Experimental Observables on Nuclear Liquid Gas Phase Transition

Progress on nuclear liquid gas phase transition （LGPT） or critical behavior has been simply reviewed and some signals of LGPT in heavy ion collisions, especially in NIMROD data, are focused. These signals include the power-law charge distribution, the largest fluctuation of the fragment observables, the nuclear Zipf law, caloric curve and critical exponent analysis etc.     

Ab initio study of the effects of Ag/Mn doping on the electronic structure of LiFePO_4

Based on density functional theory (DFT) of the first-principle for the cathode materials of lithium ion battery, the electronic structures of Li(Fe1-xMex)PO4 (Me = Ag/Mn, x = 0―0.40) are calculated by plane wave pseudo-potential method using Cambridge serial total energy package (CASTEP) program. The calculated results show that the Fermi level of mixed atoms Fe1-xAgx moves into its conduction bands (CBs) due to the Ag doping. The Li(Fe1-xAgx)PO4 system displays the periodic direct semiconductor characteristic with the increase of Ag-doped concentration. However, for Fe1-xMnx mixed atoms, the Fermi level is pined at the bottom of conduction bands (CBs), which is ascribed to the interaction be-tween Mn(3d) electrons and Fe(4s) electrons. The intensity of the partial density of states (PDOS) near the bottom of CBs becomes stronger with the increase of Mn-doped concentration. The Fermi energy of the Li(Fe1-xMnx)PO4 reaches maximum at x = 0.25, which is consistent with the experimental value of x = 0.20. The whole conduction property of Mn-doped LiFePO4 is superior to that of Ag-doped LiFePO4 cathode material, but the structural stability is reverse.     

空间结构热-动力学耦合系统稳定性的有限元分析

针对在轨航天器柔性附件的热-动力学耦合系统,提出了一种稳定性分析有限元方法。该系统的状态方程既包括考虑辐射换热且耦合了结构变形的非线性瞬态热传导方程,也包括与瞬态温度场相联系的结构动力学方程。由于结构变形对于受热条件的耦合影响以及辐射换热的存在,该系统具有高度非线性。借助于非线性振动理论,给出了系统热诱发振动的稳定性准则。针对不同的结构,可以计算出不同的运动稳定边界,该边界将参数空间分成了稳定区域和不稳定区域。对哈勃太空望远镜太阳帆板进行了稳定性分析,该方法所得数值解与文献结果一致。对更为复杂的卫星天线,用该方法给出其发生热颤振的参数条件,探讨了结构参数、加热条件对其热-动力学耦合系统稳定性的影响。     

Theoretical study on the lithium bond interaction of furan homologues C_4H_4Y (Y=O, S) with LiCH_3 via DFT and MP2

The optimizations geometries and interaction energy corrected by BSSE of the complexes between C4H4Y (Y=O, S) and CH3Li have been calculated at the B3LYP/6-311 G** and MP2/6-311 G** levels. Three complexes were obtained. Abnormally, the calculations showed that all the C10—Li14 bond lengths increased obviously but the blue-shift of C10—Li14 stretching frequency occurred after formed complexes. The calculated binding energy with basis set super-position error (BSSE) and zero-point vibrational energy corrections of complexes I―III is ?45.757, ?35.700 and ?39.107 kJ·mol?1, respectively. The analyses on the combining interaction with the atom-in-molecules theory (AIM) also showed that a relatively strong lithium bond interaction presented in furan homologues C4H4Y---LiCH3 systems. Natural bond orbital theory (NBO) analysis has been performed, and the results revealed that the com- plex I is formed with n-σ type lithium bond interaction between C4H4O and LiCH3, complex II is formed with π-s type lithium bond interaction between C4H4O and LiCH3, and complex III is formed with π-s and n-s type lithium bond interactions between C4H4S and LiCH3, respectively.     

A Novel Polymethyl Methacrylate （PMMA）TiO2 Nanocomposite and Its Thermal and Photic Stability

A new kind of polymethyl methacrylate （PMMA）-TiO2 nanocomposite was synthesized through polymerization. The thermal and photic stability of this PMMA TiO2 nanocomposites were investigated. The as prepared samples were characterized by scanning electron microscopy （SEM）, UV-Vis spectroscopy, differential thermal analysis （DTA） and the photo-induced weight loss, The results show that the photostability of the PMMA-TiO2 nanocomposite is higher than that of the pure PMMA under UV-light irradiation, The weight loss of the pure PMMA reaches 30 % after 300 h UVirradiation, while the composite only 0.3% under the identical experimental condition. The glass transition temperature （TR） of pure PMMA is only 80℃, while the Tg of the composite reaches 258℃. Compared with pure PMMA, the thermal stability of the composite is greatly enhanced.     

信息不对称下企业并购信号传递博弈模型研究

根据企业并购中的信息不对称现象,结合不完全信息动态博弈及信息经济学的有关理论,建立了目标企业与并购企业之间的信号传递博弈模型,并进行了实例分析,结果表明,目标企业所发出的信号能够反映出目标企业的真实质量,尽管并购企业不能直接观察到目标企业的价值,但可以通过观测目标企业发出的信号来判断目标企业的预期价值水平,并据此作出正确的并购行为.     

原子光谱线变宽的因素分析

分别从经典理论和量子理论的不同角度论述了使原子光谱线变宽的各种主要因素:由于能量的不确定关系导致的自然致宽;多普勒致宽;碰撞致宽;因碰撞过程中原子能级变化而导致的压力致宽、场致宽等.通过分析,阐明了实际光谱线与理想光谱线的不同及其原因.     

r序同态与r开集在子拓扑空间中的性质

提出了r不定序同态、r连续序同态、r开序同态并讨论了它们之间的相互关系,得出了LF-r开集在开子空间中仍是LF-r开集,两个LF拓扑空间之间序同态r连续的充要条件等结论。     

综合(指导)类科技期刊发展现状及对策思考

文章分析了目前我国综合(指导)类科技期刊存在的主要问题,提出了综合(指导)类科技期刊要走出困境必须采取的对策措施。     

一种高精度低功耗流水线ADC开关电容电路

提出一种新的电容失配校正方案及功耗驱动的OTA设计思路,通过对虚地电容的修正,将电容失配因子在取样保持系统中去除,达到提高电容匹配程度,降低OTA增益误差的要求,使开关电容部分的瞬态功耗下降.本文采用TSMC 0.18μm工艺设计了一个8位,取样速率为200MHz的流水线结构模数转换器作为验证电路,仿真结果说明此优化结构符合高精度和低功耗要求,可应用到流水线等高速模数转换电路中作为信号前端处理模块使用.