河台韧性剪切带型金矿床成矿作用地球化学研究

河台韧性剪切带型金矿床产于糜梭岩之中。石英中包裹体成分及氢、氧和碳同位素研究揭示,成矿流体为雨水和变质流体的混合体,富硫和碳,早期成矿流体主要为变质作用、混合岩化和花岗岩化作用过程中产生的变质流体,成矿晚期有大量雨水参与;流体成分以 K~ 、Na~ 、HCO_3~-、SO_4~=、CO、CO_2、CH_4和水为主.硫、铅同位素研究揭明,金等成矿物质来源于云开群上亚群.结合地层中金丰度和区域性金分布研究得出,在变质作用、混合岩化和花岗岩化作用过程中,矿源层中金发生明显活化转移,并在构造扩容带聚集成矿.     

龙门山地区泥盆纪锶、碳同位素与海平面变化

文章将龙门山地区泥盆系划分为四个沉积旋回,即四个地层层序,建立了该区泥盆纪海相碳酸盐锶、碳同位素地层曲线,并将同位素演化与沉积旋回结合起来研究该区泥盆纪的海平面变化。     

四川石棉大水沟碲矿床的同位素地质研究

石棉大水沟相矿是世界首例独立的破多金属矿床。矿体严格产于变质岩中，成矿作用在时间上与赋矿围岩经受的区域动热变质作用相一致。成矿输液的６Ｄ值为一６８．７％－一４１．６％，８＇勺值为２·６１‰～１１．９３‰，它最可能来源于变质水，是赋矿围岩在区域动热变质过程中发生的脱挥发反应形成的。Ｐｈ，Ｓｒ，Ｓ，Ｃ同位素研究表明，成矿物质具多来源特点，成矿组分是在区域动热变质的有利条件下，通过变质热液对围岩的浸取而它集成矿。     

福建平和大望山等铅、锌、银(金)矿床稳定同位素地球化学

对福建平和大望山等铅、锌、银(金)矿床的氧、氢、硫、铅稳定同位素分析测定结果,脉石矿物氧同位素δ~(18)O(‰)=+2.54～+10.05,其中包裹体氢同位素δD_(H_2O)(‰)=-46.6～-111.8矿石硫同位素δ~(34)Si(‰)=-3.60～+4.90,铅同位素~(206)Pb/~(204)Pb=18.3817～18.8747,~(207)Pb/~(204)Pb=15.5932～15.8328,~(206)Pb/~(204)Pb=38.5152～39.9802.据硫、铅同位素研究认为,矿质来自花岗闪长岩浆:氢、氧同位素研究认为,成矿溶液主要为演化的混合型初始岩浆水(MCIMW),局部有大气降水或演化的大气降水的混入,并讨论了水/岩作用以及矿床所在地区地质地球化学的某些特点。     

An in situ zircon Hf isotopic,U-Pb age and trace element study of banded granulite xenolith from Hannuoba basalt： Tracking the early evolution of the lower crust in the North China craton

Backscattered electron images, in situ Hf isotopes, U-Pb ages and trace elements of zircons in a banded granulite xenolith from Hannuoba basalt have been studied. The results show that the banded granulite is a sample derived from the early lower crust of the North China craton. It is difficult to explain the petrogenesis of the xenolith with a single process. Abundant information on several processes, however, is contained in the granulite. These processes in-clude the addition of mantle material, crustal remelting, metamorphic differentiation and the delamination of early lower crust. About 80% of zircons studied yield ages of 1842 ±40 Ma, except few ages of 3097-2824 Ma and 2489-2447 Ma. The zircons with ages older than 2447 Ma have high εHf (up to +18.3) and high Hf model age (2.5-2.6 Ga), indicating that the primitive materials of the granulite were derived mainly from a depleted mantle source in late Archean. Most εhf of the zircons with early Proterozoic U-Pb age vary around zero, but two have     

