A kinetic study of the reaction of ozone with ethylene in a smog chamber under atmospheric conditions

Ozone is one of the key species in the processes of atmospheric chemistry, which can be taken as an indicator of oxidation capacity in the troposphere. The reaction of ozone with reactive gases is an important process in the troposphere. Experimental simulation equipment of smog chamber for atmospheric reactions is used to study the reaction of ozone with ethylene in real atmospheric environment with ozone concentrations of 100―200 ppb. The concentrations of ozone and ethylene were moni-tored during the reaction with the combination of Model 49C-O_3 Analyzer and GC-FID. A rate constant of 1.01×10~(-18) (cm~3·mol~(-1)·s-(~1)) was obtained at 286.5 K, under condition of which the half-life of ozone was 88 min. The results obtained from our experiments are in excellent agreement with those reported previously by other researchers under extremely low pressure in terms of matrixisolation technology. This demonstrates that our equipment of smog chamber for atmospheric reactions is reliable, which can be used for further research of the processes of atmospheric reactions.     

规整填料塔内气相流动的计算流体力学模拟

通过引入表征体元的概念，采用体积平均的方法，使规整填料塔内的非连续介质连续化，建立了规整填料塔内气相单相流的体积平均连续性方程、运动方程和质量传递方程；用PHOENICS3．3对规整填料塔内气相单相流的速度分布和质量分数分布进行了模拟，给出了xz剖面的压力分布图、xz和xy剖面的速度分布图和不同时刻xz剖面的示踪剂浓度分布图；模拟结果能反映规整填料内气体的流动情况．结果表明：在压力小于2．0MP。时，气相轴向返混系数基本不受压力的影响，且随着有效气速的增加，其明显增加；轴向返混系数的模拟值与实验值的相对偏差小于40％．