掺杂Fe3+的纳米TiO2光催化降解氮氧化物研究

利用Fe(NO3)3*9H2O,采用浸渍的方法,制备了掺Fe3+的纳米TiO2.讨论了此种纳米TiO2对氮氧化物的光催化效率,并分析了Fe3+在催化过程中的作用.试验结果表明:Fe3+明显提高了纳米TiO2的光催化性能;在室内自然光作用下对较高质量浓度的氮氧化物均具有较高的光催化效率.通过对TEM照片和XRD谱的分析,从能级理论解释了Fe3+提高催化活性的原因.     

Measurements of leucocyte membrane elasticity based on the optical tweezers

A 1-μm in diameter polystyrene bead coated with lectin is trapped by optical tweezers whics is formed by a focused laser beam (740nm).A leucocyte adhered to the bottom of sample cell is chosen to close to the trapped bead.When their stable combination is confirmed,the leucocyte is displaced by moving the sample stage.A“tether”is then formed between the trapped bead and the membrane.The force acting on the tether is measured by a detector equipped on the optical tweezers system.The deformation of the membrane is diverse in different contact conditions.When the contact area is small,the tether is very thin and the force on it is 7.4pN(10^-12N),while the tether is much thicker under a larger contact area and its corresponding force is about 14pN.It is presumed that the latter is related to the deformation of cytoskeleton.     

Mechanical Studies on Treatment of Malignant Tumour by Ultralow Frequency Pulsed-Gradient Magnetic Fields

Ultralow frequency (ULF) pulsed-gradient magnetic field (with the maximum intensity of 0.6-2.0 T, gradient of 10-100 T·m-1, pulse width of 20-200 ms and frequency of 0. 16-1. 34 Hz) treatment of mice can inhibit murine malignant tumour growth and can induce apoptosis of cancer cell. The apoptotic cancer cell contracted, became rounder and divorced from adjacent cells; the heterochromatin condensed and coagulated together along the inner side of the nuclear membrane; the endoplasmic reticulums expanded and fused with the cellular membrane; many apoptotic bodies which were packed by the cellular membrane appeared and were devoured by some lymphocytes and plasma. By Lorentz force the magnetic field keeps the moving ions within bounds of Larmor radius. Thus, penetrating capability of the positive and negative ions through the cell membrane was affected, even the role on the cell membrane formed.     

PI/TiO2纳米复合膜的H2/CH4和H2/N2分离性能

以可溶性聚酰亚胺为基质 ,经乙酸修饰后的钛酸丁酯为TiO2 溶胶前体 ,NMP为共溶剂 ,采用溶胶凝胶法可制得PI/TiO2 纳米复合膜。采用XPS、TEM和气体透气性能测试等手段 ,对复合膜的结构和H2 分离性能进行了表征。结果表明 ,复合膜中钛酸丁酯已转化为TiO2 ,PI与TiO2 两相结合完好。TiO2 以颗粒状均匀分布在PI基质中 ,其颗粒粒径约为 1 0nm。复合膜的H2 ,N2 和CH4 透气系数随着TiO2 含量的增加而明显增加。当TiO2 含量为2 2 3 %时 ,对H2 的透气系数为 1 4 .1Barrer,对H2 /N2 和H2 /CH4 的分离系数分别为 1 87.5和 1 4 3 .2 ,因此 ,该复合膜是一种较为理想的H2 分离和回收膜材料     

乳状液膜法提取废水中柠檬酸传质模型的研究

在探讨乳状液膜法提取废水中柠檬酸的基础上，建立了恒界面状况下的非稳态平板传质模型，经过合理假设，推导出易于求解的拟稳态平板传质模型；利用恒界面条件下的实验数据，拟合了拟稳态平板传质模型。     

土工格栅加筋路堤的三维有限元分析

运用通用有限元程序ANSYS ,对软弱地基上路堤加筋的作用和效果进行了三维有限元分析 .计算中采用DP模型模拟土体的材料非线性 ,采用面—面接触单元考虑筋土界面的状态非线性 ,并采用薄膜单元来模拟土工格栅 .通过对相关参数的敏感性分析 ,证明了土工格栅模量对加筋效果有显著影响 ,并且加筋位置靠近路堤底部时更能发挥加筋性能 ;证明了在土体发生显著侧向变形时土工格栅能够发挥抗拉效果 ,从而限制土体侧向变形和路堤外侧土体的隆起 ,达到减小沉降和不均匀沉降的效果 .研究成果对软弱地基路堤加筋处理和新老路基结合部处理均有借鉴意义     

纳滤膜材料及其应用

介绍纳滤膜的特点和制备方法，概述纳滤膜在食品、制药、水处理、染料及冶金行业中的应用，并探讨纳滤膜技术的应用前景。     

悬浮共聚合法制墨粉的粒度特性研究

研究了Fe_3O_4表面改性悬浮共聚合法制备墨粉的工艺,试验了主要因素对墨粉粒度的影响。结果表明,当St/BA为5:1、搅拌速度为1000rpm、超声分散时间为15min、水油比为7:1、PVA用量为4％和聚合温度为85℃时,制备的墨粉粒径为12～13μm,达到了商用墨粉对粒度的要求。图9,表1,参10。     

流体环境中结构附加质量的计算

采用弱耦合法来分析流体与结构的耦合作用,探讨了流体环境中影响结构附加质量的因素,并推导了流体动能的计算方法.文中计算了椭圆柱体和平坦薄膜屋盖的附加质量,得到附加质量对薄膜结构的动力特性有重要影响的结论.     

熔融碳酸盐燃料电池阴极材料制备与导电性

研究了熔融碳酸盐燃料电池（MCFC）阴极材料锂铁氧化物电极的导电性能。实验结果表明在合成锂铁氧化物的过程中，使Li2CO3轻微过量，可以提高锂铁氧化物电极的导电性。在同一温度下，随着Li:Fe值的增大，锂铁氧化物电极的导电性增加。相同Li:Fe条件下，锂铁氧化物电极的导电性随着温度升高按指数规律增加。扫描电镜研究（SEM）表明，Li:Fe比值不同，制备的锂铁氧化物电极表面形貌也不同。