Microstructure and oxidation resistance of SiC–MoSi2 multi-phase coating for SiC coated C/C composites

In order to improve the anti-oxidation of C/C composites, a SiC–MoSi2multi-phase coating for SiC coated carbon/carbon composites(C/C)was prepared by low pressure chemical vapor deposition(LPCVD) using methyltrichlorosilane(MTS) as precursor, combined with slurry painting from MoSi2 powder. The phase composition and morphology were analyzed by scanning electron microscope(SEM) and X-ray diffraction(XRD) methods, and the deposition mechanism was discussed. The isothermal oxidation and thermal shock resistance were investigated in a furnace containing air environment at 1500 1C. The results show that the as-prepared SiC–MoSi2coating consists of MoSi2 particles as a dispersing phase and CVD–SiC as a continuous phase. The weight loss of the coated samples is 1.51% after oxidation at 1500 1C for 90 h, and 4.79% after 30 thermal cycles between 1500 1C and room temperature. The penetrable cracks and cavities in the coating served as the diffusion channel of oxygen, resulted in the oxidation of C/C composites, and led to the weight loss in oxidation.     

Cloning,sequencing of the HSC70 gene in Ctenopharyngodon idella

A cDNA encoding heat shock cognate protein 70(HSC70)was cloned from liver of grass carp(Ctenopharyngodon idella)(GenBank JF436930).This cDNA was found out to contain2 346 bp in length,including 1 950 bp of complete coding sequence encoding 649 amino acids(aa),plus 89 bp of 5′-UTR and 307 bp of3′-UTR.Analysis of its genomic structure revealed that its corresponding gene contained seven exons and six introns.Homology analysis indicated that it shared 99%of identity with HSC70 of breams and 86%of identity with HSP70 of Drosophila.Fluorescent RT-PCR analysis revealed that at 28℃,this gene was expressed in abdominal fat,muscle,intestines,brain,middle kidney,head kidney,gonads,swim bladder,liver,heart,spleen,gills,and fins with expression level in liver being the highest(p0.05),followed by that in the gonads;at 36℃,its mRNA expression level was increased at first but then decreased thereafter under heat shock stress,indicating that its expression can be regulated by heat shock.In conclusion,cloning and expression analysis identified a cDNA encoding a constitutive HSP70 gene that is expressed in many tissues of Ctenopharyngodon idella and its expression was down-regulated by heat shock.     

脉冲冲击波有效作用距离影响因素模拟分析

利用数值模拟方法,分析储能、作业次数、弹性模量、地应力对重复脉冲冲击波有效作用效果的影响。结果表明:低储能时无法致裂储层,以解堵为主,高储能时可以使储层产生微裂缝提高渗透率;随着作业次数的增加,冲击波有效作用距离不断增加至最大值,此后再增加作业次数,有效作用距离基本不变;地应力对有效作用距离影响比较明显,随着地应力的增加,有效作用距离呈对数规律减小;在地应力较小、弹性模量较大时,随着作业次数增加有效作用距离增大,但试验表明作业次数增加会使储层软化,减小弹性模量,降低冲击波作业效果;当地应力较大时,弹性模量和作业次数对有效作用距离基本无影响,因此重复强冲击波对弹性模量大、地应力小的储层解堵、增产、增注效果较好,且存在一个合理的冲击波作业次数。实际应用时应根据储层参数选井,优化冲击波作业参数。     

铝热剂填充改性PTFE/Al含能材料实验研究

为了提高PTFE/Al含能材料的力学特性,利用铝热剂对零氧配比的PTFE/Al含能材料进行了填充改性,并对改性后的含能材料进行了准静态压缩实验,获得最优配比.利用最优配比制备了含能破片,采用25 mm口径弹道炮进行发射,通过高速摄影仪记录破片的冲击过程.试验结果表明,改性后的PTFE/Al力学强度约为纯PTFE/Al的1.3倍,在1 084~1 667 m/s的撞击速度下伴有猛烈的爆炸作用,证明新材料具有可靠的冲击起爆特性,穿甲孔径比为1.91~2.54.     

