碳丝及原丝的特点。     

PAN预氧化纤维的分段碳化工艺研究

本文通过对PAN预氧化纤维在碳化过程中的热裂解反应机理的分析,采用了以600℃为分界点的两段碳化工艺。对有关分段碳化的温度、碳化时间、张力及保护气氛等对最终碳纤维的力学性能的影响,作了较详细的研究。     

脂肪醇氧化制取脂肪醛

利用混合脂肪醇减压蒸馏获得的 C_8、C_9、C_(10)、C_(11)醇,在电解银催化剂存在下,氧化制取相应脂肪醛。研究了反应条件对转化率、选择性和收率的影响。转化率、选择性达到了90%以上。     

AN INVESTIGATION OF THE RELATION BETWEEN COTTON FIBRE PROPERTIES AND YARN QUALITY BY USING HIGH VOLUME INSTRUMENT(HVI)SYSTEM

The objective of this paper is to establish reliable prediction equations relating cotton fibreproperties measured by HVI system and yarn quality,A useful statistical method is adopted for de-veloping a multiple regression model interpreting the relation between the data of Spinlab HVIfibre properties and quality parameters of yarn STQ (Strength Tex Quotient).The percent relativecontribution of a fibre property with respect of STQ is also assessed.The results show that the totalcontribution of the HVI measured fibre properties can account for 77.4% of known variation ofyarn STQ.The main feature of the approach is its flexibility in accommodating all fibre properties.The examination of regression equation showed that it could be well applied to predict STQ ofyarns spun from the same spinning system,but,for different spinning systems and also for yarns ofdifferent linear density,modification of the equation would be needed.     

原位聚合法制备聚苯胺/ 聚乙烯醇导电材料的研究

采用原位聚合方法合成了聚苯胺／聚乙烯醇导电复合材料,研究了反应体系中聚苯胺的质量分数和反应时间对复合材料电导率的影响,并且通过红外光谱和热重分析对其结构和稳定性进行了表征和分析．     

<Emphasis Type="Italic">In situ</Emphasis> generation and detection of methyl radical by voltammetry

The chemistry of free radicals is one of the advanced subjects of fundamental sciences such as biomedicine, environment protection, new energy sources and new material. The detection technique of free radicals is an essential tool for studying free radicals. Methyl radical is one of the representatives of alkyl radicals and the studies on it attract more attention. The current approaches to obtaining methyl radical are based on pulse radiolysis of organic substances that contain the methyl gro…     

HACCP在灵芝酒生产中的应用

针对食品企业对食品质量与安全性的特别要求,利用食品安全管理体系,为生产灵芝酒的企业实行HACCP建立一套食品安全管理模型,通过危害分析确定9个关键控制点,为企业提高产品质量及安全性与增强市场竞争力提供理论依据.