二元羧酸对草酸钙结晶的调控作用

采用双扩散法系统研究了凝胶体系中二元羧酸对尿结石主要成分草酸钙结晶的影响,这些羧酸分别为含有0、1、2个羟基的丁二酸、羟基丁二酸、酒石酸,含有1个氨基的L-天冬氨酸,以及含有双键的顺丁烯二酸、反丁烯二酸．对于丁二酸、羟基丁二酸和酒石酸的研究表明,随着羧酸中羟基数目的增加,抑制一水草酸钙(COM)聚集和诱导二水草酸钙(COD)生成的能力逐渐增强;随着羧酸浓度的增大,抑制COM聚集和诱导COD生成的能力也增强;随着结晶时间的增加,COM晶体钝化程度加深．对L-天冬氨酸、顺丁烯二酸和反丁烯二酸的研究表明,三者影响不明显．     

Real time monitoring of nucleic acids ligation based on molecular beacon

The replication, ligation and repair of nucleic acids are essential life processes that based the survival, pro-creation and evolution of creatures. These interactions involving proteins (enzymes) and nucleic acids have fas-cinated great interest of scientists[1]. The nucleic acids ligation has been revealed that it is catalyzed by ligase and co-enzyme (ATP or NAD)[2—4]. Along with in-depth re-search, the nucleic acids ligation becomes a significant and common tool employed in bioengineerin…     

Photo Catalytic Oxidation of Alcohols in Water under Natural Weathering Conditions in the Presence of Bromo Source

1 Results The oxidation of alcohols into the corresponding carbonyl compound is one of the most important functional group transformation in organic synthesis[1]. Traditionally,such transformations have been performed with stoichiometric inorganic oxidant or other high valent metal oxidant[2]. Despite a variety of systems for the catalytic oxidation of alcohols have been developed,there is ongoing interest in the search for new efficient and environmental friendly oxidation system.To the best of our kno...     

新型二异羟肟酸配合物催化PNPP水解的动力学研究

以3种含中心功能基(-OCH3)的二异羟肟酸开链冠醚过渡金属铜(Ⅱ)、锌(Ⅱ)和钴(Ⅱ)配合物作为水解酶模型,催化羧酸酯(PNPP)水解;研究了水解反应的动力学和机理,提出了水解反应的动力学模型。结果表明:在室温25℃条件下,这类配合物催化PNPP水解速率随着缓冲溶液pH值的增大而提高,表现出高的催化活性。     

河蚬软体部分营养成分分析及评价

通过对河蚬软体部分营养成分分析,综合评定其营养价值.结果表明:河蚬软体部干样中,粗蛋白、粗脂肪、灰分含量分别为63.33%、10.91%、6.29%;必需氨基酸占氨基酸总量的39.10%,各必需氨基酸中平均氨基酸分为88.9,第一限制氨基酸为Leu(1973年FAO/WHO标准);并富含钙、钠、钾、铁等无机元素.认为河蚬是一种营养价值较高的贝类.     

N,N-二甲基甲酰胺二异丙基缩醛对羧酸酯化反应的研究

以N，N－二甲基甲酰胺二异丙基缩醛（简称DMFDIPA）为异丙基化试剂对一些羟酸进行酯化反应。实验表明，DMFDIPA与脂肪酸和芳香酸（高位阻酸除外）都可以发生酯化，酸的强度对反应影响不大。     

Ferric chloride-catalyzed decarboxylative alkylation of β-keto acids with benzylic alcohols

β-Keto acids are unstable to heat,acids,and bases,and have rarely been employed as carbon nucleophiles for the formation of carbon-carbon bonds.In this context,an efficient decarboxylative alkylation reaction of β-keto acids with benzylic alcohols has been developed,for the first time,through sequential cleavage of carbon-oxygen and carbon-carbon bonds.In the presence of 10 mol% of ferric chloride,a range of β-keto acids smoothly undergo decarboxylative alkylation with benzylic alcohols to give structurally diverse unsymmetric ketones in moderate to excellent yields and with extremely high regioselectivity.Preliminary mechanistic studies indicate that the reaction proceeds through an SN1 alkylation followed by decarboxylation.     

抗性淀粉的生物学功效及在食品加工中的应用

抗性淀粉是一种具有多种生物学功效的新型膳食纤维,且兼具类似于淀粉的优良加工特征,适合于开发品种多样的高膳食纤维功能性食品。抗性淀粉的研究与应用目前已成为国内外食品行业的热点,介绍了抗性淀粉的分类,及其在糖代谢、脂代谢、体重控制,作为益生元和防治直肠癌方面的生物学功效;分析了抗性淀粉在面包糕点、油炸食品、面条、益生菌类食品加工领域中的应用。     

羧酸类有机锡化合物合成及结构研究概况

羧酸类有机锡化合物的合成规律和结构特点,是目前此类化合物研究的热点问题之一。概述了一烃基锡羧酸酯、二烃基锡羧酸酯和三烃基锡羧酸酯合成及其结构的研究现况。     

环烷酸氨皂W/O微乳液的相行为及溶水性能

绘制了环烷酸／煤油／氨水体系的部分拟三元相图，研究了几种醇（助表面活性剂）和几种常见的强酸强碱盐及其浓度，溶剂对环烷酸氨皂Ｗ／Ｏ型微乳液溶水性能的影响。