核壳胶粒增韧改性聚丙烯研究2. 分散相性质的影响

以甲基丙烯酸缩水甘油酯接枝改性聚丙烯 ( PP- g- GMA)作为界面改性剂 ,采用尺寸可控的聚丙烯酸丁酯 ( PBA) /聚甲基丙烯酸甲酯 ( PMMA)反应性核壳胶粒与聚丙烯 ( PP)进行反应共混 ,研究了核壳胶粒及胶粒核层交联度对 PP/PP- g- GMA/核壳胶粒共混物冲击力学性质的影响 .结果表明 ,当核壳胶粒在 0 .38～ 1 .58μm变化 ,较大尺寸的胶粒有利于增韧 ;随胶粒核层的交联剂浓度由 0增加到 5%,发现存在最适合于增韧的胶粒核层交联度 .研究还显示 ,核壳胶粒尺寸与核层交联度对 PP增韧的影响之间存在相互作用 ,最适合于增韧的胶粒核层交联度 (交联剂浓度 )随胶粒尺寸变化而改变 ,这可用空穴化 /剪切屈服机理来加以解释     

Polystyrene Microspheres Coated with Smooth Polyaniline Shells: Preparation and Characterization

Polystyrene/polyaniline core-shell structure microspheres were synthesized in the presence of poly(sodium 4-styrenesulfonate) as stabilizer and hydrochloric acid as dopant to improve the processibility of conducting polyaniline. After the one-pot reacting process, the product was easily purified by washing with water. The polyaniline shell covering the polystyrene sphere surface was confirmed with FT-IR and X-ray photoelectron spectroscopy. The conductivity of the polyaniline-coated polystyrene particles was 0.0017 S/cm and increased to 0.1 S/cm after being doped in the HCl vapor. The morphology of the microspheres was characterized by TEM and SEM. The particles show a more uniform and smooth surface than previous particles.     

龙岩花生产业化分析与发展思路

通过对目前龙岩花生的生产、加工、销售进行调查分析,找出花生产业存在的问题,针对这些问题提出加快龙岩花生产业发展措施.     

What is the matter with Corbicula fluminea (Mollusca: Bivalvia: Cyrenidiae)? Occurrence of unusual shell erosion in Northern Italy

ABSTRACT

Corbicula fluminea is a bivalve considered to be among the 100 worst invasive species in Europe due to its economic and ecological impacts in freshwater ecosystems. Here, we report for the first time a phenomenon of shell erosion observed in two distinct populations of C. fluminea collected in 2015 from two semi-natural small streams of the River Ticino hydrographic basin (Northern Italy). We measured several biometric variables in order to quantify the shell damage: length and thickness of the right valve and the shell free dry weight of each specimen and compared results with those of ‘normal’ populations from another stream of the same area. Our results confirmed that there was abnormal shell erosion and a reduction in shell thickness in both populations. We hypothesised several potential causes for the observed erosion, but none of them could provide sufficient explanation: neither the pH of the water, nor the level of calcium or total hardness of the water or granulometry of the substrates differed among streams. Similarly, predation pressure cannot be considered a reasonable explanation, since in the study area only a few animals actively prey on these bivalves and the marks they leave on the shells are completely different from the ones observed on our specimens. Lastly, we hypothesised that the bivalves may have been affected by a disease or parasitic infestation that had weakened their shells or prevented them from self-repairing and identified a fungal parasite that could possibly cause a disease to C. fluminea, namely the Ascomycota Geotrichum candidum. However, this species occurred only in one of the two abnormally eroded populations. In conclusion, a valid explanation for the morphological alteration that our study revealed has yet to be found.     

^182Os核的推转壳模型处理

利用推转壳模型的粒子数守恒方法计算了＾１８２Ｏｓ核能谱，带交叉频率，带间相互作用强度，顺排角动量等，并对＾１８２Ｏｓ核波函数的ｓｅｎｉｏｒｉｔｙ结构进行了分析，在计算过程中，根据不同的阻塞情况适当考虑了Ｃｏｒｉｏｌｉｓ减弱，结果表明，以上各种量的计算值与对应的实验值都能较好的符合。     

高方盒末次拉深中角部壁间距的优化计算

本文从主同盒形件末次拉深的变形分析出发,建立数学模型,对末次拉深中角部壁间距δ进行了优化计算,对工艺设计具有指导意义。     

Description of rotational properties of the superheavy nucleus ^256,258,260Rf by projected shell model

Band structure of the Z = 104 nucleus 256Rf has been a recent research focus in nuclear physics. We performed projected shell model calculations for this and some other neighboring Rf isotopes. Specifically, we studied rotational properties of these nuclei and showed that variations in dynamic moment of inertia were sensitive to single-particle structures, which may be useful information for locating the anticipated island of stability. Electromagnetic transition properties were also calculated, and measurable quantities were predicted for further experimental test.     

大鼠肠道对花生壳提取物主要成分的吸收研究

目的:研究花生壳提取物对大鼠在体肠的吸收情况.方法:运用单向灌流模型并采用HPLC法测定花生壳提取物中主要有效成分木犀草素在灌流液中的浓度.结果:花生壳提取物大鼠肠吸收优于木犀草素单体,两者的肠腔有效吸收系数(Peff)和吸收速率常数(ka)有显著性差异(P＜0.05).结论:花生壳提取物中的其他成分对木犀草素的吸收有促进作用.     

Bi2O3/Cu-O-Cr核壳结构纳米复合物的合成

采用沉淀法制得球形单分散Bi2O3纳米粒子；通过共沉淀法制备球形单分散Bi2O3／Cu-O-Cr核壳结构复合纳米材料,通过X射线衍射、透射电镜、能谱分析和红外光谱等技术表征所合成材料的成分组成、晶体结构、微现形貌以及颗粒尺寸，并对Bi2Oa／Cu-O-Cr核壳结构的复合纳米粒子的形成机理进行研究。研究结果表明：在包覆前先对Bi2O3粒子进行表面铵离子（NH4^＋）功能化是形成均匀核壳纳米结构的关键；铜铬包覆层以氨配合物的形式包在Bi2O3粒子表面，形成棱壳结构的复合粒子，复合粒子的平均粒度为78nm．核厚为60nm．     

导电聚苯胺/聚苯乙烯核/壳结构复合微球的制备

通过化学改性对聚苯乙烯微球进行磺化处理，引入亲水性的磺酸基，采用原住聚合的方式，在磺酸根的掺杂下制备了具有核／壳结构的导电聚苯胺／聚苯乙烯复合微球。复合微球中聚苯胺含量为19．3％时导电率约为0．10S／cm，与用聚苯乙烯磺酸本体掺杂的导电率相当。