球形和楔形光纤探针耦合特性实

采用实验方法测量了球形光纤与楔形光纤的耦合效率,得出耦合效率随楔形光纤的楔角及球形光纤弓形高变化曲线.通过实验可得,楔形与球形光纤的耦合效率随楔角增加而增大,当楔角由20.6°增大到30.3°以及楔角由40.6°增大到55.2°时,耦合效率曲线呈较快速上升趋势,由30.3°增大到40.6°以及楔角由55.2°增大到76.5°时,耦合效率曲线上升趋势较缓;随着球形光纤弓形高的增加,球形与楔形光纤的耦合效率基本上线性上升;耦合效率随着楔形与球形光纤的间距的减小而增大,当间距由0.09mm减小到0.05mm时,耦合效率曲线呈较快速上升趋势,由0.04mm减小到0.01mm时,耦合效率曲线呈下降趋势.     

Measurement of creep of optical fiber by a low coherent white light double interferometer system

The creep properties of optical fiber used in fiber optical sensors were studied in this paper.A low coherent white light double interferometer system was designed and calibrated and the creep deformations of optical fibers under static and cyclic loadings were measured with this device.The research results showed that polymer coated optical fibers crept at the beginning when they were under static or cyclic load.As the number of the cyclic loading or the static loading times increased the creep tended to s...     

High Oil-absorptive Composites Prepared from Non-woven Fiber and Sponges with 4-tert- butylstyrene-EPDM-divinylbenzene Graft Polymer

4-tert-butylstyrene-EPDM-divinylbenzene graft terpolym-er (PBED) was prepared by graft cross-polymerization in toluene using BPO as an initiator. The gel-PBED and sol-PBED were isolated from extraction of tetrahydrofuran (THF), and then they were identified by IR spectr-oscopy. The maximum oil-absorptivity of gel-PBED produced from the optimum reaction conditions was 8420% but its swelling rate was very low. The highest oil-absorptivity of photocrosslinked sol-PBED film was 5 800%. Although its oil absorbency was not as high as gel-PBED' s, swelling rate was higher than that of gel-PBED and was suitable for commercial purpose. After swelling in oil, neither gel-PBED nor photocrosslinked sol-PBED film having high oil-absorptivity had sufficient mechanical strength to be taken out of oil wholly. As is known, composite technique is one of the useful methods for reinforcing them. Fibers, sponges and non-woven cloths were used as reinforcers or supporters in this work. Oil-absorptivities and swelling kinetics     

阻燃剂硼酸锌的合成

硼酸锌是一种性能优良的无机添加型阻燃剂。组成为 2ZnO·3B2 O3·3.5H2 O的低水合硼酸锌应用得最为广泛。采用硼砂法合成了低水合硼酸锌 ,用正交法确定的最佳工艺条件是 :反应温度为 338K ,硫酸锌和硼砂的配料比为 1 .0 5∶1 ,液固比为 3.5∶1 ,反应时间为6h .     

新阻燃剂磷酸三(2-羟基)丙基酯锑的合成及性质

将环氧丙烷与磷酸反应,首次合成磷酸三(2-羟基)丙基酯,再将其与三氧化二锑反应,得出一种新型锑-磷复合阻燃剂——磷酸三(2-羟基)丙基酯锑;研究了反应体系酸度、反应温度及反应时间等因素对反应产率的影响;制得的产品经化学分析、红外光谱等测试,证明了化合物的结构为CH_3CH(OH)CH_2OP(O)[OCH_2CHO(CH_3)]_2SbOH。将其添加于氯丁橡胶及环氧树脂中,当该阻燃剂用量达到12.5％时,阻燃制品氧指数分别可达到38,39;实验结果表明,将反应体系pH控制在5.5左右、反应温度100℃、反应5h时,可制得阻燃抑烟性能优良的产品,产率达到89％。     

