丙烯酸—丙烯酰胺共聚物—稀土络合离子荧光性能的研究

本文首次采用高分子复合的方法,深入地研究了稀土离子的微观化学环境对它的荧光性能的影响,实验发现,具有含氧官能团的高分子和具有含氮官能团高分子形成的复合物中,嵌在两条分子链之间的稀土离子可同时和两种官能团配位,这样的杂配位比单一官能团配位更能提高稀土离子的荧光强度。     

氮异常辉光放电中离子成分及能量分子束质谱诊断

利用国内首台三级差分抽空的分子束质谱装置,对短间隙氮异常辉光放电阴极鞘层区正离子组分及能量分布进行了诊断研究。在所研究的实验条件下（压力１３３～２７９Ｐａ,放电电流２～７ｍＡ）,离子流中主要离子成分是Ｎ＾＋、Ｎ＾＋２,且Ｎ＾＋比Ｎ＾＋２的浓度大５倍左右。鞘层区的Ｎ＾＋、Ｎ＾＋２的能量分布均有一极大值,该极值在所研究实验条件下随气压增高而减小,随放电电压增大而增大。对氮等离子体中所包含的主要基元过程     

以匹配半径外离子数为控制变量的束晕控制

实现了以强流加速器中离子束流匹配半径外的离子数为控制变量的束晕-混沌控制,并定性地讨论了新的控制变量与已往的控制变量相比所具有的优点．通过研究,提出了一个正弦函数形式的控制器．可以看出,该控制器对离子信息的探测量较少,与以往的控制器相比,更方便于应用．     

An outlier robust GARCH model and forecasting volatility of exchange rate returns

Since volatility is perceived as an explicit measure of risk, financial economists have long been concerned with accurate measures and forecasts of future volatility and, undoubtedly, the Generalized Autoregressive Conditional Heteroscedasticity (GARCH) model has been widely used for doing so. It appears, however, from some empirical studies that the GARCH model tends to provide poor volatility forecasts in the presence of additive outliers. To overcome the forecasting limitation, this paper proposes a robust GARCH model (RGARCH) using least absolute deviation estimation and introduces a valuable estimation method from a practical point of view. Extensive Monte Carlo experiments substantiate our conjectures. As the magnitude of the outliers increases, the one‐step‐ahead forecasting performance of the RGARCH model has a more significant improvement in two forecast evaluation criteria over both the standard GARCH and random walk models. Strong evidence in favour of the RGARCH model over other competitive models is based on empirical application. By using a sample of two daily exchange rate series, we find that the out‐of‐sample volatility forecasts of the RGARCH model are apparently superior to those of other competitive models. Copyright © 2002 John Wiley & Sons, Ltd.     

锂离子电池负极材料包覆型天然石墨的研究

合成并研究了一种包覆一层氢氧化铁的天然石墨材料 ,它可作为一种新型锂离子电池负极材料。对其电化学性能测试表明 ,当所用电解质为 1m ol/L L i PF6 (EC与 DEC的体积比为 3:7)以 0 .2 5 5 m A.cm- 2充放电时 ,其可逆比容量可超过 35 0 m Ah.g- 1 ,并且具有较好的循环性能。对这种材料进行了 X光衍射分析 (XRD) ,扫描电镜测量 (SEM) ,差重 -热重分析 (DTA- TGA)。从材料的结构、充放电特性和可逆性等方面 ,对锂在该包覆型碳材料中的嵌入机理进行了初步探讨。对该材料的结构分析表明所包覆的氢氧化铁分布较为均匀 ,特别是在天然石墨的端面上包覆的氢氧化铁及其在第一次充放电期间与锂反应生成的固体电解质界面 (SEI)膜 ,能够固定石墨片 ,防止其发生滑移和剥落 ,从而对材料的电化学性能产生良好的影响     

Forecast Evaluation of Nonlinear Models: The Case of Long‐Span Real Exchange Rates

This paper deals with the nonlinear modeling and forecasting of the dollar–sterling and franc–sterling real exchange rates using long spans of data. Our contribution is threefold. First, we provide significant evidence of smooth transition dynamics in the series by employing a battery of recently developed in‐sample statistical tests. Second, we investigate the small‐sample properties of several evaluation measures for comparing recursive forecasts when one of the competing models is nonlinear. Finally, we run a forecasting race for the post‐Bretton Woods era between the nonlinear real exchange rate model, the random walk, and the linear autoregressive model. The nonlinear model outperforms all rival models in the dollar–sterling case but cannot beat the linear autoregressive in the franc–sterling. Copyright © 2011 John Wiley & Sons, Ltd.     

板式换热器在船舶轮机中的应用

介绍了板式换热器的构造、特点,提出了换热计算的方法,并结合船舶轮机中的应用实际论述了使用注意事项.     

I_2、I~-淀粉溶液显色探究

通过探究I2与I-使淀粉显色的实验条件及实质,纠正现行某些教材上是碘分子与直链淀粉形成络合物显蓝色的错误认识,证明使淀粉显色的物质应该是碘的分子离子而不是碘分子.     

Ag和Ni离子注入聚合物的分形生长

在Ag和Ni离子注入聚合物样品结构分析中,首次观察到注入的离子在聚合物中分形生长现象,用透射电子显微镜和扫描电子显微镜在注入样品表面与横同处均观察到了漂高的离子注入分形生长图,讨论了分形特点和分形生长的机理,并且与理论计算进行了比较。     

高性能磷酸盐玻璃原料(高纯KH2PO4)的制备

用离子交换法制备了高纯KH2PO4(其中杂质Fe3 ,Co2 和Ni2 的总质量分数小于3×10-6).以树脂的吸附容量和再生性能为考察指标,从三种树脂中选出了性能最佳的一种--螯合树脂D751,探讨了溶液pH值、温度、流速等因素对该树脂吸附容量的影响.结果表明提纯KH2PO4的最佳条件为:pH 4.0～5.0,温度20～30℃,流速1 mL/min.在本实验条件下,D751可将工业级KH2PO4中Fe3 ,Co2 和Ni2 的总质量分数由23×10-6降至3×10-6以下.