Nano to micro size transition of hydroxyapatite in porcine bone during heat treatment with low heating rates

This work focuses on the changes of raw hydroxyapatite obtained from porcine bones during heat treatment with heating rates of 2.5 and 5.0 °C/min between 600 °C and 1100 °C. High-Resolution transmission electron microscopy (HR-TEM) images showed that raw hydroxyapatite was formed by high-ordered nanometric platelet crystals with a length of around 18 nm and width around 7 nm. High-Resolution scanning electron microscopy (HR-SEM) images evidenced the coalescence phenomena during heating giving. It was found that the growth of the crystals and the transition from nano to a micro-size occurred at around 700 °C. And the changes in the full width at half maximum (FWHM) for the characteristic (002) plane of the X-ray diffraction patterns and the FWHM of the characteristic Raman band at 960 cm-1 for ν1 PO43- exhibited the transition from nano to a micro size, that was confirmed by HR-SEM images and the thermogravimetric (TG) analysis. The porosity of the BIO-HAp changes from intra nanometric to intercrystalline.     

Rh纳米粒子电化学制备及其表面增强拉曼效应

利用电化学手段在氧化铟锡(ITO)导电玻璃表面成功制备了Rh纳米粒子,并发现包裹剂、支持电解质以及电化学参数对产物的形貌及尺寸有着显著影响.通过对上述参数的调控实现了Rh纳米粒子的形貌可控制备,得到了准球形、岛状以及片层状的Rh纳米粒子.此外对岛状Rh纳米粒子在表面增强拉曼光谱中的应用进行了研究.结果表明该种结构具有良好的表面增强拉曼活性.     

Microstructure and properties of nano-TiN modified Ti（C,N）-based cermets fabricated by powder injection molding and die pressing

Powder injection molding （PIM） and die pressing were employed to fabricate nano-TiN modified Ti（C,N）- based cermets. The shrinkage behavior, microstructure, porosity, and mechanical properties of the samples with and without nano-TiN addition fabricated by PIM and die pressing were analyzed. It is demonstrated that for either PIM or die pressing, the porosities are obviously reduced, the mechanical properties are significantly improved after adding nano-TiN, and the hard particles are refined; the rim phase thickness obviously becomes thinner, and the number of dimples in fracture also increases. Compared the samples fabricated by die pressing, it is difficult for PIM to obtain dense Ti（C,N）-based cermets. Due to the too much existence of pores and isolated carbon, the mechanical properties of the sintered samples by PIM are inferior to those of the sintered ones by die pressing.     

纳米颗粒表面修饰对纳米流体粘度的影响

纳米流体的黏度受流体温度、纳米颗粒粒径、纳米颗粒浓度等多方面的影响。在前人的研究中,黏度随流体温度的增加而减小,随纳米颗粒粒径的增加而减小,随纳米颗粒浓度的增加而增大,但黏度随纳米颗粒浓度的增大程度不同。通过总结大量不同情况下纳米流体的黏度数据,分析纳米流体黏度随纳米颗粒浓度的增加与纳米颗粒表面性质的关系。分析结果表明:纳米颗粒的添加增加基础流体的黏度;且亲水型纳米颗粒比疏水型纳米颗粒与水形成的纳米流体的黏度高。通过对纳米颗粒表面性质的修饰,可以控制纳米流体黏度的变化,从而影响流体输送过程中的能耗。     

金纳米颗粒自组装膜的制备及其性能

采用一种简单的两步两相法合成了单分散性十二硫醇包裹金纳米颗粒（DDT AuNPs,直径约为10 nm）,以硅片、玻璃片等为基底,利用浸渍提拉法制备了金纳米颗粒(AuNPs)自组装膜.通过扫描电子显微镜（SEM）、紫外 可见光（UV-vis）光谱等表征手段研究了自组装膜的表面形貌以及表面等离子体共振特征,以一氧化碳（CO）低温氧化做为模型反应研究了其催化性能.研究表明,利用该方法制备的AuNPs自组装薄膜具有表面等离子体共振性能,有望被用于化学和生物传感方面.同时,这种薄膜在催化领域具有潜在的应用前景.     

