Synthesis and luminescence properties of Mn4+-dopant Ca14Zn6Ga10−xAlxO35 solid solution

Mn~(4+)-activated oxide phosphors,owing to their desirable spectral features,eco-friendly and low cost,are emerging as a new class of non-rare-earth red phosphors for warm white LEDs.However,these phosphors possess low photoluminescence quantum efficiency excited by blue chip currently.Herein we report an isostructural solid solution of Ca_(14)Zn_6Ga_(10-x)Al_xO_(35):0.15Mn~(4+)(0≤x≤10)synthesized by a traditional solidstate reaction route.The microstructure and luminescent performance of this red-emitting phosphor are investigated in detail with the aids of X-ray diffraction,diffuse reflection spectra,photoluminescence spectra/decay/QE,and temperature-dependent PL/QE measurements.Blue shift of energy peaks of~4A_2→~4T_1and~4A_2→~4T_2transition is illustrated by the Tanabe–Sugano diagram and the configurational coordinate diagram.The crystal field strength(Dq)and the Racah parameters(B and C)are carefully calculated to estimate the nephelauxetic effectβrespectively.Particularly we achieve external and internal quantum efficiencies as high as26.1%and 40.3%for Ca_(14)Zn_6Ga_6Al_4O_(35):0.15Mn~(4+)excited by 466 nm,the highest one ever reported in Mn~(4+)activated oxide phosphors under the similar condition.     

从沸腾炉渣中浸取有价金属

研究了从钢厂炉渣中回收有用金属的一种新方法。实验中，炉渣用硫酸浸取，浸取液采用EDTA络合滴定分析元素组成，颗粒粒径分布采用标准筛筛分，化学组成和微观结构分别采用XRF。结果表明，铝的最大提取率为86．20％，条件为：H2SO4浓度4mol·L^-1、固液比1：5条件下在80℃浸取24h。在同一条件下铁获得最大提取率为94．3％。     

孔隙型碳酸盐岩储层注气注水提高采收率试验

中东地区部分碳酸盐岩储层类型以孔隙型为主,裂缝不发育,气测渗透率低,流体物性较差.以中东某油田S油藏为例,开展注气和注水可行性试验研究,并探讨其提高采收率的微观渗流机制.结果表明:受物性特征影响,储层注伴生气驱最小混相压力高,地层条件下不易达到混相驱替,但整体上岩心注烃类气驱效率要高于水驱效率,尤其当达到混相条件时,气驱效率明显提高;注烃类非混相驱油效率也相对较高,主要是由于储层原油黏度较高,气驱使原油体积膨胀,黏度降低,进而改善流动性;试验采用的水驱和气驱方式在微观上主要动用大孔隙中的可动流体,可考虑优化驱替方式进一步提高驱油效率.     

具有不确定性输出的决策单元的相对效益评价

针对一类输出受干扰影响的多输入多输出社会经济系统的效益评价问题,研究了数据包络分析方法中决策单元的有效性、P-生产可能集以及原始性等概念,定义了一个可用于判断输出受随机因素影响的决策单元相对有效程度的指标,并在此基础上给出了一个新的随机DEA评价模型,分析了该模型的性质、求解方法以及与现有模型的一致性等,最后给出了一个评价案例.     

基于主成分分析的安徽省区域产业结构优化效率评价

通过运用主成分分析法,对安徽省2007~2012年产业结构调整和产业结构优化效率进行实证分析.首先,建立安徽省区域内产业结构调整的综合评价体系.其次,利用主成分分析模型研究安徽省内产业结构调整中,省内不同城市和地区在经济结构调整、技术进步、生态污染等不同角度所产生的综合效果,并据此对安徽省内不同城市的产业结构优化效率进行综合评价.最终提出相应的解决方案.     

EOCPWM控制技术研究

介绍了EOCPWM(效率最优脉宽调制 )控制技术的原理和采用的优化方法 ,求出了开关角度为 3个时EOCPWM数学模型的多组解 ,并把这些解和SHEPWM (选择谐波消去法脉宽调制 )的解在电机谐波电流抑制特性 (QHCF)方面进行比较 ,从而显示出EOCPWM控制技术的优越性     

利用CBP作为缓冲层增加有机发光器件的效率

制备一种利用4，4′-N，N′-dicarbazole—biphenyl（CBP）作为超薄空穴注入缓冲层．CBP作为一种较好的缓冲材料，改善了有机发光器件的性能．CBP阻挡部分从阳极ITO注入到有机层NPB的空穴，从而平衡了空穴和电子的注入．有缓冲层的有机发光器件比没有缓冲层有机发光器件的电流效率有了明显的提高．当缓冲层CBP为4nm时，最大电流效率在8V时达到5．66cd／A，这是没有缓冲层器件电流效率的近1．5倍．     

基于最小特征根的相对效率

对线性模型的最小二乘估计(LSE)与最佳线性无偏估计(BLUE)定义了一种新的相对效率,新的相对效率定义为最小特征根的比值,之后研究了它的下界及它与广义相关系数之间的关系.最后讨论了新的相对效率与已有的3种相对效率之间的关系.     

Simulation of maximum light use efficiency for some typical vegetation types in China

MAXIMUM LIGHT USE EFFICIENCY(ΕMAX)IS THE USE RATE OF PHOTOSYNTHETICALLY ACTIVE RADIATION BY VEGETATION IN AN IDEAL CONDITION WITHOUT ANY CONSTRAINTS.IT IS A PHYSIOLOGICAL ATTRIBUTE OF PLANT ITSELF.THE VALUE OFΕMAX IS DIFFERENT FOR DIFFERENT VEGETATION TYPES[1―5].IT IS A KEY PARAMETER FOR THE ESTIMATION OF NET PRIMARY PRODUCTIVITY(NPP)DRIVEN WITH REMOTE SENSING DATA.THERE…     

Reliable and Energy Efficient Target Coverage for Wireless Sensor Networks

A critical aspect of applications with Wireless Sensor Networks (WSNs) is network lifetime.Power-constrained WSNs are usable as long as they can communicate sense data to a processing node.Poor communication links and hazardous environments make the WSNs unreliable.Existing schemes assume that the state of a sensor covering targets is binary:success (covers the targets) or failure (cannot cover the targets).However,in real WSNs,a sensor covers targets with a certain probability.To improve WSNs’ reliability,we should consider that a sensor covers targets with users’ satisfied probability.To solve this problem,this paper first introduces a failure probability into the target coverage problem to improve and control the system reliability.Furthermore,we model the solution as the α-Reliable Maximum Sensor Covers (α-RMSC) problem and design a heuristic greedy algorithm that efficiently computes the maximal number of α-Reliable sensor covers.To efficiently extend the WSNs lifetime with users’ pre-defined failure probability requirements,only the sensors from the current active sensor cover are responsible for monitoring all targets,while all other sensors are in a low-energy sleep mode.Simulation results validate the performance of this algorithm,in which users can precisely control the system reliability without sacrificing much energy consumption.