Ferrocene-Nafion修饰厚膜碳糊电极的葡萄糖传感器研究

以基于丝网印刷技术制作的厚膜碳糊电极为基底电机,用二茂铁为介体、Nafion修饰厚膜碳糊电极制备了葡萄糖传感器．Nafion涂于电极表面上形成的膜具有强的附着力,防止了二茂铁及酶的流失,电极稳定性提高．并且由于低的工作电位（＋025vsSCE）和Nafion膜的阳离子交换作用,基本上消除了电活性物质（抗坏血酸、尿酸）的干扰,具有防污能力．该酶传感器的检测上限可达18mmol／L,响应时间小于60s.     

彩色涂料印花色浆罩印性能的研究

介绍了涂料印花罩印助剂的制备和应用，通过对涂料罩印浆的物理化学性能的研究，探讨了提高罩印效果的途径及罩印助剂颗粒的物理化学性质对罩印效果的影响。     

木钙-碳酸氢钠复合外加剂对水泥浆体流变性能的影响

主要考察了木质素磺酸钙(CL)—碳酸氢钠(SB)复合外加剂对水泥浆体流变性能的影响。实验结果表明,木质素磺酸钙—碳酸氢钠(CL:SB=1:1．8)不仅具有较强的减水效应,而且使水泥的凝结变成主要由AFt的生成所控制。掺剂水泥浆体的凝结时间缩短,流动度损失增大。     

泵送减水剂对尾砂-棒磨砂膏体料浆和易性与充填体强度影响研究

针对金川镍矿尾砂-棒磨砂膏体在充填管道输送中存在的堵管问题,开展了泵送减水剂对膏体的和易性与充填体强度影响试验研究.首先分析了膏体物料的物化特性和颗粒级配;然后采用金川镍矿尾砂-棒磨砂膏体充填系统工业生产中的技术参数,开展了添加不同泵送减水剂添加量的充填体强度、膏体和易性以及流变特性参数测试研究.研究结果显示,当添加1%~2%的泵送减水剂,3、7和28 d强度均有显著提高.膏体的和易性随泵送减水剂添加量的增加而提高,且浓度越高,效果越显著.当膏体浓度(质量浓度)在78%~80%的范围,膏体初始剪切应力和粘滞系数均随着泵送减水剂的增加而线性减小.结合泵送减水剂对充填体强度、膏体和易性以及流变特性影响分析,并考虑膏体充填成本与采矿经济效益,确定1%的泵送减水剂为比较合理的添加量.研究结果为金川镍矿膏体充填系统料浆制备提供重要依据,已经应用于金川矿山膏体充填的工业化生产.     

高德矿增大水砂充填供水能力的研究

因充填供水管年久失修,管径相对缩小,供水能力降低,充填能力不够,严重影响矿井生产。本文论述了在不停产条件下,改造充填供水管,增加充填能力的措施及实施后的效果。     

用颗粒流模拟技术模拟固化时间对胶结膏体细观参数的影响

Several special mechanical properties, such as dilatancy and compressibility, of cemented paste backfill (CPB) are controlled by its internal microstructure and evolution. The mesoscopic structure changes of CPB during the development process were investigated. On the basis of the scanning electron microscopy (SEM) and mechanical test results of CPB, the particle size information of CPB was extracted, and a two-dimensional particle flow code (PFC) model of CPB was established to analyze the evolution rule of mesoscopic parameters during CPB development. The embedded FISH language in PFC was used to develop a program for establishing a PFC model on the basis of the SEM results. The mesoscopic parameters of CPB samples at different curing times, such as coordination number (C_n), contact force chain, and rose diagram, were obtained by recording and loading and used to analyze the intrinsic relationship between mesoscopic parameter variations and macroscopic mechanical response during CPB development. It is of considerable significance to establish the physical model of CPB using the PFC to reveal the mesoscopic structure of CPB.     

基于数字散斑技术的水泥净浆微观蠕变与收缩

摘 要：为探究大型试件水汽平衡较长引起额外收缩开裂的问题,提出了一种新型原位微观力学试验方法对水泥净浆的微观蠕变与收缩进行研究。研究结合DIC（数字散斑技术digital image correlation）进行观测,在ESEM（environmental scanning electron microscope）环境扫描电镜和CC（climate chamber气候试验箱)中对薄水泥块分别进行单轴-双轴压缩蠕变和收缩试验。试验结果表明,相较于传统测试方法,新的测试框架显著缩短了干燥时间,至少缩短了200倍,从而有效减小了开裂的风险。水泥净浆的自由干燥收缩与RH（相对湿度relative humidity）高于60%时的质量损失之间存在高度线性相关性。在相对湿度50%-60%之间,水的空化作用对干燥收缩产生影响。ESEM中的干燥条件与气候试验箱中的环境空气干燥条件相比,气压较低,引发了强制对流流动,导致干燥速率显著增加,但在相对湿度为20%RH的平衡状态下,两者的收缩变形基本保持一致。快速干燥的试件与缓慢干燥的试件相比具有更大的孔隙,且未加载试件的孔隙大于加载试件。在单轴压缩试验中,干燥蠕变随干燥收缩的变化呈现出双线性的趋势;在双轴压缩试验中,干燥蠕变呈现出线性关系。干燥蠕变的泊松比在两种压缩试验中均表现出负值,在蠕变泊松比处于-0.1到0之间时,CC试验所得的蠕变性能与ESEM方法的结果基本一致。     

Determination of trace heavy metals in milk using an ionic liquid and bismuth oxide nanoparticles modified carbon paste electrode

A novel carbon composite electrode modified with bismuth oxide nanoparticles and the ionic liquid n-octylpyridinium hexafluorophosphate was fabricated and used to simultaneously determine cadmium and lead levels using square wave anodic stripping voltammetry.This electrode combines the unique advantages of nanomaterials and ionic liquid with the low cost and easy fabrication of the carbon composite electrode.Compared with the traditional binder based composite electrode,our electrode exhibited well-defined and separate stripping voltammetric peaks for cadmium and lead.Furthermore,the antifouling capacity of the bismuth film electrode was significantly improved by the ionic liquid.Under optimized conditions,the linear range of the composite electrode was from 3.0 to 30.0 μg L-1 for both metal ions with a detection limit of 0.15 μg L-1 for cadmium and 0.21 μg L-1 for lead.Trial milk sample analyses showed that the modified electrode was sensitive,reliable and effective for the determination of trace heavy metals,holding great promise for routine analysis applications.     

聚羧酸系高效减水剂聚合反应动力学及其减水性能

采用分子设计原理,用甲氧基聚乙二醇丙烯酸酯(MPEGAA)、丙烯酸(AA)和马来酸酐(MAD)制备聚羧酸系高效混凝土减水剂,考察了单体总浓度、引发剂浓度、反应温度等因素对高效减水剂聚合反应速率的影响,建立了聚合反应动力学关系式,即r∝cI0.590 3c0M.808 9e-5 465/T。通过测定水泥净浆流动度,考察了高效混凝土减水剂的减水性能,确定了较理想的合成工艺条件,即单体物质的量比n(MPEGAA)∶n(AA)∶n(MAD)=1∶1.50∶0.36,引发剂占单体总质量的2.5%,反应温度为60℃,反应时间为6h。     

一种新的示波滴定法——碳糊电极示波滴定法

建立了一种新的示波滴定法──碳糊电极示波滴定法．研究了固体石蜡碳糊电极示波计时电位滴定法和示波电位滴定法,讨论了电极的制作、各种滴定体系终点指示的灵敏度及响应机理．结果表明,所设计的方法简便易行,终点指示灵敏,适用范围广