氧电极催化剂的组成对H2O2分解活性的研究

以CuCl2和FeCl3原料，采用NaOH溶液中沉淀，并将沉淀物在空气中加热、氧化一还原、脱水的方法，制备不同Cu：Fe氧化物的催化荆(X=0．5、1．0、1．5、2．0、2．5、3．0)，分别以各催化剂在其他条件相同的情况下，催化分解H202，测定各反应的速率常数。并进行对比，以K对X作图表示活性与配比的关系。得出Cu，Fe3-xO4 Cu：Fe(X=2．5)时催化活性最高。     

Cryptomelane（KxMn8-xO16）： Natural active octahedral molecular sieve（OMS-2）

The Xiangtan manganese deposit (XTM) used to be considered a supergene oxide manganese ore in South China. We reported a new identification of the naturally outcropping cryptomelane by examining the physical, chemical and structural features of the XTM supergene oxide manganese ore. The MnO2 content was over 90%, K2O more than 3%, and water from 2.2%-3.1% which is similar to one in zeolite. The cell parameters of the cryptomelane were given as a0 = 0.9974 nm, b0 = 0.2863 nm, c0 = 0.9693 nm and β= 91.47°. There was a larger pseduotetragonal tunnel in the natural cryptomelane that was formed by [MnO6] octahedral double chains with aperture of 0.462×0.466 nm2, filled with K cations resulting in some Mn3+ substituting for Mn4+ to balance the negative charges of structure. The finding is important not only for prospecting manganese resources in South China, but also in application of octahedral molecular sieve of natural cryptomelane as that developed in the tetragonal molecular sieve of natural zeolite o     

Initial organic geochemical investigation on Late Neoproterozoic-Early Cambrian sediments in the Yangtze region, China

Totally 19 samples of typical Upper Proterozoic-Lower Cambrian sedimentary rocks were collected and analyzed for an organic geochemical investigation. Almost all these rocks have high TOCs, super-maturities and similar biomarker distribution. As an exception, however, the Sinian Nantuo Tillite shows much lower TOCs and little phytane and pristane in comparison with those in other strata, which implies a very faint photosynthetic process, and a restricted euphotic zone and quite limited sunlight within the sedimentary water column during the Sinian glaciation age in the western Yangtze region providing an evidence for palaeo-oceanic environment of the Neoproterozoic Snowball Earth age.     

Design and application of 60mer oligonucleotide microarray in SARS coronavirus detection

In April 2003, a novel coronavirus[1,2] which was associated with cases of Severe Acute Respiratory Syn-drome (SARS) was first isolated and sequenced in Canada. The genome of SARS coronavirus (SARS-CoV) is 29727[3] nucleotides in length and has 11 known open reading frames (ORFs). Although the genome organiza-tion of this virus is similar to that of other coronaviruses, phylogenetic analyses and sequence alignment show that SARS-CoV is not closely related to any of the previously ch…     

DNA分子标记在果树上的应用

介绍了在果树上常用的DNA分子标记的原理和特点，并对其在果树的分子遗传图谱和指纹图谱的构建，品种鉴别、系谱分析和分类，基因定位与分子标记辅助选择等方面的应用进行了综述。     

对混炼型聚氨酯弹性体生胶可塑度影响因素的探讨

详细论述了混炼型聚氨酯弹性体(MPU)的加工过程和特性，通过实验指出了生胶可塑度与MPU的加工过程和质量有密切的关系，影响可塑度的因素有生胶中硬链段的含量、聚酯二醇的结构和生胶的分子量。     

贫燃条件下钙钛矿型催化剂上C_3H_6催化还原NO_x反应的研究

利用柠檬酸络合法制备钙钛矿型复合氧化物 L a0 .8Ce0 .2 Co XFe1- XO3催化剂 ,研究其在贫燃条件下 NOX 的催化还原性能 .实验表明 :在没有水蒸气存在的条件下 ,在 30 0°C时 ,La0 .8Ce0 2 Co O3催化剂上 NOX 的转化率可达 46.8%,这时还原剂丙稀已完全氧化 ;但在水蒸气存在下 ,La0 .8Ce0 2 Co O3催化剂上 NOX的转化率明显下降 ,同时丙稀的完全氧化温度也上升5 0°C～ 1 5 0°C,这主要是由于水蒸气对反应活性中心竞争吸附的缘故 ;而双取代的催化剂La0 .8Ce0 2 Ce0 .2 Fe0 .8O3和 La0 .8Ce0 2 Co0 .8Fe0 .2 O3催化剂具有相当的催化活性和较好抗水蒸气能力 ,这可能是由于 Ce O2 和 Co Fe O3之间的协同作用增加了氧空位 ,从而弥补了由于水蒸气竞争吸附所导致的活性下降     

昆虫病原真菌分子生物学研究进展

本文综述了用现代分子生物学技术研究昆虫病原真菌的进展。其内容包括利用原生质体融合、基因工程等技术进行菌株遗传改良和利用酶谱分析、分子遗传学等技术研究其遗传变异。     

[Cu2(bpa)2(phen)2(H2O)]2·H2O的合成和晶体结构

利用线形的芳香二羧酸与邻菲啉铜盐在水热的条件下合成一种新型的分子块化合物,这种分子块通过位于钝角位置的邻菲啉配体的芳香pp-识别作用自组装成第一例由菱形分子块的自组装形成二维多聚轮烷, 这种二维的层状结构通过邻菲啉配体的芳香pp-堆积作用形成具有独特拓扑结构的三维网络结构。     

pH电位法测定咪唑及其衍生物与Cu(Ⅱ)配位反应的各级稳定常数

文中利用pH电位法，在25℃，0.1mol/L KCl存在的条件下，通过测定咪唑、苯并咪唑、2-甲基苯并咪唑、2-乙基苯并咪唑和2- 丙基苯并咪唑与二价铜离子络合反应时溶液酸度值的变化，分别求算出了五种物质的加质子常数及配位反应的各级稳定常数。