确定溶液配合物顺反异构体构型的新方法

本文首次提出了确定溶液含二齿配体的配合物几何顺反异构体构型的新方法,定义了三元配合物MLL′(或ML_2)中ML与ML′(或ML)二跃迁偶极矩分向量之间的夹角θ,作为该配合物中配体L与L′(或L)之间几何因子的量度,当θ≤90°,为顺式异构体;当θ≥120°,为反式异构体;当90°<0<120°,居于顺反异构体之间。我们把单齿配体配合物顺反异构体的定义推广到含两个二齿配体的配合物。而且对配合物内配体之间的空间相对位置作了近似定量化的描述。     

超细Co-γ-Fe_2O_3磁粉的研制

应用TEM、XPS、XRD等分析技术,研究了包钴过程中各种因素对钴改性γ-Fe_2O_3磁粉的微观结构以及磁性能的影响。结果表明,钴铁氧体的形成是Co-γ-Fe_2O_3磁粉磁性能提高的主要原因。包少量钴(钴含量<1%),可使原磁粉的矫顽力提高约6.37kA/m。     

图像分析技术在新材料研制中的应用

文中阐述了图像分析技术在新材料研制中的应用,具体介绍在塑料磁体、聚氨脂泡沫塑料研制中利用该技术对多相体系中分散相形态进行的定量测量。研究结果不但为研制性能优良的制品提供了实验数据,而且为探讨有关机理提供了有益的理论依据。     

Thermally unstable maghaemite and its palaeoclimatic significance in Chinese loess

Magnetite and maghaemite are the two main contributors to magnetic susceptibility in the Chinese loess/palaeosol sequence. Due to the close similarity in physical properties, early investigators treated them together as "magnetite". Utilising the property of thermally instability of maghaemite, we have been able to separate it from magnetite in loess and palaeosol samples from the upper parts of the Xifeng and Luochuan sections on the central Chinese Loess Plateau and compare its variation with depth and horizon. Our results indicate that thermally unstable maghaemite is relatively enriched in both 1) weakly weathered loess units and 2) towards the west, the direction of dust supply, suggesting that maghaemite is at least partially (coarse grains) of detrital aeolian origin while some pedogenic maghaemite (extra fine grains) occurs in the palaeosols. The physical meaning of magnetic susceptibility, therefore, needs to be reconsidered as a synthetic indicator reflecting the palaeoenvironment for both source area and deposition area. Thermally unstable goethite is a minor magnetic component of palaeosol samples, but it may play a significant role in determining characteristic magnetic remanence of weakly weathered loess samples, especially when one applies alternating-field cleaning.     

恒稳磁场效应对多元束配合物体系显色反应影响的研究(Ⅱ)

研究了恒稳磁场效应对W（V）－KSCN－RhB－PVA124体系显色反应的影响,发现在一定范围内,恒稳磁场能显著地提高该多元配合物体系显色反应的灵敏度．在0．05μg／mLW（V）0．7％KSCN,0．05％TiCl31．50mol／LHCl．0．12％PVA1240．0045％的RhB和室温条件下,强度为80mT的恒稳磁场能将最大吸收波长580nm处的显色灵敏度提高65．1％．     

旋转球的动力学分析

角球在飞进中产生了两种压差阻力,在其合力的作用下,球体被迫改变了正常的轨道,从而形成了“香蕉形”的轨迹。     

Functional Materials for Catalytic and Magnetic Applications

1 Introduction Metal, metal oxide and metal compound nanoparticles (NPs) received considerable attention due to their unique properties: catalytic, magnetic, optical, electronic, etc. We believe that for different applications, there are preferable morphologies of NP-stabilizing medium composites. For example, small (1-3 nm) nanoparticles formed in micro/mesoporous hypercrosslinked polystyrene demonstrate excellent catalytic properties in various hydrogenation and oxidation reactions due to high surface...     

磁通轨迹控制法变频技术的仿真研究

本文简要介绍了磁通轨迹控制ＰＷＭ方法的原理及其实现方法，并给出了磁通轨迹控制的ＰＷＭ变频器──异步电机变频调速系统的暂态仿真结果。     

稀土金属合金纳米粒子制备及特性研究

采用直流等离子体电弧法在甲烷，氢氩气氛下制备了钐铁合金的多种纳米粉，在甲烷气氛下没有钐或铁的氧化物生成，反应生成Fe3C，在氢氩气氛下，有钐的氧化物存在，在纯甲烷气氛下制备的样品的矫顽力大，在氢氩氯氛下制备的纳米颗粒的饱和磁化强度和剩余磁化强度高，而且矫顽力也不低。     

图纹结构Co／Pt多层膜的制备及研究

先采用自组装技术制备大面积有序聚苯乙烯微球模板,在此基础上,制备Co／Pt多层膜纳米碗和纳米点列阵样品．利用扫描电子显微镜（SEM）、原子力显微镜（AFM）和透射电子显微镜（TEM）对制备样品的表面形貌进行了分析．结果表明：溅射方法和刻蚀处理对纳米碗和纳米点的形貌存在影响,磁滞回线的结果表明倾斜溅射条件下制备的纳米点阵具有明显的方向取向性．