Conductive and corrosion behaviors of silver-doped carbon-coated stainless steel as PEMFC bipolar plates

Ni–Cr enrichment on stainless steel SS316L resulting from chemical activation enabled the deposition of carbon by spraying a stable suspension of carbon nanoparticles; trace Ag was deposited in situ to prepare a thin continuous Ag-doped carbon film on a porous carbon-coated SS316L substrate. The corrosion resistance of this film in 0.5 mol·L-1 H₂SO₄ solution containing 5 ppm F- at 80℃ was investigated using polarization tests. The results showed that the surface treatment of the SS316L strongly affected the adhesion of the carbon coating to the stainless steel. Compared to the bare SS316L, the Ag-doped carbon-coated SS316L bipolar plate was remarkably more stable in both the anode and cathode environments of proton exchange membrane fuel cell (PEMFC) and the interface contact resistance between the specimen and Toray 060 carbon paper was reduced from 333.0 mΩ·cm2 to 21.6 mΩ·cm2 at a compaction pressure of 1.2 MPa.     

Effects of Fe content on the microstructure and properties of CuNi10FeMn1 alloy tubes fabricated by HCCM horizontal continuous casting

Heating-cooling combined mold (HCCM) horizontal continuous casting technology developed by our research group was used to produce high axial columnar-grained CuNi10FeMn1 alloy tubes with different Fe contents. The effects of Fe content (1.08wt%–2.01wt%) on the microstructure, segregation, and flushing corrosion resistance in simulated flowing seawater as well as the mechanical properties of the alloy tubes were investigated. The results show that when the Fe content is increased from 1.08wt% to 2.01wt%, the segregation degree of Ni and Fe elements increases, and the segregation coefficient of Ni and Fe elements falls from 0.92 to 0.70 and from 0.92 to 0.63, respectively. With increasing Fe content, the corrosion rate of the alloy decreases initially and then increases. When the Fe content is 1.83wt%, the corrosion rate approaches the minimum and dense, less-defect corrosion films, which contain rich Ni and Fe elements, form on the surface of the alloy; these films effectively protect the α-matrix and reduce the corrosion rate. When the Fe content is increased from 1.08wt% to 2.01wt%, the tensile strength of the alloy tube increases from 204 MPa to 236 MPa, while the elongation to failure changes slightly about 46%, indicating the excellent workability of the CuNi10FeMn1 alloy tubes.     

Thermodynamic simulation of the effect of slag chemistry on the corrosion behavior of alumina–chromia refractory

The corrosion behavior of alumina–chromia refractory against two kinds of industrial slags (coal slag and iron smelting slag) at 1550°C was investigated via thermodynamic simulations. In the proposed simulation model, the initial slag first attacks the matrix and surface aggregates and subsequently attacks the inner aggregates. The simulation results indicate that the slag chemistry strongly affects the phase formation and corrosion behavior of the refractory brick. Greater amounts of alumina were dissolved and spinel solid phases formed when the brick interacted with iron smelting slag. These phenomena, as well as the calculated lower viscosity, may lead to much deeper penetration than that exhibited by coal slag and to more severe corrosion compared to that induced by coal slag. The thermodynamic calculations well match the experimental observations, demonstrating the efficiency of the proposed simulation model for evaluating the corrosion behavior of alumina–chromia refractory.     

乳品废水厌氧发酵生化指标变化的研究

通过厌氧发酵对乳品加工废水处理过程中的生化指标测定,找出影响因素,并进行较为系统的分析和研究。主要影响因素有温度、泥水比、发酵时间,它们在一定的范围内对乳品废水厌氧发酵、降解有机物有较大的影响。试验通过厌氧发酵对乳品废水进行处理,探寻出各单因素对乳品废水厌氧发酵的影响,找出最佳处理结果,得出各因素的合理组合,从而优化乳品废水厌氧发酵的工艺条件。     

金属、涂饰层材料长周期海水腐蚀试验工作进展

介绍了50种金属和12种涂镀层材料在我国的青岛、舟山、厦门和榆林四个海域的飞溅、潮差、全浸三个海洋区带中暴露1、2、4、8和16年的长周期工作,得到了长周期的海水腐蚀数据和长周期的海水腐蚀规律。提出一种海水腐蚀性的评价方法和一种综合评价材料耐蚀性的方法。此外,解释了在海水腐蚀试验中的一些异常现象。     

基于二维条码的酒类防伪系统设计与研究

为了满足白酒生产企业的防伪需求,设计了以加密二维条码标签为信息载体,从源头和流通环节杜绝伪劣假冒白酒的解决方案。针对现有的白酒防伪标识存在的问题,分析了二维条码技术在酒类防伪中的优越性,提出以数字密码锁和酒款级密钥分别加密防伪码和二维条码编码的双重加密方案及完整的酒类防伪业务流程,并详述了二维条码白酒防伪系统的总体设计和部署。经实践检验,该方案能满足白酒产品可靠性、实效性、方便性、经济性的防伪需求。     

水布垭大坝左岸岩溶发育规律及渗透性分析

利用水布垭大坝左岸山体灌浆平硐现场的调查结果,对防渗帷幕线剖面不同高程灌浆平硐的面溶蚀率和最大溶蚀洞径进行分区统计分析,获得了防渗帷幕线剖面岩体溶蚀特性．在此基础上,结合区域地质资料和地貌资料,得出大坝左岸山体岩溶发育规律．左岸山体岩溶发育在垂直方向从上到下逐渐减弱,水平方向从远河岸端向近河岸端逐渐增强,存在集中发育区并受岩层面控制等．最后对山体的渗透性进行了探讨,提出帷幕工程优化的初步建议。对大型溶蚀洞穴系统进行封堵后,帷幕灌浆时应对不同地区分别对待,有些地带可以简化帷幕施工,甚至可以不进行帷幕施工。     

挤压铸造制备三维连续网络结构增强金属基复合材料

基于真空反压浸渍多孔陶瓷获得一种新型三维连续网络结构增强的金属基复合材料的基础上,采用挤压铸造的方法对这种新型结构金属基复合材料的制备方法作进一步研究．以Ａｌ－ＴｉＯ２－Ｃ系为例,对利用自蔓延高温合成方法（ＳＨＳ）制备的Ａｌ２Ｏ３－ＴｉＣ多孔连通网络陶瓷骨架进行挤压铸造Ｌｙ１２Ａｌ合金液获得这种复合材料,并利用扫描电镜、光学显微镜和透射电镜对Ａｌ２Ｏ３－ＴｉＣ多孔陶瓷材料,以及得到的三维连续网络结构增强金属基复合材料的微观形貌特征进行了观察和分析     

食品中胆固醇氧化物研究进展

论述了食品中胆固醇氧化物的研究进展,包括胆固醇氧化物的形成、种类及含量、加工过程中应采取的预防措施以及分析检测方法.引用参考文献29篇.     

用埋设的微型探测器监测不同性能混凝土内的钢筋腐蚀

为了评估钢筋在不同性能的混凝土内的腐蚀程度,腐蚀程度和导致腐蚀的环境,做了一个试验,在试验中使用了微型探测器,将它们贴着钢筋埋设在混凝土内,用它们来测出三种电化学特性值：自然电位;极化电阻和电解质电阻。