MgO对硅酸盐水泥熟料形成的影响

在不同的温度下煅烧了含不同 MgO 含量的生料。结果表明,MgO 对硅酸盐水泥熟料形成的影响随煅烧温度及 MgO 在生料中含量的变化而不同。对于一定的生料,存在着最适宜的 MgO 含量范围,在此范围内 MgO 对熟料的形成有最大的促进作用。本文着重以结晶学及相平衡理论对实验结果进行了探讨。     

金属添加剂对MgO－C耐火制品力学性能的影响

在实际生产条件下，研究了Ｍｇ、Ａｌ、Ｓｉ、Ｔｉ、Ｎｉ等金属添加剂及Ｍｇ－Ａｌ、Ｓｉ－Ａｉ－Ｂａ－Ｆｅ等复合金属添加剂对碳结合ＭｇＯ－Ｃ复合耐火制品的抗压、抗折强度的影响。研究结果表明，除Ｔｉ、Ｎｉ外，其它金属添加剂均能改善制品的力学性能，而且添加金属复合物的增强效果优于添加单一的金属粉。试验中还发现，成型压力对制品力学性能有明显的影响。     

Effect of MgO content in sinter on the softening–melting behavior of mixed burden made from chromium-bearing vanadium–titanium magnetite

The effect of sinter with different MgO contents on the softening–melting behavior of mixed burden made from chromium- bearing vanadium–titanium magnetite was investigated. The results show that with increasing MgO content in the sinter, the softening interval and melting interval increased and the location of the cohesive zone shifted downward slightly and became moderately thicker. The softening–melting characteristic value was less pronounced when the MgO content in the sinter was 2.98wt%–3.40wt%. Increasing MgO content in the sinter reduced the content and recovery of V and Cr in the dripped iron. In addition, greater MgO contents in the sinter resulted in the generation of greater amounts of high-melting-point components, which adversely affected the permeability of the mixed burden. When the softening–melting behavior of the mixed burden and the recovery of valuable elements were taken into account, proper MgO contents in the sinter and slag ranged from 2.98wt% to 3.40wt% and from 11.46wt% to 12.72wt%, respectively, for the smelting of burden made from chromium-bearing vanadium–titanium magnetite in a blast furnace.     

Comprehensive recovery of gold and base-metal sulfide minerals from a low-grade refractory ore

The comprehensive recovery of small amounts of valuable minerals such as gold and base-metal sulfide minerals from a low-grade refractory ore was investigated. The following treatment strategy was applied to a sample of this ore: gold flotation–gold concentrate leaching–lead and zinc flotation from the gold concentrate leaching residue. Closed-circuit trials of gold flotation yielded a gold concentrate that assayed at 40.23 g·t-1 Au with a recovery of 86.25%. The gold concentrate leaching rate was 98.76%. Two variants of lead-zinc flotation from the residue—preferential flotation of lead and zinc and bulk flotation of lead and zinc—were tested using the middling processing method. Foam from the reflotation was returned to the lead rougher flotation or lead–zinc bulk flotation, whereas middlings from reflotation were discarded. Sulfur concentrate was a byproduct. The combined strategy of flotation, leaching, and flotation is recommended for the treatment of this kind of ore.     

Diffusion behavior and distribution regulation of MgO in MgO-bearing pellets

In this paper, the diffusion behavior between MgO and Fe₂O₃ (the main iron oxide in pellets) is investigated using a diffusion couple method. In addition, the distribution regulation of MgO in MgO-bearing pellets is analyzed via pelletizing experiments. The results illustrate that MgO is prone to diffuse into Fe₂O₃ in the form of solid solution; the diffusion rate considered here is 13.64 μm·min-1. Most MgO content distributes in the iron phase instead of the slag phase. The MF phase {(Mg_1-x Fe_x)O·Fe₂O₃, x ≤ 1} is generated in the MgO-bearing pellets. However, the distribution of MgO in the radial direction of the pellets is inconsistent. The solid solution portion of MgO in the MF phase is larger in the outer layer of the pellets than in the inner layer. In this work, the approximate chemical composition of the MF phase in the outer layer of the pellets is {(Mg_0.35-0.77·Fe_0.65-0.23) O·Fe₂O₃} and in the inner layer is {(Mg_0.13-0.45·Fe_0.87-0.55) O·Fe₂O₃}.     

