粘接层预氧化对热障涂层TGO生长与抗高温氧化性能的影响

利用预氧化技术在热障涂层(TBC)的陶瓷层/粘接层界面形成致密Al₂O₃层,经过1 100 ℃高温氧化试验,研究了该Al₂O₃层通过抑制氧气扩散,降低热生长氧化物(TGO)生长速率的作用机理,阐明了粘接层预氧化对整体热障涂层氧化行为的影响规律.结果表明:喷涂态(A-TBC)与预氧化(P-TBC)试样的TGO厚度及氧化增重均随氧化时间的延长而增长.但是,P-TBC显著减少了整个过程氧的扩散,有效抑制了氧化初期TGO的急速生长,使得P-TBC能够长期保持有益的TGO结构、降低抛物线氧化速率,并最终提高热障涂层抗高温氧化性能.     

民族地区双语绿色学校研究

本文以全国生态环境最敏感和脆弱的四川民族地区为研究重点，积极探索民族地区绿色教育，创建民族地区双语绿色学校。本文首次提出了“一类模式双语绿色学校”和“二类模式双语绿色学校”的概念，并对这二类模式学校的评价体系作了研究。只有创建双语绿色学校，才能构建民族地区绿色教育体系，才能真正建设好长江上游的生态屏障，实现民族地区山川秀美和可持续发展。     

Novel cytotoxic peptides from the tropical marine cyanobacteriumHormothamnion enteromorphoides 1. Discovery,isolation and initial chemical and biological characterization of the hormothamnins from wild and cultured material

A Caribbean cyanobacterium,Hormothamnion enteromorphoides, was found to produce a complex mixture of ichthyotoxic peptides, perhaps explaining the apparent absence of predation upon these potentially palatable life forms. Bioassay-guided fractionation was used to isolate these toxic and antimicrobial natural products, and a variety of techniques including HR FAB mass spectrometry, 2D-NMR, traditional hydrolysis-amino acid analysis, and several chemical reactions were used to define the basic structural features of the major peptide, hormothamnin A. Hormothamnin A is a cyclic undecapeptide containing six common and five uncommon or new amino acid residues. HPLC analyses indicate that the relative proportions of these peptide natural products remain relatively constant between different collection locations and years, however, they do vary seasonally. Clonal isolates of this cyanobacterium in culture produce the full spectrum of toxic peptides.     

我国实施绿色市场营销的可行性探讨

绿色营销是在企业生存环境发生变化的情况下提出了的一种新的营销观念。本文对我国实施绿色市场营销的可能性、必要性和解决对策作了探讨，企业必须在环境保护方面承担责任。要 发展与环境保护的矛盾统一起来，非常有效的途径就是实施绿色市场营销。     

陶瓷坯体车削成型工艺方法探讨

对几种不同粘结剂含量的陶瓷压坯的抗压溃强度、切削过程中刀具的磨损、切屑形貌等进行了比较，分析了其可切削性能。研究表明，粘结剂添加量过大，压坯强度下降；粘结剂过少，刀具磨损快，切削力大；两种情况都会造成危险裂纹，产生烧结开裂。当加入量适中，产生塑性切屑时，坯体表现出良好的可切削性。     

布洛芬新工艺对绿色化学的贡献

简述了绿色化学的起图、原则及特点，并通过国内、国外布洛芬合成路线的比较，指出了目前国内合成路线存在的不足。     

Sympathectomy enhances the substance P-mediated breakdown of the blood-aqueous barrier in response to infrared irradiation of the rabbit iris

Summary Rabbits were subjected to infrared irradiation of the iris 1 month after unilateral cervical sympathectomy. The resulting breakdown of the blood-aqueous barrier was greatly enhanced on the sympathectomized side. In contrast, the response to intravitreally injected substance P (SP) was the same in both eyes. The enhancement of the response to IR irradiation could be abolished by pretreatment with an SP antagonist, (D-Pro², D-Trp^7,9)-SP.This study was supported by grants from the Swedish MRC (04X-1007, 14X-2321), the Medical Faculty of Lund, Ferring Arzneimitel, Kiel (Federal Republic of Germany) and Ferring Pharmaceuticals, Malmö (Sweden).     

Chemical control of eucaryotic and blue-green algae in anaerobic photoreactors culturing Rhodospirillaceae

Summary To control the growth of eurocaryotic and blue-green algae in anaerobic reactors of photosynthetically grown Rhodospirillaceae, the effect of algae inhibitors with different modes of action was examined. Tests were performed with mixed populations of green algae and blue-green algae, besides strains of the purple nonsulphur bacteriaRhodopseudomonas capsulata, Rhodospirillum rubrum andRhodomicrobium vannielii. Chloroxuron, a urea-derivative, was found to inhibit completely growth of green and blue-green algae at 5 ppm. When it was applied to the Rhodospirillaceae cultures, growth was not reduced and nitrogenase activity was not inhibited.     

Novel substrates for the kinetic assay of esterases associated with insecticide resistance

Naphthalene thioesters were synthesized as substrates for a continuous, non- disruptive kinetic assay of general carboxylesterase activity. The continuous nature of the assay is based on the production of a soluble dianion chromophore from the reaction of naphthalene thio with 5,5-dithiobis (2-nitrobenzoic acid). Applications with 1- and 2-naphthalene thioacetates demonstrated their use in a fast accurate kinetic microassay of esterase activity, using porcine carboxylesterase as a model. These novel esters proved to be useful as substrates for the spectrophotometric assay of insecticide-resistance in two aphid species and may be applicable to other esterasebased diagnostic procedures.