CoPt-Co hybrid supported on amino modified SiO_2 nanospheres as a high performance catalyst for hydrogen generation from ammonia borane

CoPt-Co hybrids were successfully supported on amino modified SiO_2 nanospheres by a chemical reduction method at a temperature of 278 K.The solid carrier i.e.amino modified SiO_2,provides numerous anchoring sites for the metal nanoparticles(NPs)to improve the dispersion while reducing the size of metal NPs.The supported NPs displayed a narrow particle size distribution on the SiO_2 surface with an average diameter of 12 nm.The XRD results alongside with the binary alloy phase diagram suggest that the resulted NPs are bimetallic,composed of CoPt and amorphous Co.Among the prepared materials,the solid with the specific composition of SiO_2@Pt_(0.1)Co_(0.9)was proved to be effective catalyst for ammonia borane(AB)hydrolysis in aqueous solution.The turnover frequency(TOF)value of the supported nanocatalyst was 25.59mol_(H_2)min~(-1)·mol_M~(-1),almost twice as that of unsupported Pt_(0.1)Co_(0.9)NPs while the activation energy was 37.05 kJ mol~(-1).Furthermore,the SiO_2@Pt_(0.1)Co_(0.9)composite manifested high catalytic activity even after five cycles of reuse.     

一个较精确加强型的半离散Hilbert型不等式

应用权函数的方法及Hermite Hadamard不等式, 建立一个较精确且加强型的半离散非齐次核Hilbert型不等式, 并给出该不等式具有最佳常数因子联系参数的一组等价性质及一些特殊参数不等式.      

碳化细菌纤维素在钙钛矿太阳能电池对电极中的研究

在高效的钙钛矿太阳能电池(PSCs)中，通常采用贵金属对电极(Au、Ag)和昂贵的空穴传输材料(HTM)，导致了高成本和不稳定等问题.该研究使用稳定的无HTM的CsPbBr3纯无机钙钛矿的PSCs，将结构优异的天然纳米生物材料细菌纤维素(BC)经过高温碳化得到具有纳米精细结构、大表面积和孔容的多介孔碳化细菌纤维素(CBC)材料，对该材料进行SEM、XRD、FT-IR、比表面积、电导率测试以证实该材料在PSCs上的应用潜质.根据PSCs对电极的应用需要，将CBC及其与商业导电碳浆(CS)混合物作为PSCs对电极材料，通过J-V、IPCE等测试，发现纯CBC材料的电池效率高于纯CS，在作为PSCs对电极方面具有很大的潜力.该研究不仅扩大了生物质碳材料的应用领域，而且有望将CBC作为低成本稳定高效PSCs对电极材料.     

另类元素周期表

为帮助学生理解元素排列规律,综述了长式、螺旋式和三维式元素周期表,讨论了各自的优缺点和辅助教学作用.介绍的周期表在提高学生学习兴趣,开阔学生眼界,培养学生创造性思维和想象力等方面有重要的参考价值.     

GLP-1R agonists therapy for type 2 diabetes

Glucagon-like peptide-1 receptor （GLP-1R） agonists are widely used for treating type 2 diabetes mellitus （T2DM） be- cause of their glucose-lowering and weight-losing effects, and low risk of hypoglycemia. Hence, there is considerable interest in understanding the mechanism underlying the beneficial effects of GLP-I and developing stable and effective GLP-1R agonists. Here, we summarize the presently known mechanism of GLP-I actions, which are mainly through regulating cAMP-PKA signaling pathway; the latest developments in novel clinical GLP-1R agonists are also introduced, which are characterized with multiple properties, such as extended half-life, reduced side-effects, lower production costs and more convenient drug dosing mode. The potential risk of GLP-I-based therapeutics, an often-ignored fact, is also discussed.     

三氯乙酸催化合成β-烯胺酮类化合物

在三氯乙酸催化剂的作用下,以乙醇为溶剂,将芳香胺类化合物和β-二酮一锅反应合成β-烯胺酮类化合物.此法高效、安全,操作便捷,且产率高.     

模糊模式识别中隶属函数选取的探讨

通过数值实例,论证了利用最大隶属度原则对三角形类型模糊模式识别时隶属函数选取的优越性,并提出了一种给定阈值且以三角形内角和差关系作为底数变量和指数变量的指数型隶属函数.     

Waugh结构(NH_4)_6[MnMo_9O_(32)]·8H_2O催化合成乙酸异戊酯

以Waugh结构钼锰杂多酸盐作为催化剂对乙酸异戊酯的合成进行了催化研究.确定了最佳反应条件:醇酸摩尔比为1.646∶1,酸化催化剂用量为0.2 g,带水剂为3 mL甲苯,反应时间63 min左右,选择性100%,转化率达82.70%.     

新派烟台方言单字调的实验语音研究

相对于传统耳听手记的声调研究方法,实验语音学的方法使得声调研究结果更加客观化.烟台方言可以分为老派和新派方言,它们的单字调声调在某种程度上存在着不同.就目前来讲,对新派烟台方言研究相对较少,尤其是实验的方法,几乎还是空白.应用现代实验语音学的方法,侧重整个实验过程和实验数据,测算出新派烟台方言单字调调类最终分为三类,调类与调值分别为：乎声44,上声313,去声42.由于这一结果与传统烟台方言单字调调值有较大差异,故本文对新派烟台方言单字调与传统烟台方言研究结果及普通话也进行了比较,并在此基础上分析了新派烟台方言单字调调值可能演变的原因.新调值还有可能对烟台方言两字组及三字组连读变调模式产生影响.     

古典概型问题的数学模型

在古典概型问题中引入了n次随机试验,n维样本点,n维随机事件和n维样本空间等概念,对解决古典概型的应用问题提供了相应的数学模型.