织物紫外线透过率测试仪光源及测量系统的稳定性

织物紫外线透过率测试仪是衡量织物抗紫外线能力的仪器,氘灯作为优选的紫外光源,其辐射强度的稳定密切关系到测量的精度和一致性.测量电路中放大器和模/数转换电路的合理设计是保证测量精度的另一个设计关键.通过反馈及参比技术稳定氘灯辐射强度和系统测量精度的方法提高了仪器的性能,其设计方案已在实际仪器中得到验证.     

Synthesis of a symmetrical tetrasubstituted cucurbit[6]uril and its host-guest inclusion complex with 2,2′-bipyridine

Since the structure of the first cucurbituril, a cyclic oligomer of 6 units of glycoluril linked by 12 methylene bridges was determined by Freeman et al. in 1981[1,2], considerable interest has emerged inspired by this new receptor. The receptor properties have been examined in a variety of ways such as polyrotaxanes, molecular neck-laces, rotaxane dendrimers, cyclo-addition reactions which occur more rapidly inside the cavity, and the treatment of effluent from the dye industry[2—12]. Almost…     

Metabonomics analysis of the urine of rats with Qi deficiency and blood stasis syndrome based on NMR techniques

Metabonomics analysis of the urine of rats with Qi deficiency and blood stasis syndrome has been performed by comparison with those of normal rats based on NMR techniques. The relative contents of formate,creatinine,2-oxoglutarate(2-OG) ,citrate,taurine,trimethylamine-N-oxide(TMAO) ,succinate and hippurate in the urine of the rats with Qi deficiency and blood stasis syndrome have been changed. These results have provided evidence for understanding the mechanism and the therapy of Qi defi-ciency and blood stasis syndrome.     

核磁共振弛豫和辐射阻尼效应的计算机模拟

对核磁共振弛豫过程和辐射阻尼效应进行了理论分析和计算机模拟,以直观明了的方式描述了这些物理过程,并对模拟结果进行了讨论.模拟结果表明:横向弛豫和纵向弛豫过程在辐射阻尼很小时,不管实验参数如何设定,磁化矢量路径始终发生在以平衡态磁化矢量为半径的球内;当受到强辐射阻尼影响时,磁化矢量路径则发生在以平衡态磁化矢量为半径的球面上.     

3种肉桂酸（4—X—（Z）—2—烯—丁基）酯（X＝OH，Cl,I））的合成、表征及理论研究

报导了3种肉桂酸（4－X－（Z）－2烯－丁基）酯（X＝OH,Cl,I)的制备,测定了标题化合物的红外和核磁共振谱,并有HF／4－31g方法优化了3种化合物构型,在此基础上计算机了其红外光谱,再用GIAO从头计算方法计算了3种化合物的NMR谱,其结果与实验值符合较好,显然,IR,NMR的量子化学计算机可为确定化合物的结构提供一种新的工具。     

Cu15-Al85混合粉末机械合金化反应的27Al核磁共振研究

测量了经过不同时间球磨的Cu1 5-Al85混合粉末的2 7Al核磁共振 (NMR)谱 ,通过分析2 7AlNMR谱的特征参量随球磨时间的变化来研究Cu1 5-Al85混合粉末机械合金化反应的微观过程 样品在球磨过程中发生了真正的合金化反应 ;用MA法与用熔融法制备的同成分合金有相同的化学短程序     

A method for estimating the contribution of evaporative vapor from Nam Co to local atmospheric vapor based on stable isotopes of water bodies

During the summer monsoon season,the moisture of precipitation events in southern and central regions of the Tibetan Plateau is mainly moisture from the Indian Ocean transported by the Indian monsoon and terrestrial vapor derived from the surface of the Tibetan Plateau.However,the respective contributions of these two types of moisture are not clear.From June to September,the excess deuterium values of precipitation and river water in the Nam Co basin are higher than those for the southern Tibetan Plateau.This reflects the mixing of evaporation from Nam Co and local atmospheric vapor.On the basis of theory for estimating the contribution of evaporative vapor from surface water bodies to atmospheric vapor and relative stable isotopes in water bodies (precipitation,river water,atmospheric moisture and lake water),this study preliminarily estimates that the average contribution of evaporation from the Lake Nam Co to local atmospheric vapor has varied from 28.4% to 31.1% during the summer monsoon season in recent years.     

油基钻井液侵入对核磁共振测井响应影响的实验研究

油基钻井液可有效降低施工成本，缩短钻井周期，在大斜度定向井、水平井及各种复杂地层钻探施工中应用广泛。然而，油基钻井液侵入会改变井周地层的岩石物理性质，给储层流体识别、测井精细评价带来极大挑战。为了明确油基钻井液侵入对核磁共振测井响应的影响，本文选取新疆准噶尔盆地南缘超深井致密砂砾岩储层岩心，围绕岩石物性、钻井液成分、油水比、流体性质、钻井液侵入时间、温度等六个方面分别开展油基钻井液成分、油基钻井液驱替和油基钻井液渗吸三组岩石物理实验，并分析实验过程中核磁共振T2谱变化特征。结果表明，油基钻井液中的基液组分既能在正向压差作用下侵入井周地层，也可通过浮力和毛管力的作用渗吸进入地层。当地层含水/油时，油基钻井液基液侵入会引起微小孔隙T2谱（＜10ms）横向驰豫时间和谱峰值减小，谱峰逐渐左移；而中孔隙T2谱峰（＞100ms）右移且面积增大；上述T2谱变化速率主要受到地层渗透率、侵入时间和温度影响，钻井液类型、油水比等因素影响有限。     

循环动载下大理岩的力学响应及裂隙扩展规律

为研究大理岩在循环冲击载荷下的动态力学性能,利用分离式霍普金森压杆装置(SHPB)及核磁共振装置(NMR),研究循环动载(1～10 s^-1)冲击下岩石内部的裂隙发展规律.结果表明:岩石在循环动载冲击下,峰值应力随应变率的增大变化很小,但是随着冲击次数增加,存在一个临界应变率或冲击次数,当达到该临界值时,峰值应变快速增大;岩石在最初冲击时,表现出明显的弹性后效,随着冲击次数增加,岩石内部裂纹起裂时间越来越早,且裂纹扩展越来越快,应变幅值增大;通过核磁共振成像发现,随着冲击次数的增加,裂隙集中发育(白色亮点)愈来愈明显,呈条带状分布,并逐渐贯通.从最终破坏形态来看,大理岩在动载下为轴向劈裂破坏,大块较多.