Inter-phase selective corrosion of γ-TiAl alloy in molten salt environment at high temperature

Hot corrosion behavior of Ti-48Al-2Cr-2Nb alloy in molten salt environment of 75%Na_2SO_4 and 25%NaCl(mass fraction) at 800℃was studied using oxidation kinetics analysis,scanning electron microscopy,X-ray energy dispersive and X-ray diffraction analyses.The inter-phase selective corrosion,which caused the corrosion pits initiated from lamellar interfaces and the preferential corrosion ofα_2 phases,was observed during the hot corrosion of the alloy.The common controls of thermodynamic and kinetics in corr...     

高炉煤气管道的腐蚀问题分析与建议

国内大型高炉煤气净化系统投运干法、TRT发电后,TRT后部煤气管道均发生严重腐蚀问题。分析了高炉煤气的腐蚀机理,论述了目前采取的防腐措施及存在的问题,提出了控制高炉煤气管道腐蚀的建议。     

焦化氨水介质中0Cr17Ni12Mo2不锈钢电化学腐蚀行为研究

采用全浸动态挂片和极化曲线实验法研究0Cr17Ni12Mo2不锈钢在模拟现场工况条件下的腐蚀行为。结果表明,0Cr17Ni12Mo2试样的腐蚀速率随温度的升高不断加快;增大硫离子和氯离子浓度可使0Cr17Ni12Mo2试样腐蚀速率加快;氰根离子浓度不高于临界值时,试样腐蚀速率减缓,反之,腐蚀速率加快。     

泡沫Al-0.146wt.%Ti合金的制备及耐腐蚀性能研究

采用真空低压渗流铸造法,制备了泡沫A-l0.146wt.%Ti合金.分析了影响渗流法制备泡沫铝合金的主要因素,得到了制备泡沫合金的最佳条件:NaCl填料粒子预热温度300℃,合金液体浇铸温度760℃,填料粒子尺寸1~3mm.不同孔率泡沫A-l0.146wt.%Ti合金的模拟海水全浸实验结果表明:泡沫合金的耐腐蚀性能随着孔率增加显著下降.     

循环水缓蚀阻垢剂的研究

针对某公司循环水的水质情况,对原有的缓蚀阻垢剂进行改进,通过正交试验确定缓蚀效果较优的组合,有针对性地研究了一种适用于该公司循环水的缓蚀阻垢剂配方.     

含水率和腐蚀因素对钢筋混凝土柱抗震性能的影响

通过分析混凝土试块浸泡在水中和不同浓度腐蚀溶液中力学性能变化的试验结果,回归出混凝土抗压强度和弹性模量随含水率或腐蚀时间变化的计算模型,并通过纤维模型有限元程序OpenSees,对不同含水率或不同腐蚀程度的钢筋混凝土模型柱在低周往复荷载作用下的受力性能进行了模拟.结果表明:随着含水率的增加,两种养护条件下,构件抗震性能降低的程度较小,但随着腐蚀程度的增大,构件耗能能力和延性的降低及承载力和刚度的衰减比较显著.     

油套管用钢P110的CO_2腐蚀动力学研究

利用高温高压腐蚀试验及电化学原位测量技术,并辅以SEM、EDS和XRD等微观分析手段研究了油套管用钢P110在CO2分压为2 MPa、温度为100℃的3.5%NaCl水溶液中的腐蚀失重、界面反应电化学特性、腐蚀产物膜的微观形貌、成分和结构特征,探讨了油套管用钢CO2腐蚀动力学.研究结果表明:油套管用钢P110的CO2腐蚀产物为FeCO3;随腐蚀时间的延长及腐蚀产物膜的形成,平均腐蚀速率逐渐降低、趋势变缓,产物膜生长满足抛物线生长规律;腐蚀产物晶粒逐渐长大并堆垛紧密,逐渐成膜覆盖于金属表面,膜厚先增加后逐渐趋于稳定,对基体保护能力增强;不同腐蚀时间交流阻抗图谱(EIS)的拟合结果表明,极化电阻随着腐蚀时间增加逐渐增大,电极反应由最初的活化控制变为扩散控制.     

Ca对医用Mg-4Zn合金轧制板材组织与性能的影响

采用金相分析、扫描电镜分析和拉伸测试等手段研究了Ca含量(质量分数0.3%,0.6%和0.9%)对高应变速率轧制Mg-4Zn基合金板材显微组织、力学性能和耐生体腐蚀性能的影响.结果表明:加入Ca可以细化Mg-4Zn合金的动态再结晶晶粒,导致合金中残余第2相的含量增加和尺寸增大,并提高其抗拉强度和屈服强度.其中,Mg-4Zn-0.9Ca合金的抗拉强度和屈服强度分别为300 MPa和278 MPa,比基体合金分别提高了12.4%和68.5%.然而,合金的耐腐蚀性能和剩余抗拉强度随着Ca含量的增加而下降,可归因于合金中残余第2相含量的增加以及尺寸增大.Mg-4Zn合金板材中第2相比较细小、分布均匀,倾向于均匀腐蚀,在0.9%NaCl溶液中浸泡7d的平均腐蚀速率为0.80mg/(cm~2·d),浸泡7d,15d后的剩余抗拉强度分别为217 MPa和205 MPa.     

Corrosion-wear behavior of nanocrystalline Fe88Si12 alloy in acid and alkaline solutions

The corrosion?wear behavior of a nanocrystalline Fe88Si12 alloy disc coupled with a Si3N4 ball was investigated in acid (pH 3) and alkaline (pH 9) aqueous solutions. The dry wear was also measured for reference. The average friction coefficient of Fe88Si12 alloy in the pH 9 solution was approximately 0.2, which was lower than those observed for Fe88Si12 alloy in the pH 3 solution and in the case of dry wear. The fluctuation of the friction coefficient of samples subjected to the pH 9 solution also showed similar characteristics. The wear rate in the pH 9 solution slightly increased with increasing applied load. The wear rate was approximately one order of magnitude less than that in the pH 3 solution and was far lower than that in the case of dry wear, especially at high applied load. The wear traces of Fe88Si12 alloy under dif-ferent wear conditions were examined and analyzed by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. The results indicated that the tribo-chemical reactions that involve oxidation of the worn surface and hydrolysis of the Si3N4 ball in the acid solution were restricted in the pH 9 aqueous solution. Thus, water lubrication can effectively improve the wear resistance of nanocrystalline Fe88Si12 alloy in the pH 9 aqueous solution.     

腐蚀损伤的激光超声可视化成像检测

腐蚀损伤广泛存在于国防科技、交通运输等工业领域,严重威胁了结构的安全性和可靠性,因此对腐蚀损伤的安全检测具有重要意义。依据激光超声的基本理论,采用自主设计的全自动激光超声扫描实验系统,通过对铝板中的腐蚀损伤进行激光扫描实验,分析了Lamb波能量、幅值和腐蚀之间的关系,并依据“弹性波能流法”的原理,利用幅值最大值完成了损伤区域的可视化;提出了一种评估铝板腐蚀程度的方法——能量比较法,完成了对不同腐蚀程度的铝板的评估分析。该研究可实现腐蚀缺陷的快速检测与评估,并且检测结果直观可视,展现了巨大的应用前景。