尖晶石型Li-Mn-O多元素掺杂的高温电化学特性

采用高温固相浸渍法合成了多元复合掺杂尖晶石型锰酸锂Li 1.02MxMn 2-xQyO 4-y正极材料.XRD表征合成的产物均为良好的尖晶石型结构材料;SEM表明所合成的产物颗粒均匀且有良好的粒径分布.以该物质作为锂离子电池的正极材料组装成扣式电池,经充放电循环测试可知:多元素掺杂的尖晶石型锰酸锂正极材料Li 1.02CoaCrbLacMn 2-a-b-cFyO 4-y较富锂尖晶石和单元素Co、Cr掺杂的正极材料能够更好地抑制电池的可逆容量在充放电过程中的衰减,循环性能有了很大改善,表现出很好的电化学可逆特性,80次循环后放电容量仍能保持94.5%以上;特别是高温(55 ℃)性能更加突出,40次循环后放电容量仍能保持102.1mA.h/g(91.5%)以上.作为锂离子电池的正极材料,该复合掺杂材料是众多取代钴酸锂材料中最具竞争力的材料之一,也有望成为锂离子动力电池的正极材料.     

TiO2/SbXSn1-XO2复合导电粉制备技术研究

采用化学共沉淀法在TiO2表面包覆掺锑氧化锡,制备复合导电粉.利用透射电子显微镜(TEM)对样品的形貌进行观察.考察了制备条件,如SnCl4·5H2O用量、Sb掺杂量、反应的pH值、温度、煅烧温度等对复合粉体电阻率的影响.     

乙酰丙酮铕掺杂配合物的荧光光谱研究

合成了RExEu1-x(acac)3(RE=Y,La,Gd;x=0.00,0.10,0.20,0.30,0.40,0.50,0.60,0.70,0.80,0.90,1.00）固体配合物，并测定了荧光发射光谱，讨论了稀土掺杂配合物的组成与荧光发光特性的关系。     

TMS320C6x在无线信号实时分析系统中的应用

该文介绍了TMS320C6201 DSP在实时数据采集分析系统中的应用，着重介绍了如何通过RS—232和PCI完成与DSP的McBSP和HPI间的通信，并给出了软硬件的设计作为参考．     

基于主机的网络防火墙技术及其实现方法

网络防火墙技术在信息安全领域中扮演着十分重要的角色，因此介绍了网络防火墙的分类及特征，着重阐述了主机型网络防火墙的工作原理和关键技术，并结合MS Windows操作系统给出了一些具体实现方法。其主机型防火墙技术必将在解决信息安全方案中占据越来越重要的地位。     

工控系统中的多机通信系统设计

从工程应用角度,详细探讨了分布式控制系统中所采用的多机通信系统机制．论述了多机通信系统的网络结构,连接方式和软件通信协议．     

光致发光谱测量掺硅AlGaAs中的DX能级

在调制掺杂ＧａＡｓ／ＡｌＧａＡｓ多量子阱结构的光致发光谱中,靠近强发光峰的低能端存在几个弱峰,且发光强度随温度的增加而变化．这些弱峰是由于掺硅ＡｌＧａＡｓ中ＤＸ中心上的电子向起受主作用的ＳｉＡｓ原子跃迁复合而引起．由此确定ＤＸ中心有四个能级,其激活能分别为０．３５ｅＶ,０．３７ｅＶ,０．３９ｅＶ和０．４１ｅＶ．     

First host records for the rogadine genera Rogasodes Chen and He and Canalirogas van Achterberg and Chen (Hymenoptera: Braconidae) with description of a new species and survey of mummy types within Rogadinae s. str.

The parasitic wasp genus Rogasodes is recorded for the first time outside mainland China, based on a new species, R. scytaloptericola Quicke and Shaw sp. nov., from Java. Rearing data and host remains associated with the type specimen show that it is a parasitoid of the palm‐feeding drepanid moth, Scytalopteryx elongata (Snellen). Canalirogas sp. aff. balgooyi van Achterberg and Chen is recorded from an unidentified lymantriid on clove trees in Indonesia (Sumatra) and illustrated. Both of these are the first host records for the genera. Rogas spilonotus Cameron is transferred to Canalirogas. A survey of mummy sclerotization and adult emergence holes in the subfamily Rogadinae sensu stricto is presented. The data suggest an early shift to a posterior emergence position, with a strictly dorsal position being largely characteristic of the common genus Aleiodes. Only Aleiodes and a few apparently closely related taxa, including Hemigyroneuron, typically form heavily sclerotized mummies.     

Tricolor white emitting phosphor co-doped with Eu,Dy in SiO_2 matrix

A Eu, Dy co-doped SiO2 matrix, white emitting phosphor was prepared by the sol-gel technique. Strong red, green and blue emissions located at 618 nm, 573 nm and 400-550 nm were observed under UV laser excitation at room temperature. Such techniques as FT-IR and TGA-DSC were used to measure the microstructure of the luminescent material. The influence of the preparation techniques on the luminescence property of the Eu, Dy co-doped SiO2 matrix, such as anneal temperature, anneal time, dried atmosphere and the components of the matrix, was systematically studied, and the luminescence mechanism was interpreted. The red emission is the strongest when annealed at 750 ℃ . However, blue emission appears when annealed at 700 ℃ and is the intensest at 900℃ . For the samples dried in vacuum, Eu3 is more easily deoxidized to Eu2 at lower temperatures, because the samples dried in the air compared with that dried in vacuum need higher temperature to form network structures. Only the SA and SAB matrix annealed at 850 ℃ had blue emission in the four matrices (SA, SAB, SB, S) xerogel and the emission in the SAB matrix was stronger than that in the SA matrix. This may be due to the eutectic phase formed by the oxide boron, alkaline oxide and alumina in the SAB matrix, which constructs network structures and stabilizes the emission center and enhances the blue emission.     

长平立井提升系统的安全改造研究

介绍了长平公司主立井的改造,重点阐述了电气系统和机械系统的改造内容,并分析了改造后的社会效益和经济效益,为立井改扩建提供了很好的范例。