2,4,5-三苯基咪唑类化合物的合成及其双光子特性

以4,4′-二甲基苯偶酰为原料合成了3个2-(4-取代苯基)-4,5-二(4-甲基苯基)咪唑系列衍生物,对其结构进行了表征,通过测定其光物理性质,发现这类化合物不仅具有较高的荧光量子产率,而且具有较大的双光子吸收截面,是很好的双光子显微和成像以及上转换激射荧光的候选材料.     

分子距边矢量用于卤代甲烷及卤代乙烷沸点的估计与预测

基于分子距边矢量（ＭＤＥ）,借助多元线性回归技术（ＭＬＲ）建立起描述卤代烃沸点变化规律的定量结构－性质相关关系（ＱＳＰＲ）模型,其复相关系数Ｒ＝０．９９３５,均方根误差ＲＭＳ＝１０．０７Ｋ。最后５次随机选取２５个化合物作预测集,以余下的６２个化合物作校正集建ＱＳＰＲ模型（Ｒ＝０．９９２８,ＲＭＳ＝１０．８８Ｋ）,并有效地预测了沸点（Ｒ＝０．９９２５,ＲＭＳ＝１１．７８Ｋ）。结果表明,模型的预测能力良好。另外,还运用所建立的模型对３０个未知沸点的卤代甲、乙烷的沸点值进行了预测,根据预测出的沸点数据指出了ＣＦＣ１１,ＣＦＣ１２和ＣＦＣ１１３的一些可能的代用品。     

深圳市公共体育设施空间供需及影响因素研究

基于“10分钟健身圈”的视角, 结合兴趣点(POI)和手机信令等数据, 使用GIS网络分析测量深圳市公共体育设施可达性, 并利用基尼系数对深圳市公共体育设施资源供需匹配的公平性进行分析。运用地理探测器方法, 探究深圳市公共体育设施空间供需的影响因素, 得到如下结果。1) 深圳市公共体育设施总体上可达性较高, 基本上满足10分钟健身圈的要求。2) 公共体育设施资源分配相对平均。同一市辖区不同街道的设施分配高度公平, 市辖区之间的平等性可以进一步提升。3) 盐田区、坪山区和大鹏新区的街道供需匹配较好, 福田区和罗湖区交界处街道的体育设施分布集中, 对服务能力造成一定的限制。4) 地价因素是影响深圳市公共体育设施空间供需关系的最主要因素, 其次是路网密度和公交站点数目, 人口总数和人造地表比例也对供需关系存在一定的影响。     

根域限制下绣球根冠关系及光合特性的响应

设置3种不同容器规格,探讨了绣球在形态学、生物量、光合特性、氮素分配及根冠关系等方面对生境变化的具体响应.结果发现：小号容器与大号容器（对照）栽种的绣球的测定指标几乎都存在显著性差异,而中号容器栽种的绣球在冠幅、地上部生物量、花序数量及叶绿素含量上与对照之间不存在显著差异.观测绣球一个生长周期后发现,中号容器可以替代大号容器.研究结果表明：根域限制显著制约绣球生长,主要表现在形态指标、根系生物量、光合速率和根系氮素等方面,揭示了绣球对根域限制的生理生态响应,并为绣球在垂直绿墙中的拓展应用提供理论基础.     

Further mechanism of α/β interphase boundary evolution and dynamic globularization of Ti–5Al–2Sn–2Zr–4Mo–4Cr at elevated temperature deformation

The evolution characterization of the α/β interphase boundaries of the isothermally compressed Ti–5Al–2Sn–2Zr–4Mo–4Cr with lamellar microstructure was carried out via electron backscatter diffraction (EBSD) and transmission electron microscope (TEM). The effect of the α/β interphase boundary evolution on the dynamic globularization was discussed, and the nucleation model for the β recrystallized grain at the cusp of α lath in the late stage of deformation in terms of the classic nucleation theory was established. The mean α/β interface deviation angle from Burgers orientation relationship (BOR) increased continuously up to 18.9° with the increasing strain from 0.1 to 0.5, which was dominated by the continuous dynamic recrystallization. Restoration of BOR between α and β phases at the strains of 0.7 and 0.9 occurred due to the occurrence of recrystallized α and β grains following BOR, which was rationalized by a nucleation model considering the stored energy of deformation provided the driving force for nucleation at the cusp of α lath. Loss of coherency of α/β interphase boundaries at a strain about 0.3 was responsible for accelerating the dynamic globularization of α lamellae since the energy of α/β interphase boundaries increased up to the maximum value when the non-coherent α/β interphase boundaries were formed. Restoration of coherency of α/β interphase boundaries due to the recrystallization nucleation in the late stage of deformation did not substantially affect the dynamic globularization since the α/α intraphase high-angle boundaries (HAGBs) were formed and the most α/β interphase boundaries were non-coherent.     

傅里叶变换下Kramers-Kronig关系的理论推导

从物理实验事实的因果律出发,脱离具体的微观物理模型,基于傅里叶变换、色散理论和留数定理,详细地论述了Kramers-Kronig关系的物理机制和理论推导.     

Constructing Asymmetry and Symmetry in Relationships Within a Consulting System

Asymmetry is viewed as one characteristic of organizational relationships. Organizations need power structures, hierarchies and other sort of inequalities. However, symmetric relationships are also needed, at least for providing commitment and learning between people. This article focuses on the nature of asymmetry and symmetry in consulting settings. It draws from the social constructionist point of view and examines the variation of asymmetric and symmetric relationship construction within a single multi-party consulting situation. Through data collected from an authentic consulting process and methodology derived from Discourse Analysis, the article argues that asymmetry-symmetry dimension is present for consulting parties and that the parties mutually produce and re-produce the balance between the polarities. The paper discusses the role of a process consultant in the re-construction of organizational relationships.     

遥感信息模型的层次化模拟和描述方法

针对遥感信息模型的自动化模拟和计算中现有方法的不足,基于按需服务模式提出了面向空间信息应用需求的遥感信息模型模拟和描述方法,将遥感信息模型模拟计算过程分解为包含五个通用步骤的信息处理流程,采用语义关联方法来表达各阶段资源选取与应用需求间的对应关系,并给出相应的面向应用需求的遥感信息模型模拟的层次化转化和映射方法,最后通过典型应用案例展示了该方法的工作过程。     

基于不对称人际影响的舆论涌现模型研究

人际关系影响是舆论形成的重要因素。引入个体意见的不确定性以及个体间的信任因子,建立了个体间的不对称影响函数,以此为基础实现了一个舆论涌现的Agent仿真模型,仿真结果反映模型是合理有效的。对仿真结果的分析说明:个体意见的不确定性和个体间的相互信任,是影响最终舆论涌现形态与涌现速度的重要因素。     

Application of rough graph in relationship mining

Based on the definition of class shortest path in weighted rough graph,class shortest path algorithm in weighted rough graph is presented,which extends classical shortest path algorithm.The application in relationship mining shows effectiveness of it.