Transition-metal-doped Fe2O3 nanoparticles for oxygen evolution reaction

Hematite(α-Fe_2O_3)has been extensively studied as a promising photocatalyst,with the capacity to split water under visible light.To tune its electronic structure and improve the performance for oxygen evolution reaction(OER),high-quality single crystals ofα-Fe_2O_3nanoparticles were synthesized and doped by various transition metals(M=V,Cr,Mn,Zn,Co,Ni,Cu,Nb,Mo,Ti)by a molten-salt flux method.Optical,electronic and catalytic properties of transition-metal-dopedα-Fe_2O_3(TM-dopedα-Fe_2O_3)have been systematically investigated.Cobalt has been identified as the best dopant forα-Fe_2O_3,reducing the OER overpotential by 0.16 V with respect to the undoped.     

WO3 nanoflakes decorated with CuO clusters for enhanced photoelectrochemical water splitting

The low quantum efficiency arising from poor charges transfer and insufficient light absorption is one of the critical challenges toward achieving highly efficient water splitting in photoelectrochemical cells. Three dimensions(3D) structures and heterojunctions have received intensive research interests recent years due to their excellent ability to separate photo-generated charges as well as the enhanced light harvesting property. Herein,3 D Cu O/WO_3 structure was fabricated through a facile solvothermal method followed by chemical bath deposition. The loading of Cu O clusters on WO_3 nanoflake arrays results in a much improved photocurrent density compared with that of pristine WO_3 nanoflake arrays, which reaches 1.8 m A/cm2 at 1.23 V vs. the reversible hydrogen electrode. The electrochemical impedance spectroscopy measurement demonstrates that the improved performance of Cu O/WO_3 electrode is attributed to the accelerated charge transfer kinetics as a result of the desirable band alignment in Cu O/WO_3 heterojunction. This work demonstrates a facile strategy to construct superior WO_3 electrode, which will ultimately allow for efficient storage of solar energy into hydrogen.     

基于谱域球谐展开的多层快速多极子算法

介绍了基于谱域球谐函数展开的多层快速多极子算法,通过处理三维金属体的散射问题,验证了算法参数选取的经验公式,并对算法性能做出了理论分析,得出该算法具有内存占用少﹑迭代速度快的优点,数值结果显示了该方法的高效性.     

随机比例方程的波形松弛方法

将波形松弛方法应用到随机比例方程.在分裂函数满足单边Lipschitz条件和全局Lipschitz条件下,给出波形松弛方法的误差估计,该误差估计说明此方法是超线性收敛的.完成收敛速度的数值实验,验证了所得理论的正确性.     

级联型多电平变流器控制策略的比较和分析

介绍了阶梯波、载波相移脉宽调制和分段SPWM调制等几种级联型多电平变流器的控制策略,并对它们的优缺点进行了分析和比较,并指出了分段SPWM控制策略是另外两种方法的一种折中方案,它综合了阶梯波和载波相移PWM调制方法的优点,既可以减少开关损耗,又可以使得输出波形性能满足要求.最后给出了几种控制策略产生的输出波形的谐波频谱,验证了分段SPWM方案的可行性和分析的正确性.     

资源均衡问题的峰值最小化模型

将资源峰值作为资源均衡程度的一种度量,以资源峰值最小化为优化目标,分别建立了工序不可分拆、可分拆和有条件分拆的资源均衡问题的整数线性规划模型,通过算例和工程案例验证了模型的有效性,并给出了多种资源情形下资源均衡问题的序贯解法.所建模型不涉及关键路线的确定和非关键工序浮时的计算,且各种资源峰值表述相互独立,因而对部分资源用量受限和对工序开(完)工时间有特殊要求的广义资源均衡问题也有较好的适应性.     

隧道水泥混凝土路面工程质量控制实例分析

通过工程实例，对隧道水泥混凝土路面出现的混凝土劈裂抗拉强度不足的质量问题进行了分析．针对工程实际情况，采取原材料质量控制、配合比调整、施工工艺改进等技术措施，使混凝土的劈裂抗拉强度不足的问题得到较好解决．     

路基沉陷劈裂注浆加固试验

为了探寻一种针对公路路基沉陷的有效处治措施,提高注浆加固的处治效果,优化注浆施工工艺,在邵怀高速公路典型路基沉陷成因机理分析的基础上,采用劈裂注浆法对路基沉陷进行了处治技术试验研究,并进行了注浆工程的数值模拟和基于FWD检测技术的注浆效果评价.研究结果表明,注浆压力随时间的增长整体呈现波动上升趋势,劈裂注浆加固最优注浆压力为1.2MPa.FWD检测结果表明,本研究提出的竖向花管注浆及水平花管注浆方案的注浆效果良好,能够有效处治路基沉陷病害.     

N-水杨酰胺与磷酰二氯反应产物的~1HNMR鉴定

本文用~1HNMR分析方法,对由N—(杂环基甲基)水杨酰胺与(硫代)磷酰二氯关环反应的产物结构的鉴定进行了讨论。     

M－矩阵的图相容分裂

在这篇文章里，首先我们得到了一个使得图相容分裂与正则分裂等价的充要条件。其次，我们也得到Ｍ－矩阵的正则分裂是图相容分裂的必要条件和充分条件。