幂律度与成矿预测

分形理论的引入极大地促进了现代定量地学的发展。在成矿预测的科研和实践中，人们曾先后建立了多种分形预测模型，并取得较好的效果。作者另辟蹊径，通过引入新的分形变量——幂律度(power—law)，建立地质一分形联合预测模型，在理论上进行了初步探索；并以云南省宁蒗—永胜地区铜矿成矿预测为例，圈定A级找矿靶区1处、C级找矿靶区2处，已知矿点的误判率较单一地质预测模型明显降低，体现了幂律度这一分形变量在成矿预测中的优越性。     

Cryptomelane（KxMn8-xO16）： Natural active octahedral molecular sieve（OMS-2）

The Xiangtan manganese deposit (XTM) used to be considered a supergene oxide manganese ore in South China. We reported a new identification of the naturally outcropping cryptomelane by examining the physical, chemical and structural features of the XTM supergene oxide manganese ore. The MnO2 content was over 90%, K2O more than 3%, and water from 2.2%-3.1% which is similar to one in zeolite. The cell parameters of the cryptomelane were given as a0 = 0.9974 nm, b0 = 0.2863 nm, c0 = 0.9693 nm and β= 91.47°. There was a larger pseduotetragonal tunnel in the natural cryptomelane that was formed by [MnO6] octahedral double chains with aperture of 0.462×0.466 nm2, filled with K cations resulting in some Mn3+ substituting for Mn4+ to balance the negative charges of structure. The finding is important not only for prospecting manganese resources in South China, but also in application of octahedral molecular sieve of natural cryptomelane as that developed in the tetragonal molecular sieve of natural zeolite o     

新型Cu(II)双核配合物的合成、结构表征和量化计算

以二(2-苯并咪唑亚甲基)胺(N3)为配体,合成了一种新型Cu(II)双核配合物作为超氧化物歧化酶(SOD)的模型化合物.采用元素分析、UV和IR光谱进行了表征,应用X射线衍射方法测定了晶体结构,并利用G98W程序在HF/LANL2DZ基组水平上对该双核配合物进行了量子化学计算.晶体结构分析表明,Cu(II)双核配合物的化学式量分子(C42H40N12O17Cl4Cu2)是以4,4′-联吡啶为桥的Cu(II)双核配合物单元,Cu(II)与配位原子形成变形八面体构型,轴向配位氧原子来源于高氯酸根.量化计算所得原子轨道贡献和原子净电荷布居分析结果与晶体结构中的配位情况相符.     

德兴斑岩铜矿成矿流体演化与来源的流体包裹体研究

主要研究了德兴斑岩铜矿床不同期次脉石英及花岗闪长斑岩石英斑晶中流体包覆体的特征，测定了流体包裹体的均一温度和冰点，估算了成矿流体的盐度、密度等参数．结合花岗闪长斑岩与石英脉中石英氢氧同位素数据的讨论分析，对流体的演化过程和来源进行了探讨．研究表明花岗闪长斑岩石英斑晶中的包裹体代表了岩浆流体的特征，石英脉中的包裹体记录了岩浆流体演化成成矿流体的特征。研究证实成矿流体主要由岩浆流体而来，成矿流体演化晚期有大气降水的加入。     

Loess-soil sequences in southern Anhui Province： Magnetostratigraphy and paleoclimatic significance

Two parallel loess-soil sequences from Xuancheng and Fanchang in southern Anhui Provinces are dated using geomagnetic and luminescence methods.The Brunhes/Matuyama(B/M) reversal boundary is recognized within the lower part of the so-calles Vermiculated Red Soil (VRS) in the Xuancheng section while the entire Fanchang sequence is of Brunhes age.This indicated that the most recent VRS in southern China,a stratigraphic marker and an indication of extremely warm-humid conditions,was formed during the middle Pleistocene,chronologically correlative with the S4 and S5 soil units in northern China.Microscopic and sedimentologic in vestigations reveal that eolian deposition started in this region at about 0.85 MaBp,roughly synchronous with the well-known Mid-Pleistocene climate change of global significance.The strengthening of both summer and winter monsoon circulations and the consequent river hydrological changes at that time would have provided favorable conditions for sustained eolian deposition in the middle-lower reaches of the Yangtze River since 0.85 MaBP.     

铜离子在4-甲氧基-2,6-二(3,5-二甲基吡唑)-1,3,5-三嗪吸附型修饰电极上的电化学行为

用循环伏安法和方波伏安法研究了铜离子在4 甲氧基 2,6 二(3,5 二甲基吡唑) 1,3,5 三嗪(简称MBDT)吸附型修饰电极上的电化学行为.通过吸附在玻碳表面的配体与铜离子的配位作用,对Cu(Ⅱ)和Cu(Ⅰ)进行了电分析,结果表明,Cu(Ⅰ)在修饰电极上表现出比Cu(Ⅱ)高得多的灵敏度.     

邻苯二甲酸根桥联铜多聚配合物的谱学性质与成键状况

对邻苯二甲酸根桥联铜多聚配合物{[Cu(phth)(phen)(H_2O)」·H_2O}(Phth表示邻苯二甲酸根二阶阴离子;phen表示1,10-邻菲咯啉)进行了红外光谱和紫外可见光谱研究,探讨了配位中心铜(Ⅱ)离子的成键状况。结果表明,铜与配位原子N、O形成一个畸变的四方锥结构。     

4,4’-二偶氮苯重氮氨基苯与铜的显色反应

在Triton X-100存在下,研究了4,4’-二偶氮苯重氮氨基苯(BABAB)与铜的显色反应.在pH=10.0~11.5的Na284O7-NaOH缓冲溶液中,试剂与铜(Ⅱ)形成2:1型深红色配合物,其表观摩尔吸光系数达1.23×105L·mol-1·cm-1.Cu2+的浓度在0～400μg·L-1范围内符合比耳定律.     

爆堆矿岩块度分布测试方法概述

爆堆矿岩块度分布是评价爆破效果重要的指标之一.准确地测定出爆破后矿岩的块度分布,既是正确评价爆破质量的前提,又是建立爆破块度计算模型和优化爆破参数的基础.关于爆堆矿岩块度分布研究已经历了半个多世纪.本文对于爆堆矿岩块度分布的现有的测试方法,进行了系统的归纳总结,介绍了爆堆矿岩块度分布测试方法的发展历史和研究现状,将有助于该领域的深入研究.     

四-α(2,2,4-三甲基-3-戊氧基)酞菁铜LB膜制备及电子吸收光谱研究

将四-a(2,2,4-三甲基-3-戊氧基)酞菁铜在亲水基片上以Z型成膜方式拉制了多层LB膜。膜崩溃压为60 mN·m-1,分子极限面积为0.33nm2。研究了酞菁铜的成膜条件,表明LB膜形成与水的纯度、铺展剂、铺展量、推膜速度等因素有关。不同层数的酞菁铜LB膜的紫外可见光谱表明,在LB膜中酞菁铜分子之间是以J-聚集形态存在。