STUDIES ON SEQUENCE STRUCTURE OF PET/PHB COPOLYESTERS

In this paper,the sequence distribution in the copolyester made from polyethyleneterephthalate (PET) and p-hydroxybenzoic acid (PHB) at 290℃has been investigated by 400MHz ~1H-NMR.It has been found that reference factor m of PET/PHB copo!yester linearly de-creases when PHB molar fraction increases.In addition,a series of sequence structure parameters,such as PET,PHB segment mean length,randomness,etc.are calculated from a probability modelby m,X_(PHB)%.This copolyester made at 290℃ is found to be nearer to that of completely randomcopolymer compared with that of the eopolyester made at 270℃,as in the case of the generalcopolycondensation.PHB-rich phase is formed only when PHB per number≥4,basing on thisconclusion,we establish the relationship between theoretical contents of PHB-rich phaseW_(PHB)% and PHB contents X_(PHB)% :W_(PHB)%=104.0X_(PHB)~(4.40) The minimum PHB-rich phase con-tent forming liquid crystal phase is 1.1% wt.     

关于胆甾相液晶选择反射特性的探讨

本文讨论了胆甾相液晶因分子排列的螺旋结构而具有的选择反射的光学特性,利用布喇格反射条件和电偶极子辐射模型,分别导出胆甾相液晶在反射时对入射光的波长和偏振状态的选择条件。     

Self-assembly of two-dimensional DNA crystals

Self-assembly of synthetic oligonucleotides into two-dimensional lattices presents a 慴ottom-up?approach to the fabrication of devices on nanometer scale. We report the design and observation of two-dimensional crystalline forms of DNAs that are composed of twenty-one plane oligonucleo-tides and one phosphate-modified oligonucleotide. These synthetic sequences are designed to self-assemble into four double-crossover (DX) DNA tiles. The 憇ticky ends?of these tiles that associate according to WatsonCrick抯 base pairing are programmed to build up specific periodic patterns upto tens of microns. The patterned crystals are visualized by the transmission electron microscopy.     

由正负折射率材料构成的Thue-Morse序列光子晶体的共振光传输

讨论了由正折射率材料和负折射率材料构成的Thue-Morse序列光子晶体的共振光传输特性。利用传输矩阵法，得到传输矩阵元的逆推关系式及透射率。数值计算结果表明，类似于普通材料构成的TM序列光子晶体，含负折射率材料的此种多层系统的完全透射态也存在自相似排列。     

用转移矩阵方法计算一维光子晶体的禁带结构

该文提出了一种利用转移矩阵来计算一维光子晶体的光子禁带结构的新方法．利用此方法计算了不同介电常量、不同几何结构的晶体的禁带特征，并讨论了掺杂后的一维光子晶体光子禁带的变化情况．     

用凝胶法生长KClO4晶体

凝胶法是生长KClO4晶体最合适的方法．实验研究了反应物浓度、凝胶密度、温度、凝胶pH值对KClO4晶体成核数目、大小、形状及质量的影响，得出了生长较大尺寸、完整性好、高质量的KClO4晶体的最佳条件和参数．第一次对KClO4晶体形态、各晶面的显露程度进行定量分析，实验与理论分析相符合．证实了Hartman和Perdok的PBC理论．研究结果为下一步进行晶体生长机理研究打下了基础．     

多声子对弱耦合体磁极化子性质的影响

研究了磁场中多原子极性晶体中多声子相互作用对弱耦合体极化子基态能量和有效质量的影响．采用么正变换、线性组合算符和拉格朗日乘子法。计算了多声子相互作用对磁极化子基态能量和有效质量的附加贡献．结果表明，基态能量的附加贡献为电子-不同支LO声子-磁场间耦合的附加能量以及电子-不同支LO声子间耦合的附加能量之和，有效质量的附加贡献为电子-不同支LO声子间耦合的附加贡献．     

贝壳中文石晶体择优取向的XRD分析

贝壳珍珠层独特的结构是其优异力学性能的重要原因.采用X射线衍射法(XRD)对贝壳珍珠层及柱状晶的晶体结构及择优取向进行了详细的探讨.结果表明:珍珠层中文石晶体在沿珍珠层面上存在两种定向排列,即(002)和(012),具有择优取向性,柱状晶层结构的无序性比珍珠层大.     

单轴晶体中三阶非线性自作用极化强度矢量的计算

讨论单轴晶体中三阶非线性自作用极化强度矢量的计算．在主轴坐标系下对6／mmm和6／m点群晶体中由o光和e光激发的极化强度矢量作了具体分析,并且通过坐标变换得出其在传输坐标系下的表达式．该矢量变换方法可直接用于计算3^-和3^-m,以及4／m和4／m岫4类单轴晶体中的非线性极化强度矢量,并可推广应用于各向异性介质中其他非线性光学过程中的非线性极化强度矢量的计算．     

Bleaching effect and nonvolatile holographic storage in doubly doped LiNbO<Subscript>3</Subscript>:Fe:Cu crystals

The bleaching effect, i. e. the crystal shows that decoloration after it is illuminated by ultraviolet light, has been observed in congruent LiNbO3:Fe :Cu crystals. Based on this bleaching effect, a new technique including the reco rding phase by two interfering red beams and fixing phase by both UV light and a coherent red beam has been experimentally investigated to realize nonvolatile holographic storage in LiNbO3:Fe:Cu. The results of proof-of-concept experiments confirm that bleaching effect becomes an alternative physical mechanism for nonv olatile holographic storage with high recording sensitivity and weak light-induced scattering noise.