分支载体浮选的理论与实践

分支载体浮选(RCF)是一种处理细粒低品位矿石的革新工艺。该工艺采用分支浮选流程并用自身的粗粒精矿取代了常规载体浮选中的外加异类载体矿物。本文研究了黑钨矿、红铁矿、难溶铜、氧化铅锌、铜钼矿和锑砷硫化矿等七种不同矿物的分支载体浮选。和常规方法相比较,分支载体浮选除了可以显著降低药剂消耗,避免载体与超细粒之间的再分离,不需回收载体等,从而解决了常规法中存在的技术问题以外,还能够得到更高的回收率与分选效果。通过浮选试验、动电位测定和电子显微镜观察,进行了分支载体浮选过程机理的研究,结果表明矿泥罩盖的机理已经不适用,提出了新的“碰撞-粘附”模型。在这一模型中,将影响分支载体浮选的因素分为几何、物理、化学三大类并根据实验现象进行了详细的讨论。     

外掺轻烧氧化镁混凝土的膨胀研究

目前用于评定水泥熟料中方镁石安定性的是压蒸法,该方法不适宜用于评定混凝土中轻烧氧化镁(MgO)的安定性。本试验开展80℃水养护条件下外掺轻烧MgO混凝土的膨胀过程研究,并与216℃,2.0MPa压蒸试验结果进行比较,以提出适宜轻烧MgO安定性评定试验方法。研究表明,外掺轻烧MgO混凝土在80℃水养护法的膨胀率比216℃压蒸法的小,抗压强度却比压蒸法的大,80℃水养护比216℃压蒸的混凝土膨胀更接近外掺轻烧MgO混凝土在正常水化条件下的膨胀,因此80℃水养护法比216℃压蒸法更适合于评定混凝土中外掺轻烧MgO的安定性。     

解决氯氧镁水泥制品返卤泛霜的根本途径

通过试验分析了氯氧镁水泥制品返卤泛霜的原因及目前常用的各种改性措施的效果,并找到从根本上解决氯氧镁水泥制品返卤泛霜的方法。     

热固性钼酚醛树脂的合成工艺研究

针对普通酚醛树脂(PF)作为耐火材料结合剂使用中存在的问题，研究了以钼酸改性PF的可行性。由苯酚和甲醛先合成羟甲基苯酚，再用钼酸与羟甲基经酯化反应得到一种新型的热固性钼PF。通过正交试验与结果分析，讨论各因素对合成工艺的影响，并确定了最佳的工艺参数，在n(苯酚)：n(甲醛)：n(H2MoO4)：n(NaOH)=1：1．3：0．06：0．15，反应温度为90℃，反应时间为1h的条件下合成的钼PF残碳率可达56．31％，比一般热固性PF的残碳率高出13个百分点。表明它是比较理想的耐火材料用结合剂。     

(NH4)2SO4浸取轻烧氧化镁的反应动力学

为确定轻烧氧化镁浸取过程的最优控制参数,采用硫酸铵作为浸取剂,考察了浸取体系温度、硫酸铵初始浓度以及轻烧氧化镁颗粒粒度对浸取反应动力学的影响,并得到了宏观反应动力学方程式.结果表明 在一定的浸取剂初始浓度和固体反应颗粒粒度范围内,该浸取反应过程符合Crank-Kinstelin-Browhetein模型; 表观反应活化能为 57.41 kJ/mol, 属表面化学反应控制类型.当硫酸铵与氧化镁初始物质的量之比大于2时,反应过程逐渐由Crank-Kin-stelin-Browhetein模型向减缩核模型过渡.当轻烧氧化镁颗粒初始粒度较大时,浸取反应过程也呈现上述过渡趋势.