碳包铁钴合金纳米颗粒的制备及磁性能表征

采用回流法制得前驱体粉体,用此前驱体粉体在流动氮气保护下、750℃下热处理10h制得碳包铁钴合金纳米颗粒.利用SEM、TEM、XRD、Raman和VSM对碳包铁钴合金纳米粒子进行了表征.结果表明:所得碳包铁钴合金纳米粒子分散性较好,包覆结构比较完整,具有典型的核-壳结构,粒径为30～70nm,内核为铁钴合金颗粒,外壳为无定形碳.碳包铁钴合金纳米颗粒在室温下为铁磁性,有望应用于磁诱导的药物传递系统.     

功能性CdS纳米颗粒的制备与性质

以氯化镉和硫化钠为原料,巯基乙酸(CH2SHCOOH)为稳定剂,制备了发射波长在518~600 nm范围内连续可调的水溶性CdS纳米颗粒,分别以紫外-可见吸收光谱、荧光光谱、红外光谱、粒度分析及扫描探针显微镜对所得样品的光谱性质、表面基团、粒度分布及形貌进行表征.结果表明,随着回流时间的延长,其紫外-可见吸收边及荧光发射峰红移;颗粒表面有羧基;样品分散性好,形貌呈球状.     

Optical nonlinearity and ultrafast dynamics of ion exchanged silver nanoparticles embedded in soda-lime silicate glass

Ag nanoparticles embedded in soda-lime silicate glass were fabricated by ion-exchange and subse-quently annealing method. Z-scan technique, femtosecond time-resolved optical Kerr effect （OKE） technique and femtosecond pump-probe experiment were used to investigate the effects of laser wavelength and laser pulse duration as well as annealing temperature on the third-order optical nonlinearity and ultrafast dynamics of the composites. It was found that the third-order susceptibility of Ag nanoparticles composite glass measured by 400 nm pulse source is larger than that measured by 800 nm pulse source due to an enhancement effect of local field near surface plasmon resonance of Ag nanoparticles in silicate glass. The third-order optical nonlinearity measured by ns laser source is about two orders of magnitude larger than that measured from fs pulse. The annealing temperature has an important effect on the third-order optical nonlinearity and ultrafast dynamics of the composites. Third-order nonlinear susceptibility up to 10^-l0 esu and fast relaxation process up to 0.2 ps have been obtained in Ag nanoparticles doped glass.     

液相激光烧蚀合成TiO2纳米颗粒及其XPS研究

采用液相激光烧蚀法制备了二氧化钛纳米颗粒,研究了二氧化钛纳米颗粒的生长与微结构．XRD、TEM、XPS等表征表明：此方法可在室温条件下一步获得金红石型二氧化钛纳米颗粒胶体,颗粒直径约50nm,尺寸分布窄,分散性好,从而显示出良好的应用前景．结合微观表征与激光诱导的瞬态等离子体分析对TiO2纳米颗粒形成机理进行了探讨．     

离子辐照形成空心银纳米颗粒

离子辐照是控制金属纳米颗粒分布和结构的有效方法。将能量为200 keV、剂量为5×10^16ions/cm2的Ag＋注入到非晶SiO2中,形成Ag纳米颗粒层,再用能量为200和500 ke V的Ar＋辐照Ag纳米颗粒。Ar＋辐照后,在部分较大的Ag纳米颗粒中出现空洞,空洞的平均尺寸随着Ar＋辐照剂量的增加而变大。辐照前,Ag纳米颗粒在非晶SiO2中沿纵向呈近似高斯分布;辐照后,投影射程附近的较大的Ag纳米颗粒平均尺寸变大,而投影射程下面的小颗粒逐渐消失。结合Trim程序模拟分析结果可知,Ar＋辐照时的核能量损失和电子能量损失是影响Ag纳米颗粒尺寸分布和结构的重要因素。