Fracture behavior and microstructure analysis of Al2O3–MgO–CaO castables for steel-ladle purging plugs

Three different castables based on the Al₂O₃–MgO–CaO system were prepared as steel-ladle purging plug refractories: corundum- based low-cement castable (C-LCC), corundum-spinel-based low-cement castable (C-S-LCC), and corundum-spinel no-cement castable (C-S-NCC) (hydratable alumina (ρ-Al₂O₃) bonded). The fracture behavior at room temperature was tested by the method of “wedge-splitting” on samples pre-fired at different temperatures; the specific fracture energy G′_f and notched tensile strength σ_NT were obtained from these tests. In addition, the Young’s modulus E was measured by the method of resonance frequency of damping analysis (RFDA). The thermal stress resistance parameter R′′′′ calculated using the values of G′_f, σ_NT, and E was used to evaluate the thermal shock resistance of the materials. According to the microstructure analysis results, the sintering effect and the bonding type of the matrix material were different among these three castables, which explains their different fracture behaviors.     

核矩阵协同进化的震荡搜索粒子群优化算法

针对粒子群算法搜索后期易陷入局部极值的缺点,提出一种基于核矩阵协同进化的震荡搜索粒子群优化(kenel matrix synergistic evolution shock search particle swarm optimization,KMSESPSO)算法,该算法对粒子进行局部与全局结合的震荡搜索,且当整个粒子种群陷入停滞状态时,利用核矩阵对特定粒子组进行协同进化以扩大种群的多样性.实验结果表明,KMSESPSO算法有效提高了粒子的全局搜索能力,既避免粒子种群易早熟收敛,又较好地提高寻优精度、加快收敛速度,且有一定的鲁棒性.     

环氧丙烷复合燃料冲击点火的微观研究

利用多种光谱技术提出了一种确定复合燃料冲击点火延迟时间和临界条件的新方法。先用谱仪确定燃料各组分冲击点火最早出现的中间产物,对于环氧丙烷复合燃料中,环氧丙烷氧原子辐射总是先出现;对于硝酸丙酯,NO2辐射总是先出现;而铝反应先形成AlO;把三台单色谱仪分别调至O、NO2、AlO波长处,并利用压力传感器测得冲击波到达样品的时间便可确定环氧丙烷复合燃料冲击点火延迟时间。这种方法比国内外常用光电二极管(峰值波长约在800nm)的结果更接近实际值。环氧丙烷复合燃料受冲击后,冲击点火临界压力Pc=1．25MPa,点火延迟时间为8μs。     

石墨渗铜喉衬材料的抗热震性能与烧蚀微观结构研究

对粗粒级高强石墨加压渗铜制备的石墨渗铜喉衬材料的微观结构与抗热震性能的关系进行了研究,结果表明渗铜提高了原石墨的导热系数及整体增韧的综合效果。对热试车后的石墨渗铜喉衬进行烧蚀微观结构及能谱分析研究,得到了铜的分布情况与烧蚀性能的关系。     

聚能射流引爆炸药的数值模拟研究

采用显式有限元程序对聚能射流引爆裸露和带壳装药的过程进行了数值模拟分析。分析了射流引爆裸露装药和带壳装药两者间的不同作用过程,对射流引爆炸药的现象进行了探讨。结果表明,聚能射流引爆裸露装药取决于射流本身特性参数,而引爆带壳装药则与壳体性质密切相关。     

联系激波及其传播介质的无穷维动力学系统(英文)

导出了描述行星际激波及其非齐次传播介质间关系的无穷维动力学系统 ,将行星际激波求解化为涉及背景物理场的一组常微分方程组。理论上讲 ,借助数值求解该常微分方程组便可得到有关激波的主要信息 ,结果将为行星际激波求解提供便捷的途径。