高丰度硅-28同位素的分离技术

同位素纯硅片具有特殊的物理性质,在信息技术领域有着非常广阔的应用前景。为获得高丰度28Si,利用国产的高速气体离心机,选择SiF4作为分离的工作介质,对硅同位素进行了离心分离实验。通过单机分离实验,调整气体离心机的有关参数,摸索出适合级联分离的单机参数,同时得到气体离心机分离硅同位素的单位质量数的全分离系数γ0。利用由4台离心机组成的级联,经过6个阶段的分离,得到了28Si丰度达到99.5%的样品。实验结果表明,离心法分离硅同位素是完全可行的。     

Fuzzy cluster analysis of the provenance of ancient Yaozhou porcelain body

The technique of neutron activation analysis (NAA) has been employed to measure the content of 29 kinds of elements in the sample of Yaozhou porcelain bodies,Then a fuzzy cluster analsis has been conducted to the NAA data and a diagram of the dynamic fuzzy cluster analysis has been achived,The results indicate that the batch of ancient Yaozhou porcelain bodies,which were of different overglaze color and were produced by different kilns during a period of over 800 years from the Tang Dynasty (618-907 A.D.) to the Yuan Dyansty(1271-1368 A.D.) ,has shared a stable and concentrated raw material source,Provenances of porcelain bodies from different times ,though having their specific independence ,enjoy a close relationship and are not far from one another,Provenances of porcelain bodies made during the Tang Dynasty and the Five Dynasties (907-960 A.D.)are found to be closer to one another,while those of the Song (960-1279A.D.) and the Jin Dynasty (1115-1234 A.D.)are comparatively concentrated in certain areas and are different from those of the Tang Dynasty .Both the tri-colored glazed pottery made in Yaozhou kilns during the Tang Dynasty and the Yaozhou porcelain bodies of the Tang period are from the same provenance.     

Hf isotope composition of zircons and implication for the petrogenesis of Yajiangqiao granite,Hunan Province,China

In the peralumineous granite of Yajiangqiao zircon population can be divided into two groups (i.e. Zircon Ⅰ and Zircon Ⅱ), which were formed in magmatic chamber and in emplacement place, respectively. The Hf isotope compositions of two stages of zircon show that the host magma was essentially derived from crustal material by melting. However, some higher 176Hf/177Hf ratios indicate that the granitic zircons should contain fine crystal of zircon formed in mantle-derived magma. In fact, the backscattered electron imaging and the electron microprobe analysis reveal that there is another type of zircon included within Zircon Ⅰ, which is quite different from Zircon Ⅰ and Zircon Ⅱ in morphology and chemistry. They are considered to be the product of the mantle-derived magma intruded into the granitic magma chamber at the beginning of anatexis. Thus,it is suggested that the formation of Yajiangqiao granite is related to the underplating of mantle magma.     

Diet control on carbon isotopic composition of land snail shell carbonate

Carbon isotope compositions for both the carbonate shells and soft bodies (organic tissue) of living land snails collected mostly from the Loess Plateau, China have been measured. The result shows that δ 13C values range from -13.1‰ to -4.3‰ for the aragonite shell samples and from -26.8‰ to -18.0‰ for the soft body samples. Although the shells are enriched in 13C relative to the bodies averagely by 14.2(±0.8)‰, the shell δ 13Ca values are closely correlated to the body δ 13Corg values, expressed as δ 13Ca = 1.021 δ 13Corg 14.38 (R = 0.965; N = 31). This relationship indicates that δ 13Ca is primarily a function of the isotopic composition of the snail diets since previous studies have proved that the snail body is the same as their food in carbon isotope composition. In other words, carbon isotope compo-sition of the carbonate shell can be used as a proxy to estimate the dietary 13C abundance of the land snails. The data also support that the 13C enrichment of the carbonate shells results mainly from the equilibrium fractionations between the metabolic CO2, HCO3-in the hemolymph and shell aragonite, and partially from kinetic fractionations when snail shells form during their activity.     

黔西北地区铅锌矿硫同位素特征研究

通过对黔西北地区铅锌矿中硫化物硫同位素的分析表明,各铅锌矿床具有硫同位素组成较为均一,但水城与赫章地区硫同位素组成差异显著的特点。综合分析认为,区内铅锌矿床中的硫可能主要来源于含矿围岩之外的多个膏盐层。