2,4-二氯苯基荧光酮分光光度法测定环境水样中微量铜

研究铜(Ⅱ)-2,4-二氯苯基荧光酮(DC IPF)-表面活性剂体系,提出以溴代十六烷基吡啶(CPB)增敏,在pH 5.82的HA c-N aA c缓冲介质中Cu(Ⅱ)与DC IPF反应生成1∶2的络合物,最大吸收波长为602 nm,线性范围为0~0.8 m g/L,检出限为0.04 m g/L摩尔吸光系数为8.98×104L/(m o l.cm).将该体系用于环境水样中微量铜的测定,方法准确可靠,抗干扰效果好且简便易行.     

BFe30-1-1铁白铜熔铸过程中碳含量控制技术研究与实践

BFe30-1-1铁白铜用途重要且特殊,因而质量要求十分严格。铸锭的碳含量控制一直是熔铸生产中的难题。阐述了碳元素对BFe30-1-1铁白铜性能的影响,通过对碳元素来源及熔铸特性的分析研究,在熔铸工艺改进的同时,开发利用熔体精炼净化除杂新技术,有效解决控制铸锭碳含量难题。     

铜带可控气氛连续热处理炉断带问题研究与优化

退火是铜带热处理中的重要手段之一,气垫式退火炉是连续热处理的新技术,其应用不仅提高了带材的表面品质,而且强化了铜板带组织性能的均匀性.在对可控气氛连续热处理退火炉的主要组成部分、运行原理及生产中遇到的问题进行梳理的同时,结合多品种合金带材的退火案例,重点分析了铜带退火过程中容易产生断带的几大因素,并提出了相对应的改进方案,通过实践措施和实际应用,形成了可以借鉴的初步结论.     

我国精炼铜行业现状及发展趋势浅析

综述了近几年我国铜冶炼行业的生产、分布、贸易及供需平衡情况;阐述了国内产能规模在40万t以上的大型精炼铜生产商情况及发展动态;分析了过去10年中国精铜的价格走势及主要影响因素,对未来一段时期内的铜冶炼行业发展及价格趋势进行了初步预判,指出中短期内,我国铜冶炼行业将始终处于供大于求的态势,原料对外依存度提高、环保要求日趋严格、完全成本上涨等将成为制约我国铜冶炼行业发展的主要因素,预计未来一段时期内铜价将继续保持震荡走低的态势.     

硫化铜矿物电子结构的第一性原理研究

基于密度泛函理论的平面波赝势方法,计算黄铜矿、辉铜矿、铜蓝、斑铜矿的电子结构性质,并讨论硫化铜矿物电子结构与其可浮性之间的关系.利用费米能级讨论不同硫化铜矿物参与化学反应的活性位置及其与黄药作用生成不同产物的原因.计算结果表明:黄铜矿禁带宽度为0.99 eV,属于直接带隙p型半导体,而辉铜矿、铜蓝、斑铜矿则为导体.前线轨道计算结果能够很好地解释4种硫化铜矿物氧化性差异.为进一步认清硫化铜矿物可浮性的差异及硫化铜矿物新药剂开发提供理论参考.     

云南普朗超大型斑岩铜矿特征及成矿模型

普朗斑岩铜矿床位于义敦岛弧带南端,是中国目前可以确定的印支期斑岩铜矿床的典型代表.矿床产于由石英闪长玢岩、石英二长斑岩小岩株组成的复式岩体中,通过野外观察和典型地质体的辉钼矿Re-Os年龄、黑云母Ar/Ar年龄和K-Ar年龄测定,确定成矿年龄为(213±3.8)～(216.0±1) Ma,为晚三叠世诺利期,表明普朗斑岩铜矿床的成矿作用在印支期完成.含矿岩体蚀变分带明显,由中心向外发育强硅化带(局部)→钾长石、黑云母化带→石英、绢云母化带→青磐岩化带(局部发育伊利石-碳酸岩化带).工业矿体主要产于石英二长斑岩中的钾长石、黑云母化带和石英、绢云母化带.矿床具有斑岩铜矿中下部细粒状浸染、中上部细网脉状浸染和顶部围岩中产出大脉状矿体的"三层楼"模式.其斑岩体、元素组合及矿化特征与蒙古的欧玉·陶勒盖斑岩铜矿可以对比,资源潜力巨大.     

