二维椭圆柱长方晶格可控光子带隙研究

从理论上研究了GaAs为背景介质,电磁感应透明(EIT)气体灌注的二维椭圆柱长方晶格光子晶体的光子带隙,发现在优化光子晶体几何参数的基础上,通过调控原子气体的自发辐射率、无辐射衰变率、控制光Rabi频率、原子数密度等外参数可以使高频区域的能带从完全光子带隙向零带隙转变.     

Dynamic analysis of preferential orientation of arasonite crystals in nacre from mollusk shell

Based on the scanning electron microscope （SEM） observations, it is confirmed that the nacre is composed of aragonite crystals and organic matrix with interlaced arrangement, showing ordered ＂brick-mortar＂ structure. The dynamic analysis of preferential orientation of aragonite crystals in the nacre from the abalone （Haliotis diverscolor supertexta） with different shell ages is systematically investigated using X-ray diffraction （XRD） and high resolution transmission electron microscope （HRTEM）. Experiments reveal that, in the nacre from the juvenile mollusk shell, there exist three kinds of orientations of aragonite crystals： （113）, （002） and （012）. However, along with the growing of the mollusk shell, the intensity of （012） and （113） becomes weak, and the （002） becomes the preferred crystal orientation of aragonite in the nacre from the adult mollusk shell, which means that the c axis of aragonite crystals is perpendicular to the nacreous layers. The results obtained show that the nacre possesses a highly ordered structure at the micrometer/nanometer mulUscale levels.     

声子晶体导线的振动带隙特性

为了解决超、特高压输电线路的舞动问题,提出了一种由导线、间隔棒、弹簧振子组成的声子晶体导线。基于导线的振动微分方程与Bloch理论,建立了计算声子晶体导线振动能带结构的传递矩阵法,进而通过计算发现声子晶体导线在舞动常发的频率范围内具有局域共振型带隙特性。为了验证该带隙特性,以四分裂导线为例,应用有限元法计算了有限周期声子晶体导线的振幅和频率响应特性。结果表明,在带隙的频率范围内导线振动响应具有明显衰减,为输电线路减振防舞提供一种新思路。     

利用核磁共振研究可逆热变色物质的变化机理

利用核磁共振光谱研究了可逆热变色复配物的变色机理，结果表明，变色色基在酸性条件下开环，形成共轭结构，双酚Ａ在高温时不解离，在碱性条件下下解离。     

双十八烷基二甲基氯化铵水溶液的性质

采用动态光闪射、透射电子显微镜、流变仪等手段初步探讨了双十八烷基二甲基氛化铵(TA-100)水溶液内部胶束大小、形貌以及溶液的流变性质,借助偏光显微技术观察了TA-100表面活性剂形成的各相异性水溶液的液晶织构.研究发现,溶液中表面活性剂聚集体的平均粒径、溶液流变性质随表面活性剂的质量分数发生规律性变化,TA-100本...     

对称约化胞及其应用

初基胞约化处理是重构点阵和确定未知晶体Ｂｒａｖａｉｓ点阵的一个重要环节，原始数据的测量和计算引入的积累误差给初基胞约化处理靠民困难和不确定性，为此，提出了一种新的约化胞分数法及其约化处理的判据，并给出了对称的约化胞与Ｂｒａｖａｉｓ点阵之间的对应关系，与Ｎｉｇｇｌｉ约化处理相比，对称约化处理方法更为简捷和合理。     

Crystallization and preliminary X-ray analysis of an anti-insect toxin BmK I6 from Buthus martensii Karsch scorpion

An excitatory anti-insect toxin from BmK scorpion, named BmK I6, has been purified and crystallized recently. Two crystal forms have been obtained by using ammonium sulfate as precipitant at different pH, one of which is single crystal. Diffraction data have been collected for the single crystal on a Mar Research 345 Image Plate. The analyses of the data show that the crystal can diffract to 0.28 nm resolution and belongs to the space group C2 with unit cell parameters a = 4.65 nm, b = 8.52 nm, c = 3.26 nm, α = γ = 90° ,β = 110.5° . There are 2 molecules per asymmetric unit according to its unit cell volume and molecular weight.     

添加剂对LAP晶体性能的影响

选用（ＮＨ４）３ＰＯ４作添加剂，生长了不同添加量的ＬＡＰ晶体，实验发现：添加（ＮＨ４）３ＰＯ４后，扩大了晶体生长的过饱和温区，抑制杂晶的生长，提高了晶体利用率。     

Structural properties of matrix metalloproteinases

Matrix metalloproteinases (MMPs) are involved in extracellular matrix degradation. Their proteolytic activity must be precisely regulated by their endogenous protein inhibitors, the tissue inhibitors of metalloproteinases (TIMPs). Disruption of this balance results in serious diseases such as arthritis, tumour growth and metastasis. Knowledge of the tertiary structures of the proteins involved is crucial for understanding their functional properties and interference with associated dysfunctions. Within the last few years, several three-dimensional MMP and MMP-TIMP structures became available, showing the domain organization, polypeptide fold and main specificity determinants. Complexes of the catalytic MMP domains with various synthetic inhibitors enabled the structure-based design and improvement of high-affinity ligands, which might be elaborated into drugs. A multitude of reviews surveying work done on all aspects of MMPs have appeared in recent years, but none of them has focused on the three-dimensional structures. This review was written to close the gap. Received 18 November 1998; accepted 11 December 1998     

一类流场作用下晶体生长模型解的适定性

晶体在形核时。熔体内存在的温度和浓度起伏有助于扩大“近程有序”结构的范围，进而促进形核。研究熔体中有对流作用时三维非稳态晶体生长的温度起伏和浓度起伏数学模型．有助于从本质上认识这一自然现象。证明了稳定流场的作用下晶体生长数学模型解的适定性。