新型离子型有机锡化合物{[Ph2Sn]2[2,6-Py(CO2)]3H2O}2-[HNEt3]+2的晶体结构研究

利用三苯基氯化锡和2,6-吡啶二甲酸在三乙胺存在下以1:1摩尔比反应,合成了离子型有机锡化合物[Ph_2Sn]_2[2,6-Py(CO_2)]_3H_2O~(2-)[HNEt_3]_2~+.通过元素分析、红外光谱和核磁共振氢谱对其结构进行了表征.用X-射线单晶衍射测定了该化合物的晶体结构.化合物的单斜晶系,空间群P2_1/n,α=1.707 3(7)nm,b=1.744 7(7)nm,c=2.433 3(10)nm,β=109.694(7)°,Z=4,V=6.824(5)nm~3,Dc=1.282 g/cm~3,μ=0.793 mm~(-1),F(000)=2 696,R_1=0.056 3,WR_2=0.1539.化合物中两个锡原子呈七配位畸变五角双锥构型.     

碳酸乙烯酯(EC)增塑的(PEO)16LiClO4聚电解质电导率的研究

采用差示扫描量热法(DSC)和交流阻抗方法对EC增塑的(PEO)₁₆LiClO₄聚电解质进行了研究。结果表明(PEO)₁₆LiClO₄/EC体系的玻璃化转变温度(t_g)及PEO的结晶度(X_c)降低,电导率(б)增加,且б与温度(T)的关系符合Arrhenius行为。提出了离子导电聚电解质/不锈钢(SS)这种结构的界面双层结构和交流阻抗谱图的模拟等效电路。     

保护渣性能对结晶器内传热的影响

在实验室模拟研究了结晶器内酸性保护渣的传热情况。结果表明：增加保护渣的粘度、提高保护渣的凝固温度，结晶器与坯壳之间渣膜的传热系数和热流密度都减小而热阻增加，通过调整保护渣的性能，可调节渣膜的传热系数，使其适应连铸坯生产的要求。     

磁化水的物理化学性能

除红外光谱和核磁共振谱与磁化前无明显差别外,磁化水的ｐＨ值、溶解氧和难溶盐的溶解度均增加,紫外吸收知和密度降低,挥发性加快,电导率的变化与磁场强度和磁经时间有关,并发现磁化水的电导率有滞后效应,对磁化水性能变化的机理提出了初步见解。     

W-Cu合金中Cu相纯度对热导的影响

为了探讨提高ＷＣｕ合金热导（ＴＣ值）的途径,采用４种不同纯度的铜,用熔渗工艺制备Ｗ１５Ｃｕ（质量分数,％）复合材料试样,并用ＣＯ２激光仪测试熔渗试样的ＴＣ值．研究发现,铜相纯度的微小变化对ＷＣｕ合金的ＴＣ值产生重大影响．并对铜相纯度影响ＷＣｕ合金ＴＣ值的机制进行分析和探讨．实验证明,用９９．９％的铜,并用适当的熔渗工艺,可以得到ＴＣ值为２００Ｗ·ｍ－１·Ｋ－１的Ｗ１５Ｃｕ合金．     

毛细管中两相流动特性的电导测量方法

建立了单毛细管中两相流动传递参数实验系统,基于该系统开发了测取泰勒流下气泡速度气含率、气泡频率以及液栓长度等参数的双电导测试系统。结果表明,与常用的摄像法进行比较,双电导探针具有在线、实时和动态响应快等特点,可替代摄像法,并可扩展应用于结 构化催化剂内部测定气液两相流动参数分布。同时,采用电导法对毛细通道中多种流型——包括分散气泡流、气泡串流、泰勒流、膜流及多种过渡流型——进行辨识,取得了较好的实 验结果.     

小尺寸金属系统电导率的计算

运用量子统计要函数方法和久保公式分别计算一维金属线、二维金属薄膜的杂质散射电导率,计算结果表 尺寸金属系统的电导率跟金属系统上有关,具有量子尺寸效应。     

新四电极法测定离子溶液和熔体电导率的研究

在Van der Pauw公式基础上,导出了用正方形排列的四电极法测量溶液或熔体电导率的计算公式和测量方法。并设计和制造了DC—1型电导仪,对比实验表明该方法较方便可靠。     

Effect of addition of poly（ethylene glycol） on electrical conductivity of poly（3,4-ethylenedioxythiophene）-poly（styrenesulfonate） hybrid

By mixing various concentrations of poly (ethylene glycol), a series of poly(3,4-ethylenedioxythiophene)-poly(styeenesuffonate) composite thin films were prepared.The electrical conductivity of the PEDOT-PSS/PEG thin films was measured by the four-pcobe method. Experimental results showed that the inclusion of poly(ethylene glycol) influenced the electrical conductivity of PEDOT-PSS film significantly. With the increase of PEG concentrations, the electrical conductivity sharply increased to reach a maximum and then slowly decreased down. Furthermore, the PEG molecular weight and environment temperature also played important roles on the electrical conductivity of PEDOT-PSS/PEG thin films. A good linear relationship was found between in σDC and T^-1/2 within the entire temperature range detected.     

Thermal conductivity of nanoscale thin nickel films

The inhomogeneous non-equilibrium molecular dynamics (NEMD) scheme is applied to model phonon heat conduction in thin nickel films. The electronic contribution to the thermal conductivity of the film is deduced from the electrical conductivity through the use of the Wiedemann-Franz law. At the average temperature of T=300 K, which is lower than the Debye temperature ΘD=450 K, the results show that in a film thickness range of about 1?11 nm, the calculated cross-plane thermal conductivity decreases almost linearly with the decreasing film thickness, exhibiting a remarkable reduction compared with the bulk value. The electrical and thermal conductivities are anisotropic in thin nickel films for the thickness under about 10 nm. The phonon mean free path is estimated and the size effect on the thermal conductivity is attributed to the reduction of the phonon mean free path according to the kinetic theory.