NMR study on self-assembled cage complex of hexamethylenetetramine and cucurbit[n]urils

Self-assembled complexes between cage com-pounds cucurbit[n = 5—8]urils and hexamethylenetetramine were studied by using NMR techniques. Experimental results reveal that hexamethylenetetramine can lid cucurbit[5]uril to forming self-assembled capsules in which nothing is encap-sulated yet; the cavity of the cucurbit[7]uril can accommo-date a hexamethylenetetramine molecule to form a self- assembled host-guest inclusion. Moreover, both the cavity interaction of the cucurbit[7]uril with hexamethylenetetra-mine稨Cl and the portal interaction of the dipole carbonyl of the cucurbit[7]uril with hexamethylenetetramine稨Cl lead to form self-assembled capsules in which the hexamethylene-tetramine稨Cl are encapsulated in the hexamethylenetetra-mine稨Cl lidded cucurbit[7]uril. Although the structures of the portal and cavity to cucurbit[5]uril are similar, there is no obvious interaction between decamethylcucurbit[5]uril and hexamethylenetetramine, and also between cucurbit [6]uril or cucurbit[8]uril and hexamethylenetetramine.     

[CrMo_6O_(24)H_6]~(3-)掺杂聚苯胺材料的制备及荧光性质

在盐酸介质中,以(NH4)2S2O8为氧化剂,杂多阴离子[CrMo6O24H6]3-为掺杂剂合成出了聚苯胺掺杂材料,用FT-IR,XRD进行了表征,测定了该材料的电导率、常见溶剂中的溶解度及其荧光性质.该材料的电导率为1.4×10-2S·cm-1,最高溶解度可达到0.60mg·mL-1,在以260nm和332nm为激发波长,可分别在425nm和567nm处得到荧光发射峰。     

半(p,r)-预不变凸函数及其规划的最优性条件

首先在半预不变凸函数和(p,r)-预不变凸函数的基础上,定义了一类新的广义凸函数半(p,r)-预不变凸函数,它既是半预不变凸函数又是(p,r)-预不变凸函数的推广形式,从而是熟知的凸函数和不变凸函数的推广形式.接着,讨论了半(p,r)-预不变凸函数的一些有用性质.最后利用半(p,r)-预不变凸(凹)函数讨论了目标函数和约束函数均不可微的多目标规划问题,从而获得两个最优性条件.     

3-甲基-6-氨基-5-氰基-4-（4-对甲氧基）苯基-1-苯基-1，4-二氢吡喃并[2，3-c]吡唑与牛血清白蛋白相互作用的研究

采用荧光光谱法研究了人体生理pH值条件下,3-甲基-6-氨基-5-氰基-4-(4-对甲氧基)苯基-1-苯基-1,4-二氢吡喃并[2,3-c]吡唑(Ⅰ)与牛血清白蛋白(BSA)分子间的相互结合反应;获得了不同温度下Ⅰ与BSA作用的结合常数K和结合位点数n;并根据Forster非辐射能量转移机理,计算出其与BSA相互作用时给体-受体间距离r为5.01 nm及能量转移效率E为0.280.证实了Ⅰ与BSA的相互结合作用为单一的静态猝灭过程,确定了其与BSA分子间有较强的结合作用,且结合力以疏水作用力为主.     

2-[(2,6-二氯苯基)氨基]苯乙酸钾的合成

以苯胺和氯乙酰氯为起始原料,合成2-[(2,6-二氯苯基)氨基]-苯乙酸钾,并对反应的工艺进行优化,确定了反应条件,总收率为75.8%。关键中间体及最终化合物的结构经核磁共振氢谱及碳谱得到确证。新工艺做法简单,成本低,适于工业生产。     

The equilibrium between diagenetic calcites and dolomites and its impact on reservoir quality in the sandstone reservoir of Kela 2 gas field

