江苏沿海沙脊群表层沉积物Pb同位素特征及对物源的指示

为进一步查明江苏沿海沙脊群沉积物的来源,分析了该区域沉积物酸不溶组分Pb同位素特征。结果表明,远岸沙脊群陆向区域沉积物Pb同位素比值与近岸沙脊群相似,暗示其在潮波作用下有向岸运移的趋势。铅-钕同位素分析揭示长江及周边河流沉积物在长江冲淡水和东海沿岸流作用下输移至远岸沙脊群海向区域。在苏北沿岸流作用下,老黄河三角洲沉积物输入对近岸沙脊群及远岸沙脊群陆向区域有影响;相反,诸如现代黄河口、济州岛和韩国河流等地沉积物输入对江苏沿海沙脊群的影响较弱。     

氦原子Rydberg态1D-3D谱项分裂值的多体微扰计算

通过自洽迭代求解Hartree方程得到各组态下的轨道波函数。以此构造组态波函数为基矢,对氦Rydberg态1snd组态的^1D—^3D谱项分裂值进行了多体微扰计算,计算结果与实验结果符合得较好。对于由同科电子构成的组态,由于没有相应的^3D谱项,所以由此计算得到的二级以上单态、三重态的能级修正值是不对称的。     

Petrogenesis and significance of the Hongshan syenitic pluton,South Taihang: zircon SHRIMP U-Pb age, chemical compositions and Sr-Nd isotopes

The Hongshan syenitic pluton (South Taihang) is mainly made up of hornblende syenite and minor granite. SHRIMP zircon dating yields a U-Pb age of 135±2.7 Ma for the emplacement of the pluton, while biotite Rb-Sr isotopic data give an isochron of 120. 3±2.4 Ma. Hongshan syenites show low silica, high alkalis and LILE such as Sr, and exhibit negligible Eu anomalies or slightly positive anomalies in the REE patterns. The syenites show quite enriched isotopic compositions with Isr from 0.7052 to 0. 7102 and εNd(t) from -7.5 to - 11.1. Petrogenesis of the pluton can be that partial melting of an enriched lithospheric mantle gave birth to an alkali basaltic magma, which subsequently underplated in the lower crust and experienced a coupled fractionation of ferromagnesian phases like pyroxene and hornblende and minor (<10 %) contamination of lower continental crust, producing the Hongshan syenites that partially e-volved into granite through combined fractionation of hornblende and feldspar. Our data are not in agreement with a previous model that the syenites originated from melting of lower crust in a thickened crust circumstance, and thus do not support the speculation of "East China Plateau" in the Mesozoic.     

银川地区降水氢氧同位素变化规律分析

大气降水是区域水循环中重要环节,对于研究区域内水分循环、水分来源、水分转换等水文过程有重要意义.通过对银川地区降水中氢氧同位素特征随月降水量变化趋势进行分析,得出不同季节的降水水汽来源是影响银川地区降水同位素变化的主要因素,秋冬季节降水水汽主要来自于北冰洋地区,春夏季节降水水汽主要来源于印度洋、孟加拉湾及太平洋地区.区域内蒸发的水汽对降水的贡献及降水过程中的二次蒸发作用都使降水中重同位素富集.全年来看,银川地区降雨量效应不明显,但是夏季降雨量对降水中氢氧稳定同位素变化影响不容忽视.通过分析氘过量参数d随月平均降水量的变化趋势,辅助论证了不同季节不同水汽来源的降水是影响氢氧同位素变化的主要因素.     

用相对论平均场理论研究氧同位素及其镜核的基态性质

用相对论平均场理论计算了氧同位素及其镜核的基态性质,并和实验比较,发现当质子（中子）是幻数时,核的性质有规律地随中子（质子）数的变化而变化,由此间接证明了幻数核子对另一类核子无直接影响;同时,也检验了相对论平均场理论在该区域的适用性．     

Late Neoproterozoic to early Cambrian sulphur cycle-An isotopic investigation of sedimentary rocks from the Yangtze Platform

The sulphur cycle responds to changes in seawater chemistry, biological evolution and tectonic activity. We follow an isotopic approach in order to constrain the state of the ocean/atmosphere system during late Neoproterozoic and early Cambrian. For this purpose, a sedimentary succession deposited on the Yangtze Platform, South China, was analysed for its sulphur isotopic composition in different S-bearing phases. Redox changes were defined by the degree of pyritization (DOP) values in order to show variations in the oxygenation of the depositional environment. The sulphur isotopic composition of late Neoproterozoic to early Cambrian seawater sulphate ranges from +30‰ to +35‰ as evident from trace sulphate in unaltered carbonates and phosphorites. The isotopic composition for pyrite and organic sulphur varies between -16‰ and +23‰. The apparent sulphur isotopic fractionation between seawater sulphate and pyrite as well as organically bound sulphur varies between 7‰ and 50‰. This large fractionation, as well as its variability suggests a biological origin for pyrite and organically bound sulphur. The temporal evolution of different geochemical proxy signals is comparable for different successions across the Yangtze Platform.     

