全文获取类型
收费全文 | 5132篇 |
免费 | 196篇 |
国内免费 | 318篇 |
专业分类
系统科学 | 93篇 |
丛书文集 | 189篇 |
教育与普及 | 22篇 |
理论与方法论 | 9篇 |
现状及发展 | 110篇 |
综合类 | 5222篇 |
自然研究 | 1篇 |
出版年
2024年 | 10篇 |
2023年 | 24篇 |
2022年 | 48篇 |
2021年 | 63篇 |
2020年 | 64篇 |
2019年 | 53篇 |
2018年 | 52篇 |
2017年 | 73篇 |
2016年 | 88篇 |
2015年 | 124篇 |
2014年 | 185篇 |
2013年 | 150篇 |
2012年 | 292篇 |
2011年 | 300篇 |
2010年 | 245篇 |
2009年 | 310篇 |
2008年 | 302篇 |
2007年 | 428篇 |
2006年 | 393篇 |
2005年 | 302篇 |
2004年 | 283篇 |
2003年 | 262篇 |
2002年 | 201篇 |
2001年 | 196篇 |
2000年 | 198篇 |
1999年 | 170篇 |
1998年 | 107篇 |
1997年 | 116篇 |
1996年 | 101篇 |
1995年 | 77篇 |
1994年 | 74篇 |
1993年 | 72篇 |
1992年 | 70篇 |
1991年 | 55篇 |
1990年 | 40篇 |
1989年 | 40篇 |
1988年 | 40篇 |
1987年 | 19篇 |
1986年 | 6篇 |
1985年 | 7篇 |
1984年 | 4篇 |
1980年 | 1篇 |
1955年 | 1篇 |
排序方式: 共有5646条查询结果,搜索用时 140 毫秒
31.
《科学通报(英文版)》2008,(11)
Based on density functional theory (DFT) of the first-principle for the cathode materials of lithium ion battery, the electronic structures of Li(Fe1-xMex)PO4 (Me = Ag/Mn, x = 0―0.40) are calculated by plane wave pseudo-potential method using Cambridge serial total energy package (CASTEP) program. The calculated results show that the Fermi level of mixed atoms Fe1-xAgx moves into its conduction bands (CBs) due to the Ag doping. The Li(Fe1-xAgx)PO4 system displays the periodic direct semiconductor characteristic with the increase of Ag-doped concentration. However, for Fe1-xMnx mixed atoms, the Fermi level is pined at the bottom of conduction bands (CBs), which is ascribed to the interaction be-tween Mn(3d) electrons and Fe(4s) electrons. The intensity of the partial density of states (PDOS) near the bottom of CBs becomes stronger with the increase of Mn-doped concentration. The Fermi energy of the Li(Fe1-xMnx)PO4 reaches maximum at x = 0.25, which is consistent with the experimental value of x = 0.20. The whole conduction property of Mn-doped LiFePO4 is superior to that of Ag-doped LiFePO4 cathode material, but the structural stability is reverse. 相似文献
32.
《科学通报(英文版)》2008,(9)
The optimizations geometries and interaction energy corrected by BSSE of the complexes between C4H4Y (Y=O, S) and CH3Li have been calculated at the B3LYP/6-311 G** and MP2/6-311 G** levels. Three complexes were obtained. Abnormally, the calculations showed that all the C10—Li14 bond lengths increased obviously but the blue-shift of C10—Li14 stretching frequency occurred after formed complexes. The calculated binding energy with basis set super-position error (BSSE) and zero-point vibrational energy corrections of complexes I―III is ?45.757, ?35.700 and ?39.107 kJ·mol?1, respectively. The analyses on the combining interaction with the atom-in-molecules theory (AIM) also showed that a relatively strong lithium bond interaction presented in furan homologues C4H4Y---LiCH3 systems. Natural bond orbital theory (NBO) analysis has been performed, and the results revealed that the com- plex I is formed with n-σ type lithium bond interaction between C4H4O and LiCH3, complex II is formed with π-s type lithium bond interaction between C4H4O and LiCH3, and complex III is formed with π-s and n-s type lithium bond interactions between C4H4S and LiCH3, respectively. 相似文献
33.
采用射频溅射技术沉积Cu/Sn/Zn金属前驱体叠层结合硫化技术在玻璃衬底上成功制备了Cu2ZnSnS4薄膜。X-射线衍射分析表明,通过优化制备条件可以获得单一黝锡矿结构且具有(221)择优取向的Cu2ZnSnS4薄膜。霍尔效应和紫外可见透过谱测量表明,样品的薄膜电阻、吸收系数和光学带隙分别达到0.073Ω·cm,10^4cm^-1和1.53eV,具有适合作为薄膜太阳电池吸收层应用的可能性。 相似文献
34.
《科学通报(英文版)》2007,(16)
The photoluminescence quenching behaviors of 5D3-7FJ and 5D4-7FJ (J = 0―6) transitions of Tb3 in YBO3:Tb under 130―290 nm excitation were systematically investigated. The results revealed that the quenching concentrations of both 5D3-7FJ and 5D4-7FJ transitions of Tb3 in YBO3:Tb were mainly de-pendent on excitation wavelength. Particularly,the quenching concentrations of 5D4-7FJ transitions of Tb3 under 130―290 nm excitation were correlated with excitation bands of YBO3:Tb. The quenching concentrations of 5D3-7FJ transitions remained at low concentration (2%) under 186―290 nm excitation and then increased gradually with energy of incoming excitation photon when excited at 130―186 nm. This dependence should be involved in their excitation mechanisms and quenching pathway in particular excitation region. 相似文献
35.
36.
设计并实现了以Nexperia PNX1300 Series媒体处理器为核心,集视频、音频、通信、图象和控制为一体的数字多媒体平台,它具有高性能的实时数字信号处理能力,是数字多媒体编解码标准的算法研究与实现的理想平台,实验证明,数字多媒体平台是一个性能卓越、功能强大的实时信号采集与处理系统,完全满足数字多媒体实时处理的需要,它将MPEG-4的视频压缩技术与流媒体技术结合,具有广泛的应用前景。 相似文献
37.
为寻求简便、合理的合成超细粉体的方法,利用NH4HCO3 作沉淀剂,通过考察料液配比、加料速度、升温速度等实验因素,得到了简单的合成超细 Ce Zr O粉末的工艺,并利用比表面积测定仪、激光粒度仪、XRD、Raman等仪器对相关产物进行了表征.结果表明:利用简单工艺合成的超细 Ce Zr O粉末具有中位粒径为0.30μm、比表面积为21.2 m2/g、悬浮性大于30 min、松装密度小于 1 g/cm3等性能,产物具有 CaF2 型的空间结构. 相似文献
38.
E. Flückiger U. Briner B. Clark A. Closse A. Enz P. Gull A. Hofmann R. Markstein L. Tolcsvai H. R. Wagner 《Cellular and molecular life sciences : CMLS》1988,44(5):431-436
Summary The profile of action in animals of CQP 201-403, a novel 8-amino-ergoline, is in most aspects that of a very potent dopaminomimetic, both as a prolactin secretion inhibitor, and at the levels of the CNS and the cardiovascular system. Qualitatively CQP 201-403 differs slightly from bromocriptine and apomorphine in its effects on the CNS (no influence on serotonin metabolism in the rat cortex; induction of masculine mounting behavior in rats) and the cardiovascular system of the dog (reflex tachycardia in response to a blood-pressure fall). In man the new compound proved to be highly active in lowering prolactin serum levels and to be more potent than bromocriptine (Parlodel®).In memory of Dr Annemarie Closse, who died 14 June 1987. 相似文献
39.
40.