用陷阱参数作为聚合物电老化特性参数的试验研究

本文以高分子聚丙烯薄膜材料为试样,在真空与均匀电场中进行加速电老化试验。试验结果表明,试样的老化场强与老化时间呈指数关系。在电老化过程中,用红外光谱分析了试样的内在化学结构变化,用电子顺磁共振测量了老化生成的自由基,用光电导谱和表面电位的测量技术测量了陷阱深度与陷阱密度的变化。试样在电老化过程中,短分子链随时间而增加,陷阱的深度与密度也随时间而增长,都与电老化寿命的经验公式有类似的形式。通过讨论电老化的化学过程,提出陷阱参数可以作为表征材料电老化特性的新参数。本文的结论将为建立新的电老化理论提供了试验依据,并为非损伤性电老化试验创造了前景。     

V_2O_5和SiO_2-V_2O_5导电膜的制备及性质

离子交换法制得V_2O_5凝胶和SiO_2含量低于50％(mol)的SiO_2-V_2O_5凝胶。借助透射电镜和电子衍射仪,研究了凝胶的结构,并用DTA-EGA和XRD分析了热处理过程中凝胶的物理化学变化。浸涂法制得V_2O_5和SiO_2-V_2O_3导电膜。凝胶具纤维状结构并含有V_2O_5·H_2O晶子。热处理温度影响膜的状态和电导率。电导率随温度升高,在305～315℃达最大值0.3 Ω~(-1)cm~(-1),温度进一步提高时将导致V_2O_5晶化和电导率下降。SiO_2的掺入提高膜的抗划伤强度并阻缓V_2O_5晶化,但是降低了电导率。     

电荷平衡式电容传感器的研究

本文介绍电荷平衡式电容传感器位移测量系统的原理、结构和系统设计。本系统采用特殊设计的三积分A/D转换器,使仪器的分辨率达二十五万分之一,采样速率达50次/s以上。本文对传感器、三积分A/D转换器等关键部分均作了详细分析和设计。     

中小河流小水电的综合优化开发方式

中小河流综合优化开发方式是综合优化各种开发方式，诸如龙头水库、集水网式开发方式、电力补偿和抽水蓄能的开发方式．实施这种开发方式可成倍地提高保证出力和保证电能，获得巨大经济效益．     

可调谐的同轴腔滤波器

本文介绍一种带宽为5～8MHz,调谐范围在350～510MHz的同轴腔带通滤波器。详细地介绍了腔间孔耦合理论。给出消除耦合环自感影响的方法及减弱电耦合的途径,並给出了实测结果与理论计算的比较。     

两个半圆柱面极板间电场和电容的初等函数表达式

本文应用求解析函数的方法求得由两个半圆柱面组成的电容器的电容为一简单的初等函数C=(2ε)/πlnctg(θ_0)/2,本文还讨论两个半椭圆柱面间电场和电容。     

电阻炉温度微机控制系统的研制

以个人计算机为基础，以Ａ／Ｄ转换器为核心，并配以适当的外围接口电路，实现对电阻炉温度自动控制．设计了一种过零检测电路，将ＰＩＤ控制增量转换成占空比，并由数字电路输出有一定占空比的矩形波，利用硬件方法实现普通双向可控硅的同步过零触发从而实现功率可调     

应用电阻层系成像技术测量垂直管道气/液两相流分相含率

通过对垂直管道中气／液两相流截面相含率测量影响因素的分析,以电阻层析成像系统为检测工具,提出了提取原始测量数据边界特征值的方法和描述气／液两相流截面相含率的特征函数,得到了气／液两相流的截面含气率,仿真计算与实验测试结果表明,在研究导电的液相为连续相的气／液两相流情况下的分相含率时,上述方法是一种有效的测量手段．     

Correlation between geometrical parameters of electrical tree and corresponding partial discharge parameters in XLPE

This paper deals with the experimental study on the correlation between the geometrical parameters of electrical tree and corresponding partial discharge (PD) characteristic parameters in the course of electrical tree aging within cross linked polyethylene (XLPE) insulation. The electrical tree aging tests were performed on specimens removed from a section of 220 kV transmission cable. The PD macroscopic characteristic parameters were found to be significantly dependent on the corresponding geometrical parameters of electrical tree channels in the course of aging of XLPE, and different kind of electrical tree has different characteristics, and there is obvious correlation between the type of electrical tree and the pre-applied power-frequency stress. Beside, using regression analysis, the expression of the relation between them were obtained, and from which it can be seen that there is significant nonlinear correlation between geometrical parameters of electrical tree and corresponding PD characteristic parameters in the course of aging of XLPE. Therefore, the aging degree of XLPE can be effectively evaluated by recognizing the changing regularity of the PD rnacroscopic characteristic parameters.     

Effect of addition of poly（ethylene glycol） on electrical conductivity of poly（3,4-ethylenedioxythiophene）-poly（styrenesulfonate） hybrid

By mixing various concentrations of poly (ethylene glycol), a series of poly(3,4-ethylenedioxythiophene)-poly(styeenesuffonate) composite thin films were prepared.The electrical conductivity of the PEDOT-PSS/PEG thin films was measured by the four-pcobe method. Experimental results showed that the inclusion of poly(ethylene glycol) influenced the electrical conductivity of PEDOT-PSS film significantly. With the increase of PEG concentrations, the electrical conductivity sharply increased to reach a maximum and then slowly decreased down. Furthermore, the PEG molecular weight and environment temperature also played important roles on the electrical conductivity of PEDOT-PSS/PEG thin films. A good linear relationship was found between in σDC and T^-1/2 within the entire temperature range detected.