离子沟道自由电子激光的自发辐射谱

计算了离子沟道中的库仑场,在小振幅条件下导出了相对论性电子束的运动轨迹,运用麦迪定理研究了电子的自发辐射谱分布,并对结果进行了讨论.     

不平衡电桥法测电池的内阻

阐述了不平衡电桥法测量电池内阻的原理，给出实验设计，测量结果与电位差计法相比可提高测量精度。     

制碱工业中离子交换膜使用寿命的探讨

结合本公司离子膜装置多年来实际运行情况，全面分析了离子交换膜发生针孔的原因，并提出了相应的防止对策。     

离子浮选法从钨酸盐溶液中分离钨钼

利用作者试验室合成的捕收剂采用离子浮选法进行了钨钼分离．对于（ＮＨ４）２ＷＯ４溶液和Ｎａ２ＷＯ４溶液体系，每克钼捕收剂用量为６７６ｇ的条件下，对于含钼量为０４～１２ｇ／Ｌ的料液，其除钼率可达到９４％～９９％．     

在制备环已酮中Cr~(3 )的回收利用

利用合成正溴丁烷的实验中所回收的Ｎａ２ＣＯ３废液来回收制备环已酮所产生的废液中的Ｃｒ３＋。     

Electrochemical behavior of adriamycin at a cobalt ion implantation modified electrode

With Co/GCE in 0.005 mol Tris/L/0.05 mol/L NaCl solution (pH 7.1), a sensitive reductive peak of adriamgcin (ADM) was obtained by the linear scan voltammetry. The peak potential is ?0.62 V (vs. SCE). The peak current is proportional to the concentration of ADM. The electrochemical behavior of the system was studied by the linear-sweep and cyclic voltammetry. The experiments showed that the reduction at Co/GCE is a quasi-reversible process with adsorption. According to Laviron’s theory, the electrode reaction rate constant k₀ and the electron transfer coefficient a are determined to be 2.15 s^-1 and 0.62, respectively. The composition of the surface, valence state of elements and depth distribution of elements on the surfaces of Co/GCE were determined by the X-ray photoelectron spectroscopy and Auger electron spectroscopy. The experiments showed that Co was surely implanted into the surface of GCE. The implanted Co element in the form of Co-C catalyzed the reduction of ADM.     

改性聚丙烯酰胺螯合树脂的合成及对污水中金属离子吸附性

以丙烯酰胺为单体,双丙烯酰胺为交联剂,先制得交联聚丙烯酰胺聚合物,再用氨基硫脲对交联聚丙烯酰胺进行功能化改性,反应制得以聚丙烯酰胺为主链,侧链带螯合基团的改性氨基硫脲树脂.采用元素分析,红外光谱对树脂进行了表征,并用动态吸附法测定了该树脂对几种金属离子的吸附性能,发现该树脂对银离子有较好的吸附性能.     

用钌离子催化氧化法研究干酷根及其显微组分的化学结构

用钌离子选择性催化氧化法研究了茂名油面岩士酪根、山西蒲县藻煤藻类体、长广树皮煤的树此体以及山西繁峙褐煤镜质组的化学结构。研究结果表明，茂名油面岩干酷根和蒲县藻煤藻类体的化学结构均以醚／酸键形式交联的中等链长的脂链结构为主，繁峙褐煤镜质组中的芳 结构仍保留着木质素基本结构单元的单环结构，同时含有丰富的脂族化合物。这些脂族化全物可能来自这一富氢显微组分中的超微类脂体。长广树皮煤中树皮体以少于４个环的稠     

Preparation, structure and application of a new ecomaterials cesium ion-sieve

A new ecomaterials cesium ion-sieve (Cs-IS). which has high selectivity to cesium and excellent acid resistance, is prepared with zirconyl molybdopyrophosphate as its matrix by specific chemical sieve-making means. Cs-IS has large exchange capacity (1. 83 mmol'g^-1) and high distribution coefficient (4. 09 X 104 mL'L^-1) in the medium of 3 mol'L^-1 HNO3. In the static exchange with strongly acidic high-level radioactive liquid waste (HLLW) (3 mol'L HNO3). Cs-IS exhibits high exchange rate for cesium (above 96. 53% ) and large separation factor (greater than 958. 41). These indicate the possible use of Cs-IS in cesium^-137 selective removal and recovery from highly saline acidic HLLW system.     

重离子注入对小麦染色体畸变率的影响

采用中科院近代物理研究所100kev、200kev及20mev离子注入机,产生不同剂量的C~(1 )、N~(1 )、Fe~(1 )对春小麦品种“81529”及N~(7 )对“82579”进入注入实验,研究对小麦染色体畸变率的影响及其生理生化效应。 研究结果表明:①不同离子同一剂量对小麦染色体畸变率的影响不同;②同一离子随剂量的增加染色体畸变率呈上升趋势;③小麦剥皮后提高了离子注入的敏感性;④中能离子注入对小麦染色体畸变率的影响更为明显;⑤Fe~(1 )离子注入可使小麦种子呼吸强度增强;⑥重离子N~(7 )注入对小麦可溶性蛋白质和过氧化物酶的影响效果随剂量的增加更为明显。