钨基辐照材料纳米氦泡诱导位错成核的分子模拟

基于分子动力学模拟,系统研究纳米氦泡的内压、孔径和温度对钨基辐照材料位错成核机理的影响.首次采用微动弹性带(nudged elastic band,NEB)方法对氦泡诱导位错成核的能垒进行分析.研究发现,存在一个极限氦/空位比,当氦/空位比超过该极限值时,纳米氦泡通过内压驱动位错成核、位错竞争与反应、交滑移等微观机理生...     

Re-Os isotope geochemistry of three Chinese chondrites

Three Chinese ordinary chondrites,including Jilin (H5),Boxian (LL3.8) and Lujiang (LL6),have been studied for their Re and Os abundances and Os isotopic composition in whole-chondrite samples,separated magnetic and nonmagnetic fractions,and nodules. The results indicate that the Re and Os abundances of the whole-chondrite samples are in the ranges of corresponding H-and LL-Groups,respectively. The Re and Os abundances of magnetic fraction from Boxian and Lujiang are within the range of high-Os ⅡAB and ⅢAB irons,whereas those of nonmagnetic fractions of Boxian and Lujiang are lower than the whole-chondrite values. The Re and Os abundances of nodules in Jilin are in the range of the LL-Group. 187Re/188Os and 187Os/188Os ratios of the three whole chondrites are in the range of ordinary chondrites which locate around the isochron of ⅡAB ⅢAB irons. 187Re/188Os and 187Os/188Os ratios of the magnetic and nonmagnetic fractions from Boxian have a larger difference. The nonmag-netic fraction of Lujiang may contain a recent addition of Re,which causes deviation of the 187Re/188Os ratio from the irons isochron. The Re and Os abundances of nodules in Jilin are lower than those of the whole-chondrite,but their 187Os/188Os ratios are higher than that of the whole chondrite.     

Isotopic composition of helium in eclogite from the Dabie Mountains, central China and its geological significance

Isotopic geochemical characteristics of helium in garnet and omphacite of eclogite in the Dabie Mountains are discussed. Concentrations of³He and⁴He in garnet and omphacite are 3.9 × 10⁻¹⁴–24.0 × 10⁻¹⁴ and 0.48 × 10⁻⁷–9.42 × 10⁻⁷cm¹³.g⁻¹, respectively. Values of³He/⁴He have a range of (1.19–4.63) × 10⁻⁷. Helium In the eclogite is derived from both mantle and crust. Isotopic geochemical data of helium indicate that eclogite in the Dabie Mountains might be formed in depleted mantle and the age of the cologite would be Indo-China epoch.     

新路盆地火山岩Sr-Nd同位素地球化学特征及其地质意义

在浙西新路盆地中生代酸性火山岩的Sr-Nd同位素组成和Nd同位素模式年龄基础上,探讨了其源岩性质及其大地构造意义。结果显示,构成新路盆地主体的黄尖组晶屑熔结凝灰岩和花岗斑岩的平均锶初始值分别为0.714 10、0.710 39,ε_(Nd)(t)值分别为-5.5、-5.7;黄尖组晶屑熔结凝灰岩和花岗斑岩的两阶段模式年龄均值分别为1 366Ma、1 387Ma,与扬子地块基底双溪坞群变质岩年龄(900~1 000 Ma)差异明显,而与华夏地块基底陈蔡群变质岩年龄(1 400 Ma)接近;2个单元火山岩Nd同位素均位于陈蔡群Nd同位素演化域。研究认为,新路盆地黄尖组熔结凝灰岩和花岗斑岩具有相似的物质来源,均表现出壳源和幔源物质混合成因特点,壳源物质可能源自南部华夏地块的陈蔡群变质岩,与扬子地块变质基底双溪坞群无关;推测发生于1 000~900 Ma B.P.时期或其后的浙西地区扬子地块与华夏地块之间的陆陆碰撞,具有华夏地块向扬子地块俯冲的动力学特点。上述大地构造运动方式以及岩石成因特点,或许是导致赣杭火山岩带分属华夏地块和扬子地块的火山岩均呈现出与铀成矿关系密切的重要原因。