Adhesion of PBO Fiber in Epoxy Composites

The high mechanical and thermal performance of poly p-phenylene- 2, 6-benzobisoxazole ( PBO ) fiber provides great potential applications as reinforcement fibers for composites. A composite of PBO fiber and epoxy resin has excellent electrical insulation properties, therefore, it is considered to be the best choice for the reinforcement in high magnetic field coils for pulsed magnetic fields up to 100 T.However, poor adhesion between PBO fiber and matrix is found because of the chemically inactive and/or relatively smooth surface of the reinforcement fiber preventing efficient chemical bonding in the interface, which is a challenging issue to improve mechanical properties. Here, we report the surface modification of PBO fibers by ultraviolet (UV)irradiation, O2 and NH3 plasma, as well as acidic treatments. The interfacial adhesion strength values of all the treatments show the similar level as determined for aramid fibers by pull-out tests, a significant impact on fibermatrix-adhesion was not achieved. The surface free energy and roughness are increased for both sized and extracted fibers after plasma treatments together with maleic anhydride grafting. The sized fiber shows marginal improvement in adhesion strength and no change in fiber tensile strength because of the barrier effect of the finish.For the extracted fiber, different surface treatments either show no apparent effect or cause reduction in adhesion strength. Atomic force microscopy (AFM) topography analysis of the fracture surfaces proved adhesive failure at the fiber surface. The fiber surface roughness is increased and more surface flaws are induced, which could result in coarse interface structures when the treated fiber surface has no adequate wetting and functional groups. The adhesion failure is further confirmed by similar adhesion strength and compression shear strength values when the fiber was embedded in various epoxy resins with different temperature behavior. The tensile strength of fiber is sensitive to surface treatment conditions as revealed by a bimodal Weibull statistical distribution analysis. Considerable strength reduction occurred, particularly for cases of acidic and plasma treatments, while UV irradiation shows the better ability to retain fiber strength.     

微火焰温度场的自动扫描微型热电偶测量

探索了一种用微型热电偶自动点扫描测量微火焰温度场的方法,从理论上分析了热电偶大小与热气流速度对测温误差的影响,并以3个直列预混微火焰为对象,通过实验详细考察了自动扫描热电偶的数据采集时间间隔和热电偶移动速度对火焰温度测量的影响.结果表明:当丝径小于50μm时,微型热电偶测量的火焰温度误差将小于0.6％;实验中采用丝径50 μm的R型微型热电偶,当温度数据采集时间间隔为0.1s和热电偶移动速度为1.82 ～ 4.22 mm/s时,自动扫描测得的火焰温度与手动单点长时间停留热电偶测得的温度场一致;微型热电偶自动扫描方法可实现快速、准确的微火焰温度场测量.     

非本征光纤F—P传感器制作工艺

分析非本征光纤F-P传感器制作工艺上存在的问题,对传感器工艺制作进行了研究,设计了半自动光纤F-P腔调节工作台,利用光纤五维调节架对光纤进行插入和对准,提高了光纤F-P传感器制作的速度和质量。     

High Oil-absorptive Composites Prepared from Non-woven Fiber and Sponges with 4-tert- buty1styrene-EPDM-divinylbenzene Graft Polymer

4-tert-butylstyrene-EPDM-divinylbenzene graft terpolymer (PBED) was prepared by graft cross-polymerization in toluene using BPO as an initiator. The gel-PBED and solPBED were isolated from extraction of tetrahydrofuran (THF), and then they were identified by IR spectroscopy. The maximum oil-absorptivity of gel-PBED produced from the optinum reaction conditions was 8 420% but its swelling rate was very low. The highest oil-absorptivity of photocrosslinked sol-PBED film was 5 800%. Although its oil absorbency was not as high as gel-PBED' s, swelling rate was higher than that of gelPBED and was suitable for commercial purpose. After swelling in oil, neither gel PBED nor photocrosslinked sol-PBED film having high oil-absorptivity had sufficient mechanical strength to be taken out of oil wholly. As is known, composite technique is one of the useful methods for reinforcing them. Fibers, sponges and non-woven cloths were used as reinforcers or supporters in this work. Oil-absorptivities and swelling kinetics were evaluated by method ASTM (F726 - 81 ) and an experimental equation. The mechanical properties and the morphologies of some composites were measured by tensile tester and SEM , respectively.     

CFRP筋预应力锚具受力性能试验

设计一套圆弧槽夹板式锚具,通过拉拔试验研究锚具的夹持性能,并研究包括施加于夹板紧固件螺栓上的总扭矩值和扭矩沿夹具纵向分布等主要参数对锚具性能的影响.结果表明,总扭矩值和扭矩分布均对锚具的性能有明显影响.当施加在夹板紧固件螺栓的总扭矩值小于200 N·m,试件最终将发生滑移破坏;当总扭矩值超过200 N·m,试件最终发生...