甲醇液相氧化羰化合成碳酸二甲酯动力学研究

研究了不同Schiff碱配合CuCl对甲醇液相氧化羰化合碳酸二甲酯反应的影响，得到了Schiff碱与CuCl复合催化体系的动力学方程，通过对实验数据的处理，得到了相关动力学参数，研究结果表明，当催化剂的浓度为0.2mol/L，Schiff碱与CuCl的量满足cSchiff base/cCuCL=2:1的条件，反应温度为120℃，反应压力为2.4MPa,CO与O2的进气摩尔比为2：1时，phen/CuCl复合催化体系的反应速率最快，其动力学方程为－dpCO/dt=0.216p^1.10PCO,活化能为44．31kJ/mol.     

微波辐射下9—芳基—3,3,6,6—四甲基—1，8—二氧代—1，2，3，4，5，6，7，8，9，10—十氢吖啶的合成

对氯苯甲醛（或3，4-二甲氧基苯甲醛），5，5-二甲基-1，3-环己二酮，醋酸铵为原料在无溶济条件下经微波辐射得9-对氯苯基-3，3，6，6-四甲基-1，8-二氧代-1，2，3，4，5，6，7，8，9，10-十氢吖啶，结构通过红外光谱、核磁共振谱，元素分析确定。     

最简点预测动态矩阵控制器的性能分析

定义了线性系统脉冲响应模型的相对误差和模型失配时的最小鲁棒指数，并在此基础上分析了各种拍控制器的性能，指出动态矩阵控制所能达到的性能的极限，为动态矩阵控制设计提供指导。     

Reservoir characteristics and genesis of high-porosity and high-permeability reservoirs in Tarim Basin

Based on detailed studies, this paper proposesthat in the Tarim Basin, hydrocarbon reservoirs widespreadeither in vertical sequences or in plane and high-porosity andhigh-permeability reservoirs are developed all over the basin.However, obvious difference and heterogeneity exist amongdifferent kinds of reservoirs. The lithologic characteristics,reservoir space types and reservoir properties in variousstrata have been probed. The result indicates that althoughthe Paleozoic carbonates have been deeply buried for a longperiod, high-quality reservoirs with the porosity of up to 5%—8% (12% as the maximum) and the permeability of10×10^-3—100×10^-3 μm² (1000×10^-3 μm² as the maximum)can be found in certain areas. These include the area withthe development of reefs and carbonate beaches, the weath-ered-crust buried-hill belts that have undergone thelong-term exposure, weathering and leaching, the area withthe development of dolomitization, and those areas that haveexperienced the resolution of carbonic acid and organic acidgenerated by the maturity of the organic matter. Finally, thegenesis of the high-porosity and high-permeability reservoirsin deep-buried conditions (with the depth more than 3500 m)have been investigated thoroughly.     

鄂尔多斯盆地早奥陶世沉积特征及其演化

鄂尔多斯盆地的早奥陶世沉积可划分为西缘末端变陡的碳酸盐岩缓坡、东缘蒸发-局限台地和南缘镶边碳酸盐岩台地3个沉积区。岩相古地理的发展可划分为3个阶段,即冶理—亮甲山期为稳定的发展阶段,早、晚马家沟期为岩相分异阶段,峰峰期为中奥陶世陆源浊积盆地这一新的发展阶段的前奏。其演化具有东升西降的特点,东部沉积区的沉积相演化为一个向上变浅的沉积序列,而西部为一个向上变深的沉积序列。     

反式2—呋喃硝基乙烯与二甲胺加成中间体结构的MO研究

在LCAO-SCF-MO-AM1水平上研究了反式2-呋喃硝基乙烯同二甲胺亲核加成反应中间体的结构和性质,从理论上证实了该中间体是一个极性两性离子。     

<Emphasis Type="Italic">In situ</Emphasis> generation and detection of methyl radical by voltammetry

The chemistry of free radicals is one of the advanced subjects of fundamental sciences such as biomedicine, environment protection, new energy sources and new material. The detection technique of free radicals is an essential tool for studying free radicals. Methyl radical is one of the representatives of alkyl radicals and the studies on it attract more attention. The current approaches to obtaining methyl radical are based on pulse radiolysis of organic substances that contain the methyl gro…     

TCE的物理化学特性及其生物降解作用

以加拿大一厂址区碳酸盐岩水是中地下受到三氯惭烯（ＴＣＥ）化合物的污染作为实例,对ＴＣＥ的物理化学特性及其降解作用进行论述,指出ＴＣＥ污染物的生物降解作用的存在的,但是不完全,因此,当ＴＣＥ污染物深度明显超标时,仍应考虑采取去除污染措施。     

The controlling factors and distribution prediction of H_2S formation in marine carbonate gas reservoir,China

Generally, there are some anhydrites in carbonate reservoir, as H2S is also familiar in carbonate oil and gas reservoirs. Nowadays, natural gas with high H2S concentration is usually considered as TSR origin, so there is close relationship between H2S and anhydrite. On the contrary, some carbonate rocks with anhydrite do not contain H2S. Recently, researches show that H2S is only a necessary condition of H2S formation. The reservoir porosity, sulfate ion content within formation water, reservoir temperature, oil/gas and water interface, hydrocarbon and some elements of reservoir rock have great controlling effects on the TSR occurrence. TSR deoxidizes hydrocarbon into the acidic gas such as H2S and CO2, and the H2S formation is controlled by TSR occurrence, so the relationship among reaction room, the contact chance of sulfate ion and hydrocarbon, the reservoir temperature has great influence on the TSR reaction. H2S has relatively active chemical quality, so it is still controlled by the content of heavy metal ion. Good conditions of TSR reaction and H2S preservation are the prerequisite of H2S distribution prediction. This paper builds a predictive model based on the characteristic of natural gas reservoir with high H2S-bearing. In the porosity reservoir with anhydrite, the formation water is rich in sulfate and poor in heavy metal ion. Oil and gas fill and accumulate in the gas reservoir with good preservation conditions, and they suffered high temperature later, which indicates the profitable area of natural gas with high H2S-bearing.     

车用合成燃料能源消费和温室气体排放对比分析

为了评价在我国发展以天然气和煤为原料的车用合成燃料所带来的能源和全球变暖影响,使用“从矿井到车轮”的方法对甲醇、二甲醚和费托柴油在资源开采、炼制加工、运输分配及最终使用中的能耗和温室气体排放进行定量计算,并与传统汽油和柴油的相关指标进行对比。计算结果表明,甲醇、二甲醚和费托柴油的全周期石油消耗远低于汽油和柴油,对解决中国石油安全问题有一定作用。在能源消费总量、化石能源消费量和温室气体排放量方面,天然气基燃料优于煤基燃料,但两者均明显劣于汽柴油,对中国未来承担温室气体减排责任构成潜在压力。