Microbial production of biopoly esters-poly hydroxyalkanoates

Polyhydroxyalkanoate, abbreviated to PHA, is a family of polyesters produced by a variety of microorganisms. Over 90 PHA with various structure variations have been reported and the number is still increasing. Some interesting physical properties of PHA such as piezoelectricity, nonlinear optical activity and biocompatibility, offer promising applications in areas such as tissue engineering and drug delivery. Worldwide there have been many attempts to produce PHA as biodegradable plastics using various microorganisms obtained from screening natural environments, genetic engineering and mutation methods. It has been found that PHA synthesis is a common phenomenon of bacteria inhabiting in various locations, especially oil-contaminated soils. Bacterial strains capable of synthesizing PHA with various monomers have been identified from oil-contaminated soils, and PHA production strains capable of rapid growth and rapid PHA synthesis on molasses substrate have also been found on molasses contaminated soil. It seems that the combination of novel properties and lower cost will allow easier commercialization of PHA.     

导电聚酯片的制备及酸处理对导电层吸附量和黏附性的影响

以盐酸为掺杂剂,过硫酸铵(APS)为氧化剂,采用原位聚合的方法制备了导电聚酯片(PET)。为了增大导电高分子聚苯胺(PANI)在合成基材聚酯片表面的吸附量和黏附性,在苯胺聚合前对聚酯片进行酸处理。酸处理对聚酯片表面润湿性、化学组成及形貌的影响分别采用接触角测试仪、X射线光电子能谱仪、扫描电镜进行表征。苯胺聚合后聚酯片质量变化用于评估聚苯胺在聚酯片表面吸附量的大小。1-甲基-2-吡咯烷酮清洗后导电聚酯片颜色和电导率的变化用于判断聚苯胺在聚酯片表面的黏附性大小。实验结果表明,酸处理有效地提高了聚苯胺在聚酯片表面的吸附量和黏附性。该方法制备的导电聚酯片有望直接作为导电器件使用,可在一定程度上提高聚苯胺的可加工性。     

Performance Research of UPR/Al_2O_3 Composite Particles

UPR/Al2O3 composite particles were synthesized from unsaturated polyester resin(UPR) and nanometer/ultra-fine Al2O3 powders by means of suspension polymerization.The effects of Al2O3 with two different particle diameters on the density and hardness of the composite particles during the synthesis were studied.The results show UPR/Al2O3 composite particles synthesized by suspension polymerization are spherical,smooth,with a yield of 60%～75%(wt),and the particle diameters are 140～250μm;Al2O3 can effectively improves the density and hardness of the composite particles;when the contet is the same,effect of ultra-fine Al2O3 on the density and hardness of the composite particles is better than that of nanometer Al2O3;When the mass fraction of Al2O3 is 55%,the maximum hardness of ultra-fine Al2O3 composite particles and nanometer Al2O3 composite particles are 39.42HV and 25.66HV respectively.     

涤纶长丝织物吸湿排汗的整理工艺

应用整理剂HF-1通过后整理方式赋予涤纶长丝织物吸湿排汗性能,提高涤纶织物的穿着舒适性,改善织物手感和服用性能.通过对涤纶织物吸湿排汗性能整理工艺的研究,确定出涤纶织物应用整理剂HF-1进行吸湿排汗整理的最佳工艺条件.对整理后织物的毛细效应综合值、导湿综合值、干燥速率及耐洗性进行测试,结果表明,经整理剂HF-1整理后的...     

分散染料的多晶性及其染色行为的研究

利用X-射线衍射分别鉴定了C.I.分散红225和167的两种晶型及无定形,并定量地测试了这些晶型的热稳定性。结果表明:这些晶型受干热的行为相同,都无晶型转变发生:在水中受热时,仅有C.I.分散红167的α晶型转变成了β晶型。在染色时,发生这种晶型的转变会导致染色匀染性下降。又,染色结果表明:这两个染料在涤纶纤维上的上染量受晶型的影响不大。     

AN INVESTIGATION ON TENSILE FRACTURE FEATURE FOR THREE KINDS OF POLYESTER FIBERS

This paper deals with the fracture feature of three kinds of polyester fibers with differentstructures under different tensile conditions.We studied fracture initiation,crack propagationand ultimate fracture characteristics under tension of polyester fibers.The fracture features ofpolyester fibers are related with fiber structure and tensile condition.Crack is initiated in fibersurface.It propagates from outside to inside and eventually causes rupture of the fiber.In addi-tion,it is stated also that the analysis on tensile fracture feature of fibers might be confirmed bydynamic testing technique of scanning electron microscopy.     

混纺比对异形涤纶混纺纱光泽的影响

基于不同混纺比，借助于显微镜观察和利用Onions指数法研究了7种异形涤纶混纺纱线中三角涤纶纤维的径向分布对纱线光泽的影响．根据实验结果得出纱线光泽与Onions指数有较高的相关性；Onions指数与三角涤纶的混纺比成线性关系，而三角涤纶的利用率与三角涤纶含量并不成线性关系．     

Effects of Heat Treatment on Properties of Polyester Filaments

Many properties of polyester filaments such as heat shrinkage, tenacity, elongation at break and etc. are greatly influenced by drawing, so post-drawing is important in downstream processing. As more and more profile fibers and multi-variance fibers used in textile industry, the properties of above two kinds of differential polyester filaments after drawing in different heat conditions were studied. Finally following conclusions were obtained: Firstly, the tenacity and elongation at break decreases with the rise of Tp. Secondly, the tenacity rises but the elongation at break decreases with the increase of Tb. Then, when the Tb is low, both the shrinkage in boiling water and hi hot air decreases with the rise of Tp, while, when the Tb is high, both the shrinkage rises with the rise of Tp. The last, both the shrinkage decreases with the rise of Tb.     

多功能仿毛涤纶纤维性能的研究

测试了广东肇庆产多功能涤纶纤维的截面特性、机械力学性能及热性能；并与普通涤纶纤维及日本ＳＰｉｋｉｏ仿毛涤纶纤维作比较，为制织仿毛织物提供依据．     

涤/丙混纺纱线的开发

介绍开发涤／丙混纺纱线的过程所采用的工艺流程和设备调整方法，研究了工艺特性、产品特征和影响工艺的主要因素及其解决方法，纺制出适应市场需求的新型纱线。