CH3NO2+O[3P]→CH2NO2+OH反应途径和速率常数的研究

采用DFT(B3LYP)从头算法,在6-311G**和cc-pvtz基组水平上,优化了CH3NO2 O[^3P]→CH2NO2 OH反应的反应物、过渡态和产物的几何结构,结果表明,基组选择对驻点的几何构型影响很小．由B3LYP／cc-pvtz计算所得的反应位垒为24．52kJ／mol,比实验值22．38kJ／mol大2．14kJ／mol．沿内禀反应坐标(IRC)的分析指出,C—H键断裂和H-O键生成是以协同方式进行的,且在反应途径上存在一个引导反应进行的振动模式,这一振动模式引导反应进行的区间为S=-0．35～0．85(amu)^1/2Bohr;在1300-2100K范围内运用改进的变分过渡态理论(ICIVT)计算出的该反应速率常数与实验结果一致．     

化学发光法研究大白兔外周血巨噬细胞中呼吸爆发随年龄的变化

首次建立了检测兔外周血巨噬细胞化学发光的方法,探索了在不同受体刺激剂,例如刀豆蛋白Con A、PMA、N-FMLP等作用下巨噬细胞化学发光信号的变化。实验表明,巨噬细胞化学发光信号随受体刺激剂浓度的提高增大,并在一定条件下与细胞的浓度成线性关系。化学发光试剂鲁米诺的浓度在5×10^-4mol/L、受体刺激剂的浓度在150μg时化学发光强度最大。4种不同的细胞稀释液中,含1% BSA的HBSS用于化学发光的缓冲溶剂效果最佳。应用这一方法对机体年龄增长过程中细胞呼吸爆发程度的变化进行了细致和深入的研究,探索了机体年龄增长与巨噬细胞呼吸爆发间的相互关系。     

Observation of biophoton emission from plants in the process of defense response

Biophoton emission from germinating soybean under adverse circumstance has been observed by high sensitive imaging system based on ICCD detector. It is found that the intensity of biophoton emission from the injured position of the cotyledon is enhanced obviously compared with the intact position. In addition, a strong biophoton emission has been detected at the tip of the root when the root is supplied with water after drought. The emission induced by wounding may be associated with the defense response of plants. The emission during the process of convalescence after drought may be the results of the changes of oxidative metabolism in cells.     

红霉素发酵过程前期参数相关分析及调控

对红霉素发酵过程前期调控策略进行了研究,从宏观代谢流的变化着手,对表征细胞代谢特征的参数进行了相关分析,对发酵前期的摄氧率(OUR)、二氧化碳释放率(CER)及呼吸商(RQ)相关变化及红霉素发酵前期CER与pH的变化进行了分析,确定了合适的调控方式,在工业规模发酵罐上通过控制发酵过程前期补糖速率等措施,使发酵平均水平从原来的4500u／mL提高到了6000u／mL。     

New views on age of the Salawusu Formation of Late Pleistocene in northern China

The Salawusu Formation in the Salawusu River basin of Inner Mongolia is a typical sequence of the Upper Pleistocene in northern China. However, there have been some different views about the division and age of stratigraphic facies since the establishment of the Salawusu Formation. According to the stratigraphic subdivision and dating of the Dishaogouwan section, it is thought that the fluviolacustrine-aeolian sand sequence from the Dishaogouwan section can be compared with loess, deep-sea deposit records and climatic fluctuations of glacial period. The Salawusu Formation of fluviolacustrine facies was formed in the last interglacial period from 140 to 70 ka BP, roughly corresponding to the fifth stage of deep-sea oxygen isotope, and developed in the same period as the palaeosol S1 on the Loess Plateau; the aeolian sand of the Chengchuan Formation was formed in the last glacial period from 70 to 10 ka BP, constituting the heteropic geological body along with the Malan Loess on the Loess Plateau; the fluviolacustrine deposit and black soil of the Dagouwan Formation and the Dishaogouwan Formation was formed in the Holocene warm period from 9 700 to 3 000 a BP, or developed in the same period as the plaeosol B1 on the Loess Plateau.     

Oxygen isotopic (17O-18O) heterogeneity in Archaean continental nucleus, North China Craton

The oxygen isotopic data for amphibolites from Archaean continental nucleus, North China Craton indicate that ( i ) the evolving lines structured by the data are parallel to the geoselenic evolving line, which means that the parent materials of these continental nucleus originated from solar matter; ( ii ) different intercepts for these evolving lines manifest that oxygen isotopic compositions of different continental nucleus are heterogeneous, which means that these continental nucleuses originated from different parent resources with different original compositions.     

Laserprobe oxygen isotope analysis of minerals from mantle-derived rocks in eastern China

Oxygen isotope analyses were carried out by the laserprobe technique for mineral separates from mantle xenolith and megacryst in Cenozoic basalts, East China. The results not only give the δ I8O range consistent with that reported for peridotites in the world, but also yield oxygen isotope equilibrium between coexisting minerals.     

足球运动员“运动寿命”的探讨

本文以心理学、生理学的观点为依据,结合足球运动的特点,研究足球运动员的“运动寿命”,为提高我国足球人才效益,提供科学依据。     

投资组合的增长率及其极限定理

研究了投资组合增长率的性质,证明了任何投资组合的超额增长率恒为非负,进而证明了一般市场条件下序列投资组合的极限定理．     

温度对Cr_2O_7~(2-)阳极形成过程的影响

用分解极化曲线法研究了在 0 .1 mol/ L Cr2 ( SO4) 3 1 mol/ L Na2 SO4 0 .2 mol/ L H2 SO4溶液中 Pt和Pb O2 电极上 Cr2 O2 - 7阳极形成和 O2 析出过程中温度的影响 .实验结果表明 ,在 1 .95V下 ,Pt电极上 O2 和Cr2 O2 - 7的表观活化能分别为 57.4 k J/ mol和 61 .3 k J/ mol;Pb O2 电极上 O2 和 Cr2 O2 - 7表观活化能分别为 4 0 .2 k J/mol和 4 6.2 k J/ mol.温度对于 Cr2 O2 - 7形成的加速作用要大于对 O2 析出的加速作用 ,当温度升高时 ,使 Cr2 O2 - 7的电流效率提高 .固定温度和固定电位下 Pb O2 上 O2 析出速度较之 Pt电极上增加不大 ,但 Cr2 O2 - 7形成速度远比 Pt电极上大 ,可见 Pb O2 电极对于 Cr2 O2 - 7的阳极形成具有较高的催化活性 .