稀土金属有机氢化物的合成及其引发Claisen 重排反应的研究

用(C9H7)2LnCl@2THF与过量氢化钠在THF溶液中反应,得到相应的稀土有机氢化物[(C9H7)2LnH]2@4THF@NaCl,用制得的氢化物与不饱和羰基化合物苯乙酸烯丙酯反应,发生Claisen重排,同时选择性还原羰基.     

镁改型蛭石对铵离子的交换性能

对经人工改型所得的镁型蛭石进行了铵离子交换性能的研究．在不同pH值下测定了镁型蛭石对NHr的全交换容量，在不同温度下测定了样品的平衡等温线．结果表明，镁型蛭石对NH4^ 的交换总量随pH值的变化而波动，在pH值为7时其交换总量为59．32mmol／100g，其选择性随温度的降低而升高，这为蛭石作为一种新型填料提供了一定的理论依据。     

Parity Nonconservation in of Multiply Dielectronic Recombination Charged Ions

A parity nonconserving （PNC） asymmetry in the cross section for dielectronic recombination of polarized electrons on multiply charged ions with Z≥40 is discussed. This effect is strongly enhanced for close doubly-excited states of opposite parity in the intermediate compound ion. Such states are known for He-like ions. However, these levels have large energy and large radiative widths which hampers observation of the PNC asymmetry. We argue that accidentally degenerate states of more complex ions may be more suitable for the coresponding experiment.     

展览建筑中受众选择性注意的应用研究

分析了展览建筑设计中受众选择性注意的社会因素,提出了展览建筑设计中针对受众选择性注意的设计原则。     

Experimental Observables on Nuclear Liquid Gas Phase Transition

Progress on nuclear liquid gas phase transition （LGPT） or critical behavior has been simply reviewed and some signals of LGPT in heavy ion collisions, especially in NIMROD data, are focused. These signals include the power-law charge distribution, the largest fluctuation of the fragment observables, the nuclear Zipf law, caloric curve and critical exponent analysis etc.     

Ab initio study of the effects of Ag/Mn doping on the electronic structure of LiFePO_4

Based on density functional theory (DFT) of the first-principle for the cathode materials of lithium ion battery, the electronic structures of Li(Fe1-xMex)PO4 (Me = Ag/Mn, x = 0―0.40) are calculated by plane wave pseudo-potential method using Cambridge serial total energy package (CASTEP) program. The calculated results show that the Fermi level of mixed atoms Fe1-xAgx moves into its conduction bands (CBs) due to the Ag doping. The Li(Fe1-xAgx)PO4 system displays the periodic direct semiconductor characteristic with the increase of Ag-doped concentration. However, for Fe1-xMnx mixed atoms, the Fermi level is pined at the bottom of conduction bands (CBs), which is ascribed to the interaction be-tween Mn(3d) electrons and Fe(4s) electrons. The intensity of the partial density of states (PDOS) near the bottom of CBs becomes stronger with the increase of Mn-doped concentration. The Fermi energy of the Li(Fe1-xMnx)PO4 reaches maximum at x = 0.25, which is consistent with the experimental value of x = 0.20. The whole conduction property of Mn-doped LiFePO4 is superior to that of Ag-doped LiFePO4 cathode material, but the structural stability is reverse.     

利用积分算子方程的小波－矩量法分析频率选择反射面

小波－矩量法以小波基作为矩量法中的基函数，通过Ｇａｌｅｒｋｉｎ法可以获得很稀疏的阻抗矩阵，用迭代法求解时可减少计算机内存和计算时间。该文以有限尺寸的频率选择反射面为例，用小波－矩量法分析散射特性和电流分布，着重讨论了阻抗矩阵的稀疏化程度对计算精度的影响。结果表明，当非零元素仅为１０％时，仍能达到满意的精度，因此小波－矩量法不失为分析电大尺寸问题的一种有效方法     

碱土金属化合物晶格能计算的新方法——离子贡献法

本文提出了一种计算碱土金属化合物品格能的新方法——离子贡献法。该方法只需本文提供的离子贡献值即可计算得到晶格能,而不需要任何实验数据。对碱土金属氧化物、卤化物、氢化物、氢氧化物、硫酸盐、碳酸盐、磷酸盐等十九类75种化合物的计算结果表明,计算值与实验值之间的一致性令人满意,计算结果的平均相对误差仅0.79%,小于目前已有的所有方法的计算误差。     

离子选择电极法测定牙膏中的含氟量

采用氟离子选择电极法测定氟含量，具有简便、快速、灵敏、选择性好等优点，最低检出浓度为0.05mg／L，适用浓度范围宽，在测定牙膏含氟量中取得良好效果。     

Using genetically-defined rodent strains for the identification of hippocampal traits relevant for two-way avoidance behavior: a non-invasive approach

Summary Genetically-defined rodent strains permit the identification of hippocampal traits which are of functional relevance for the performance of two-way avoidance behavior. This is exemplified here by analyzing the relationship between infrapyramidal mossy fibers (a tiny projection terminating upon the basal dendrites of hippocampal pyramidal neurons) and two-way avoidance learning in about 800 animals. The necessary steps include 1) identification of structural traits sensitive to selective breeding for extremes in two-way avoidance, 2) testing the robustness of the associations found by studying individual and genetical correlations between hippocampal traits and behavior, 3) establishing causal relationships by Mendelian crossing of strains with extreme structural traits and studying the behavioral consequences of such structural randomization, 4) confirming causal relationships by manipulating the structural variable in inbred (isogenic) strains, thereby eliminating the possibility of genetic linkage, and 5) ruling out the possibility of spurious associations by studying the correlations between the hippocampal trait and other behaviors known to depend on hippocampal functioning.In comparison with the classical lesion approach for identifying relationships between brain and behavior, the present procedure appears to be superior in two aspects: it is non-invasive, and it focuses automatically on those brain traits which are used by natural selection to shape behaviorally-defined animal populations, i.e., it reveals the natural regulators of behavior.