InCl3/HMS中孔固体酸烷基化催化剂的制备和表征

研究以HMS中孔材料为裁体，用浸渍蒸发法制备了InCl3/HMS负载型固体酸催化剂，并考察了不同InCl3负载量催化剂对苯和氯苄的酸催化苄基化反应的催化活性．用XRD、FT—IR和N2等温吸附等技术表征催化剂．结果表明，所制备的InCl3/HMS具有中孔结构；活性组分InCl3负载量与催化烷基化活性相关．过多的负载量，造成InCl3积聚于HMS裁体孔道内，导致催化剂孔容和比表面积的降低，从而降低了催化活性；在InCl3负载量为1．41mmol／g裁体时，催化剂活性最高．FT—IR分析初步表明活性组分InCl3通过化学键合的方式结合于载体HMS表面上，而不是简单地物理吸附于载体表面．     

FTIR assessment of the secondary structure of proteins in human breast benign and malignant tissues

The compositions of the secondary structures of protein in the human breast normal, hyperplasia, fibroadenoma and invasive ductal carcinoma tissues have been estimated from the Fourier self deconvolved spectra, the second derivative spectra and the curve-fitting analysis of the amide I bands in their spectra. Some parameters of the secondary structures of proteins in these 4 types of tissues are significantly different and located in separate ranges. Fibroadenoma tissue demonstrates the most remarkable difference in the compositions of α-helical and atypical helical structures. The carcinoma tissue has the highest ratio of the intermolecular β-sheet content and the intramolecular β-sheet content. This noticeable difference in the secondary structure may have important implications for analyzing the properties and types of human breast disease.     

TURP术后排尿困难或尿潴留原因分析

目的:对TURP术后排尿困难或尿潴留的原因进行分析,同时探讨其预防和处理方法.方法:对21例TURP术后排尿困难或尿潴留患者的病因和处理进行分析.结果:尿道水肿4例;前列腺组织残留2例;前列腺增生复发7例;尿道狭窄2例;膀胱颈口瘢痕挛缩2例;膀胱逼尿肌收缩乏力4例.结论:TURP术后排尿困难或尿潴留的原因有尿道水肿、组织残留、前列腺增生复发、尿道狭窄、膀胱颈口瘢痕挛缩和膀胱逼尿肌收缩乏力等.提高手术技巧和术前尿动力学检查对避免发生术后排尿困难和预测疗效有重要意义.     

对改革开放中多样价值取向的思考

多样价值取向的产生是全球一体化所引起的剧烈碰撞中的必然现象,它代表着社会不同阶层、集团的经济利益、政治诉求和意识形态倾向。尽管多样价值取向会给社会带来一定的消极影响,但是也有其存在的合理性。总结历史经验教训,探求出一条以核心价值体系引领多样价值取向的道路,可以有效实现良性共存,共创和谐社会。     

我国地方立法发展趋势的回顾与展望

建国后五十多年,尤其是恢复地方立法后的近三十年,地方立法逐渐成熟.在未来数年内,会突出呈现以下发展趋势:人性化色彩更浓,愈加尊重人性和尊严;自主性立法将成为地方立法的主要形态;调整内容、规范程度等方面的差异进一步扩大;立法模式由政府单一立法模式向政府立法与社会立法相结合模式转变;中央与地方、地方与地方之间的立法良性互动逐渐加强.     

科技产业的发展可以实现自然生态循环的良性平衡

分析了工业化对自然生态循环平衡的破坏,指出科技是促进生态环境良性平衡的根本要素,并对科技如何实现生态循环良性平衡进行了思考。     

电镀Zn-Fe-SiO2复合材料的性能研究

镀锌与Zn-Fe合金广泛用于钢铁零件的防护,但是仍存在钝化液毒性大、环境污染严重、耐蚀性低、氢脆高等不足。本文采用无氰电镀技术制备了Zn-Fe-SiO2复合材料,并测试了Zn-Fe-SiO2复合材料的耐蚀性、孔隙率和氢脆性等综合性能,同时与电镀Zn及Zn-Fe合金进行了对比。实验结果表明:电镀Zn-Fe-SiO2复合材料的耐蚀性及其它综合性能均优于镀锌与Zn-Fe合金,无需钝化处理,环境友好,应用前景广阔。     

山西省主要城市“两型”建设及其评价体系研究

城市的发展离不开资源的支撑与环境的保障.目前,＂两型＂城市建设已成为探索城市可持续发展的重要课题.从我国＂两型＂城市建设的实际情况出发,借鉴国内外有关评价指标体系等的研究成果,设计了一套指标体系,以山西省主要城市为例,采用主成分分析法进行了＂两型＂城市建设的实证分析.     

环保型可降解油墨色料的研究

通过对金属离子、显色母体进行筛选，并对显色母体进行化学修饰，可以制得多种色泽、并在温和条件下褪色的环保型可降解油墨色料。     

Design of optimum solid oxide membrane electrolysis cells for metals production

Oxide to metal conversion is one of the most energy-intensive steps in the value chain for metals production. Solid oxide membrane (SOM) electrolysis process provides a general route for directly reducing various metal oxides to their respective metals, alloys, or intermetallics. Because of its lower energy use and ability to use inert anode resulting in zero carbon emission, SOM electrolysis process emerges as a promising technology that can replace the state-of-the-art metals production processes. In this paper, a careful study of the SOM electrolysis process using equivalent DC circuit modeling is performed and correlated to the experimental results. A discussion on relative importance of each resistive element in the circuit and on possible ways of lowering the rate-limiting resistive elements provides a generic guideline for designing optimum SOM electrolysis cells.