冷热兼供热泵空调器的性能模拟与分析

针对冷热兼供热泵空调器的特点,建立了冷热兼供热泵空调器稳态运行的数学模型,对该系统进行了较全面的模拟分析,并将模拟结果和实验数据进行了比较,两者吻合良好．同时应用该软件对不同设备参数和不同工况下性能进行分析,得到若干有用的结果．     

2-(1-萘甲基)-3(2-四氢呋喃基)丙酸N,N-二乙氨基乙酯草酸盐的新法合成

改进２－（１－萘甲基）－３－（２－四氢呋喃基）丙酸Ｎ,Ｎ－二乙氨基乙酯草酸盐（Ⅵ）合成方法．方法在１－氯甲基萘和四氢糠基丙二酸二乙酯（Ⅰ）的烷基化反应中使用ＮａＨ／ＤＭＦ为催化剂;在２－（１－萘甲基）－３－（２－四氢呋喃基）丙酸（Ⅳ）与２－氯乙基－Ｎ,Ｎ－二乙基胺的酯化反应中加入相转移催化剂;在２－（１－萘甲基）－３－（２－四氢呋基）丙酸Ｎ,Ｎ二乙氨基乙酯（Ⅴ）与草酸成盐中,直接使用二水合草酸替代脱水草酸．结果烷基化反应产率提高到７５％,反应时间缩短到２ｈ;酯化反应产率从文献报道的７２％提高到９２％;二水合草酸成盐效果与脱水草酸相同．结论该方法较已有的合成方法产率有较大提高且操作简便,有较好的工业化前景．     

静电像管均方根半径的计算及像质评价

探讨在电子光学成像系统中像评定的一种途径。方法,从静电这像差均方根理论出发,追迹计算大量空间轨迹的落点及系统均根半径,并由此衍算成弦财制传递函数。     

谐振腔镜对高斯光束远场发散角的影响

利用变换矩阵和ＡＢＣＤ定律讨论了激光谐振空对高我束的变换,推导出高斯光束参数通过光腔输出镜的变换公式。并对热透镜腔,光束远场发散角等问题进行了讨论。     

Explicit analytical solutions of non-Fourier heat conduction equation for IC chip

Four basic explicit analytical solutions of non-Fourier heat conduction equation simulating IC chip thermal condition are derived. Some other analytical series solutions can also be derived with the above-mentioned basic solutions. Analytical solution has its own irreplaceable important meaning in theory. In addition, as the standard solution to check the accuracy, convergence and effectiveness of various numerical computational methods and their differencing schemes, grid generation ways and so on, the analytical solution is very useful also for the newly rapidly developing computational heat transfer.     

The v-v energy transfer of highly vibrationally excited states (I)

The relaxation of the highly vibrationally excited CO (v = 1–8) by CO₂ is studied by timeresolved Fourier transform infrared emission spectroscopy (TR FTIR). 193 nm laser photolysis of the mixture of CHBr₃ with O₂ generates the highly vibrationally excited CO(v) molecules. TR FTIR records the intense infrared emission of CO(v→v-1). The vibrational populations of each level of CO(v) have been determined by the method of spectral simulation. Based on the evolution of the time resolved populations and the differential method, 8 energy transfer rate constants of CO(v = 1–8) to CO₂ molecules areobtained: (5.7±0.1), (5.9±0.1), (5.2±0.2), (3.4±0.2), (2.4±0.3), (2.2±0.4), (2.0±0.4) and (1.8±0.6) (10¹⁴ cm³ · molecule⁻¹ · s⁻¹), respectively. A two-channel energy transfer model can explain the feature of the quenching of CO(v) by CO². For the lower vibrational states of CO, the vibrational energy transfers preferentially to the u³ mode of CO² For the higher levels, the major quenching channel changes to the vibrational energy exchange between CO(v→v-1) and the u¹ mode of CO².     

Leakage of mantle helium from the Liaodong Peninsula, China

The isotopic cumpositions of helium have been investigated in hot spring gases sampled from the Liaodong Peninsula. China. The³He/⁴He ratios range from 0.14 Ra (0.14 times the atmospheric³He/⁴He ratio of 1.40 × 10^-6 to 0.72 Ra.³He/⁴He versus⁴He/²⁰Ne ratios and He contents suggest that a small amount of mantle-derived helium reaches the earth’s surface. Helium iwtope ratios of the hot spring gases show a distribution pattern similar to the regional heat flow values, indicating that the positive thermal anomaly occurring in the rtrea is closely associated with the presence of mantle-derived helium. The observations described above provide some significant evidence that the molten magma originating from partial melting of the upper mantle may have intruded into the continental crust along the activity fault. The coupling of the presence of mantle He and heat flow anomalies to seismic activity in studied region seem to imply that there is an internal relationship between mantle degassing and seismic activity.     

The v-v energy transfer of highly vibrationally excited states (II)

The vibrational energy transfer from highly vibrationally excited CO to H₂O molecules is studied by time-resolved Fourier transform infrared emission spectroscopy (TR FTIR). Following the 193 nm laser photolysis of CHBr₃ and O₂ the secondary reactions generate CO(v). The infrared emission of CO(v → v−1) is detected by TR FTIR. The excitation of H₂O molecules is not observed. By the method of the spectral simulation and the differential technique, 8 rate constants for CO(v)/H₂O system are obtained: (1.7 ±0.1), (3.4 ±0.2), (6.2 ±0.4), (8.0 ±1.0), (9.0 ±2.0), (12 ±3), (16 ±4) and (18 ±7) (10¹³cm³ · molecule^-1· s^-1). At least two reasons lead to the efficient energy transfer. One is the contributions of the rotational energy to the vibational energy defect and the other is the result of the complex collision. With the SSH andab initio calculations, the quenching mechanism of CO(v) by H₂O is suggested.     

Effect of lanthanum ions on tRNAphe structure: Imino proton NMR spectroscopy

The effect of lanthanum ions on the structural and conformational change of yeast tRNA Phe was studied by 1H NMR. The results suggest that the tertiary base pair (G-15)(C-48), which was located in the terminal in the augmented dihydrouridine helix (D-helix), was markedly affected by adding La 3+ and shifted 0.33 downfield. Based pair (U-8)(A-14), which is associated with a tertiary interaction, links the base of the acceptor stem to the D-stem and anchors the elbow of the L structure, shifted 0.20 upfield. Another imino proton that may be affected by La 3+ in tRNA Phe is the tertiary base pair (G-19)(C-56). The assignment of this resonance is tentative since it is located in the region of highly overlapping resonances between 12.6 and 12.2. This base pair helps to anchor the D-loop to the TΨC loop.     

超声心动图象内外膜的自动检测与测量

为定量计算一些重要的心脏功能数据,提高心脏病的诊断水平,研究了超声心动图象内外膜的自动检测与测量技术．首先对超声心动图象进行滤波以消除图象中的噪声,并运用模糊数学理论进行模糊边缘增强,提取超声心动图象的内外膜边缘信息;接着对超声心动图象作二值化处理和椭圆曲线拟合,初步得到心脏的内外膜边缘;再采用相应的三次样条插值和平滑技术,得到光滑、连续的心脏内外膜边缘．在此基础上,再对心脏进行节段划分,并计算有关的心脏功能数据．经实验证实,用此方法可快速得到较准确的结果．