含有氨基酸基团的聚(ε-己内酯)合成与表征

采用氨基酸钠游离的氨基引发ε-己内酯单体开环得到酯肽齐聚物,并以六亚甲基二异氰酸酯为扩链剂,将这些齐聚物扩链合成4种聚酯酰胺.将4种天然氨基酸(L-丙氨酸、L-亮氨酸、L-谷氨酸、L-赖氨酸)引入到聚(ε-己内酯)(poly(ε-caprolactone),PCL)中,合成和表征了4种含有氨基酸残基的聚合物.通过1H-NMR、FT-IR、水接触角、水吸收率和降解实验对该聚酯酰胺进行了表征.实验结果表明:经氨基酸改性PCL的亲水性和降解性得到了改善,其中含有L-赖氨酸残基的聚酯酰胺因亲水性最高,降解速率最快.     

A positive-temperature-coefficient electrode with thermal protection mechanism for rechargeable lithium batteries

A new positive-temperature-coefficient(PTC) material was prepared simply by blending of conductive Super P carbon black(CB) with insulating poly(methyl methacrylate)(PMMA) polymer matrix,which was empolyed as a coating layer on the aluminium foil substrate to fabricate a sandwiched Al/PTC/LiCoO2 cathode.The experimental results from cyclic voltammetry,charge-discharge measurements and impedance spectroscopy demonstrated that the PTC electrode has a normal electrochemical performance at ambient temperature,but shows an enormous increase in the resistance at the temperature range of 80?120℃.This PTC behavior greatly restrains the reaction current passing through the electrode at elevated temperatures,capable of acting as a self-actuating safety mechanism to prevent the battery from thermal runaway.     

Fluorinated Hyperbranched Poly（urea-urethane）s Containing Reactive Groups： Synthesis, Characterization and Application on Cotton Fabric

A series of hyperbranched poly(urea-urethane) s (HPUs)containing short fluoroalkyl chain and reactive groups (HPUFs)capable as hydrophobic and oleophobic coating materials were synthesized.The obtained polymers were characterized by FTIR ( fouier transform-infrared spectroscopy ),1 H NMR ( nuclear magnetic resonance),13C NMR,19F NMR,GPC(gel permeation chromatography),TGA ( thermogravimetric analyzer),and XPS (X-ray photoelectron spectroscopy) analyses.Highly hydrophobic and oleophobic cotton fabrics could be achieved from these fluorinated hyperbranched polymers by solution-immersion coating method.The static contact angles reached to 143°,114°,and 92° for water,hexadecane,and decane,respectively.The water and oil repellency ratings were 90 and 6,respectively,and still kept 80 and 5.respectively,after 10 soaping cycles at 50℃.     

药用辅料——高分子聚合材料测定方法的正交试验

设计正交试验,建立药用辅料——高分子聚合材料测定方法.以L9(34)正交试验考查该方法的4个重要因素及水平.确立方法后按2010年中国药典要求做方法学研究.结果表明:该法检测的线性范围为2～100μg.mL-1;r=0.999 8;检出限为0.5μg.mL-1;该方法的平均回收率为0.96;日内RSD为0.02.该方法符合2010年中国药典关于杂质限量检测方法的规定,是检测此类PLLA辅料中乳酸含量的可行方法.     

环氧端基聚丙烯酸正丁酯的光聚合反应机理

研究了以N.N-二(2,3环氧丙基)苯胺(DEA)-二苯甲酮(BP)或DEA-4-(2,3环氧丙氧基)二苯甲酮(EBP)为引发体系的丙烯酸正丁酯的光聚合动力学。提出了DEA-BP引发体系的丙烯酸正丁酯的聚合反应速率方程式。研究表明,DEA分子连结于大分子链的末端,DEA-EBP体系的光聚合引发速率较DEA-BP体系为快。     

等离子体处理对碘掺杂PPS电导的影响

导电的PPS(聚对苯硫醚)的电导稳定性至今未得到解决,其根本原因是掺杂剂与PPS分子之间不能形成或不能永久形成电荷传递结合物。本文以不形成电荷传递结合物的掺杂剂碘(I)作为研究对象,在化学掺杂之后进行了等离子体处理,使PPT的电导率和稳定性大幅度提高,达到强掺杂剂的程度。红外吸收和二次离子质谱分析表明,经低温等离子体处理后,I和PPS之间形成(C_3 H_2S)~+和(HCIS)~+ 基团,电导的活化能从原始的2.0eV降低到0.2V,电导的机理是载流的热活化过程。     

PBT/PET共混体系熔融过程的DSC研究

用共溶解-沉淀法制得的共混物PBT/PET各组分分别结晶,PET的存在对PBT的结晶有抑制作用;熔融共混PBT/PET的DSC图谱与共混时间有关;超过一定时间后只呈现单一的熔融峰,其本质是由于酯交换使共混物变为共聚酯,而非互溶共晶.