含铜无取向电工钢中析出相及其析出机理

研究了含铜低碳低硅无取向电工钢中的析出相及其析出机理.由能谱(EDS)及选区电子衍射(SAED)分析可知,铁素体基体上存在的大量弥散分布的等轴状析出相为类B2结构的铜.这些铜析出相的析出机理可以是一般析出、位错析出、台阶机理相间析出和弓出机理相间析出:一般析出在550、650和750℃三个等温温度均可发生;位错析出只发生在较低的等温温度(550℃),此时析出相呈特殊的平行短列状;台阶机理相间析出也可在上述三个等温温度下发生,但650℃等温时最有利于台阶机理相间析出,此时析出相平直列状分布;弓出机理相间析出只发生在较高的等温温度(750℃),析出相弯曲列状分布.     

Characteristics of strontium isotopes and their implications in the Qixing Cave of Guizhou,China

The strontium isotopic compositions (87Sr/86Sr) of samples including soils, bedrock, soil waters, drip waters and their corresponding speleothems in the Qixing Cave (QXC), Guizhou Province, China, were systemically measured and analyzed. The results indicate that there are significant Sr isotopic differences among samples. The mean 87Sr/86Sr ratios in drip water for the samples 1#, 4# and 9# were 0.709568, 0.709139 and 0.708761, respectively, which possibly result from different flow paths, residence times, and other hydrogeological processes in the unsaturated zone overlying QXC. Meanwhile, levels of 40.8%, 57.6% and 72.4% of Sr in drip waters for 1#, 4# and 9#, respectively, were derived from bedrock dissolution, which was calculated by the mixture model of the two end-members (soil and bedrock). There is, however, no positive correlation between the relative proportion from bedrock dissolution (δ13C value is 1.8‰) and drip water δ13CDIC values. The mean drip water δ13CDIC value in 1# is the heaviest (–4.5‰) with the lowest contribution rate of bedrock dissolution, whereas the value in 9# is the lightest (–9.3‰) with the highest contribution rate of bedrock dissolution. The proportion from host rock dissolution in 4# is higher than that in 1# and lower than that in 9#, while its mean drip water δ13CDIC value (–8.6‰) is higher than that of 9# and lower than that for 1#. This suggests that the prior calcite precipitation (PCP) processes in the unsaturated zone overlying the cave are responsible for the δ13CDIC value differences between different drip waters, and not bedrock dissolution. Furthermore, this study also demonstrates that the 87Sr/86Sr ratios of speleothems in the 1# and 4# mainly reflect the variation in the relative proportions from the soil system (soil water) and bedrock dissolution overlying the cave. It is, therefore, feasible to use the strontium isotopic signals of speleothems as an indicator for soil chemical weathering intensity, and consequently as a monsoon proxy in the study area.     

Molybdenum isotopic composition as a tracer for low-medium temperature hydrothermal ore-forming systems: A case study on the Dajiangping pyrite deposit,western Guangdong Province,China

Little is known about the range or controls on the molybdenum isotopic composition of low-medium temperature hydrothermal ore-forming systems. We present molybdenum isotope data from 12 hydrothermal syndepositional silicalite and carbonaceous slate samples from the Dajiangping pyrite deposit in western Guangdong Province, South China. The δ ^97/95 Mo values from Orebody III range from −0.02‰ to 0.29‰, with an average of 0.18‰. In contrast, the composition values from Orebody IV display a larger variation from −0.70‰ to 0.62‰. However, the five samples from the main ore bed all show strong negative values. This indicates that the significant variation in molybdenum isotopic composition supports different hydrothermal ore-forming metallogenesis and a metallogenic environment between the two orebodies. Orebody III is likely to have been deposited from submarine exhalative hydrothermal fluids under a relatively strong reducing environment and Orebody IV may have also been influenced by hydrothermal superimposition in a more oxidized disequilibrium condition. In addition, the δ ^97/95 Mo values of Orebody IV are clearly negative, together with the values increasing stratigraphically upward in the ore beds, suggesting that the metallogenic environment of Orebody IV is different from the open oceanic systems. There might be dynamic fractionation in this restricted environment. Therefore, the molybdenum isotope can be used as an effective tracer for the ore-forming fluid and metallogenic environment.     

二乙酰丙酮铜催化下无溶剂法合成2,5-二溴-3,4-二((辛氧基)甲基)噻吩[2,3-b]并噻吩

以2,5-二溴-3,4-二甲基噻吩[2,3-b]并噻吩和正辛醇为原料,在二乙酰丙酮铜作催化剂和无溶剂条件下,合成了未见文献报道的产物2,5-二溴-3,4-二((辛氧基)甲基)噻吩[2,3-b]并噻吩,探讨了影响反应的各种因素,并找到了较好的合成条件.