Based on the equilibrium theory of chemical reactions between water and rocks,this paper establishes a thermodynamic phase relationship diagram among calcites,dolomites and water solution under the condition of diagenesis based on the thermodynamic database of related minerals and fluids and dolomite's degree of order parameters.It has been discovered that the equilibrium between calcites and dolomites in the diagenetic environment is strongly impacted by temperature and the Ca/Mg ratios in groundwater,and that the dolomite's degree of order in the diagenetic environment is a function of crystallization temperature and time,not controlled by water solution.Hereby,the authors make a further analysis of the close relationship of chemical reaction between carbonate cements and pore water in the sandstone reservoirs of Kala 2 gas field in Kuche sag.It can be seen that there are different impacts on sandstone reservoir quality among the equilibrium system of calcites,dolomites and pore water at different depths of reservoirs.     

From deep basin gas to diagenetic trap—An example from the Yulin Gas Field in the Ordos Basin

In the updip portion of the Yulin Gas Field in the Ordos Basin, there are no any structural, stratigraphic and sedimentary lithologic seals. Using thin-section petrography, ultraviolet fluorescence microscopy, micro-thermometry and Raman microspectrometry, this paper finds out the diagenetic trap and studies the diagenetic history of this field. It was revealed that three phases of diagenesis and hydrocarbon charging happened in late Triassic, late Jurassic and the end of early Cretaceous respectively. In the first two phases, acid geofluid entered the reservoir and caused dissolution and cementation. Although the porosities had been increased, further compaction accompanying re-subsidence resulted in tight sandstone and conglomerates. Till the end of the early Cretaceous, bulk of gas migrated into the tight reservoir. Cementation, however, kept on in the updip portion of this field due to low gas saturation and formed the diagenetic trap. The mechanism for gas accumulation was changed from deep basin gas to diagenetic trap, which offers a sealing condition that can retain gas for much longer time.     

甘谷驿油田长6油层储层成岩作用及其对储层物性的影响

甘谷驿油田长6油层为湖泊三角洲平原分流河道砂体及三角洲前缘水下分流河道、河口坝砂体．砂岩以中细粒长石砂岩为主，主要成岩矿物有绿泥石环边、方解石胶结物、长石和石英加大生长、伊利石、伊一蒙混层、钠长石和高岭石等．在成岩过程中，强烈的压实作用及胶结作用导致原生孔隙丧失殆尽，是储层成为特低渗透率的主要原因；而晚期的溶蚀作用，特别是方解石、浊沸石的溶解，使得储层的孔隙度和渗透率有所改善，这才使得鄂尔多斯盆地长6层发育部分“甜点”储层，成为有利的储集相带．     

低渗透储层成岩储集相及储集空间演化模式

以砂西油田古近系下干柴沟组下段（E3^1）为例,综合应用取心井的岩石铸体薄片、图像分析、扫描电镜、电子探针能谱、阴极发光、粘土矿物X衍射分析、镜质体反射率等实验测试资料,对E3^1储层的成岩作用、成岩演化序列和成岩阶段划分方法进行了研究,分析了低渗透储层成岩作用对储集物性的影响,详细阐述了低渗透储层中各类成岩储集相的特征及其形成机制,并探讨了其储集空间类型及演化模式。研究结果表明,本区储层砂岩较低渗透率的主要成因是成岩期各种自生矿物的充填和胶结作用。根据成岩作用及其特有的储集空间组合,可将E3^1储层划分为4种成岩储集相类型,即不稳定组分中强溶解次生孔隙成岩储集相（A相）、中等胶结中强压实残余粒间孔成岩储集相（B相）、碳酸盐强胶结成岩储集相（C相）和早期硬石膏强胶结成岩储集相（D相）,其中A类储集相的储集性能最好,D类最差,为差储层或非储层。     

浅谈高职院校数字电路课程的改革

随着科学技术的迅猛发展，高职院校的数字电路课程教学内容已经与现实技术严重脱节，并且培养出来的学生已经无法满足企业对应用型人才的需要。因此数学电路课程的改革势在必行。文章分析了目前数字电路课程教学所存在的问题，然后提出了改革的方向和方法，重点提出了要加强实验实训的教学，从而提高学生的实际动手能力，满足企业的需求。