烟煤型城市大气PM2.5中水溶性阴离子的测定及分析

本文测定了烟煤型城市枣庄2013年春季五个观测点PM2.5及四种水溶性阴离子浓度水平,并进行了污染特征分析.     

文冠果外皮对水体中锌的去除研究

生物吸附法是最经济有效的去除水体重金属污染的方法.为研究文冠果外皮对水环境中的锌离子的去除效率和去除机理,本文以文冠果外皮为吸附剂,研究了溶液pH值、吸附动力学、锌离子浓度、吸附剂投加量对水溶液中锌的吸附量与去除率的影响;通过模型拟合、离子交换实验和远红外光谱分析(FTIR),对吸附机理进行了探讨.结果表明:文冠果外皮是一种理想的锌吸附剂:适应pH值范围宽(3～6),达到吸附平衡时间短(30 min),吸附容量大(最大值为18.656 mg.g-1),去除效率高(60%～90%);吸附过程符合伪二级动力学模型和Langmuir等温吸附模型.离子交换实验和远红外波普扫描分析表明离子交换和络合反应是主要吸附机理,主要的交换离子为K+,Ca2+,Mg2+和Na+,参与络合、螯合反应的官能团主要有-OH、-NH、-COO-、-C=O.     

卤素离子在Ti/nano TiO2-Pt电极上的电化学行为

采用电化学合成法和电沉积法制备高活性纳米TiO2-Pt修饰电极(Ti/nanoTiO2-Pt电极),用循环伏安法和线性扫描法研究了卤素离子在Ti/nanoTiO2-Pt电极上的电化学行为,以及离子液体([EMI]BF4)中卤素离子的电化学行为,并与Ti/nanoTiO2和石墨电极进行比较.结果表明,Ti/nanoTiO2-Pt电极对卤素离子有显著的电催化活性,Epa=0.94V,ΔEp=0.098V,Ipa/Ipc=1,为准可逆电极过程.     

结构动力方程的精细积分-FFT方法

 离散结构动力方程为差分方程,并假设始、末时刻位移已知,将初值问题形式上转化为边值问题,然后利用快速傅立叶变换(FFT)进行求解,从而得到非齐次结构动力方程的一个数值特解。将该数值特解与通过精细积分法求得的齐次方程通解相结合,建立了求解结构动力方程的一种新方法。该方法具有较高的精度和计算效率,算例的数值结果证明了本文方法的有效性。     

High resolution imaging using scanning ion conductance microscopy with improved distance feedback control

Microscopy is an essential technique for observation on living cells. There is currently great interest in applying scanning probe microscopy to image-living biological cells in their natural environment at the nanometer scale. Scanning ion conductance microscopy is a new form of scanning probe microscopy, which enables non-contact high-resolution imaging of living biological cells. Based on a scanned nanopipette in physiological buffer, the distance feedback control uses the ion current to control the distance between the pipette tip and the sample surface. However, this feedback control has difficulties over slopes on convoluted cell surfaces, which limits its resolution. In this study, we present an improved form of feedback control that removes the contribution of up to the third-order slope from the ion current signal, hence providing a more accurate signal for controlling the distance. We show that this allows faster and lower noise topographic high-resolution imaging.     

Analysis of the design methods of word oriented linear feedback shift registers

Based on analysis of the structure characteristics and implementation methods of some representative word oriented linear feedback shift registers （LFSRs） in several modem software oriented stream ciphers, this paper firstly classifies the word oriented LFSRs into two classes： the machine instruction type and the arithmetic type. The similarities and differences between each type are illustrated by concrete examples. Then we give a detailed analysis about the word oriented LFSRs in each category from design structure, cryptographic properties and implementation issue aspects. Finally, some basic design criteria for modem word oriented LFSRs and suitable for software implementation are summarized.     

半夏组织培养研究

半夏采用块茎、叶片、叶柄为外植体进行组织培养均可诱导成苗.块茎在培养基1.0mg/L 6-BA+0.1mg/L NAA中诱导率高为96.7%,在培养基2.0mg/L 6-BA+0.1mg/L NAA中增殖倍数高为8.5倍.叶片、叶柄在培养基3.0mg/L 6-BA+0.5mg/L NAA中小块茎的诱导率较高达86.7%,在培养基2.0mg/L 6-BA+0.1mg/L NAA中增殖倍数较高为5.4倍.半夏试管苗在增殖培养中同时分化出根,可免去诱根环节.     

基于有理函数的高速轧机角接触球轴承接触角曲面拟合

利用有理函数拟合方法,在轴向力和转速变化的条件下对轴承接触角的变化进行曲面拟合,得出函数表达式,并对实例进行了分析。     

大采高综采工作面过宽断面空巷技术研究

通过对02215综采工作面过20102回撤通道的支护设计、矿压情况、劳动组织和回采工艺的阐述,提出了过空巷的工艺。     

一种弧焊机器人熔池图像的快速标定方法

为了获得弧焊机器人焊接过程中熔池的几何尺寸,须在焊接过程中采用摄像机采集熔池图像,并完成系统的标定.将摄像机模型考虑为理想针孔透视模型,采用固定角度和高度对熔池图像进行采集,使标定模型参数缩减至8个,和传统标定方法相比,大大降低了计算量.采用同一平面4个目标点进行了系统标定和实验,理论和实际熔宽平均误差为0.031 mm,因此应用该方法对弧焊机器人熔池图像进行标定是可行的.