负载型丝光沸石催化剂的催化性能研究

运用二元碱氮置换吸附红外光谱法、分子筛孔径分布测定技术、XPS技术,考察了丝光沸石表面酸性与孔结构的相互关系、钯在丝光沸石上分布情况和价态及其与沸石的相互作用。结果表明,随着丝光沸石脱铝程度的增加,表面出现大量不规整晶格,存在较多的次级孔道。强质子酸中心主要分布在它的“外表面”。钯在其表面富集,并与“外表面”上的质子酸中心协同作用,促进了轻质烷烃异构化反应。     

润滑轧制时铜板表面质量的研究

本文研究了润滑剂粘度、轧制压下率和热处理工艺对冷轧铜板表面质量的影响。对于不同的润滑剂粘度和轧制压下率,应用修正的Stribeck图分析了变形区润滑状态及其对板材表面质量的影响。结果表明,当润滑剂粘度和轧制压下率在最佳范围内时,可获得优良的板材表面质量,光亮退火对板材表面质量亦有利。     

4-二甲胺基吡啶催化美欧卡霉素的合成

由麦迪霉素Ａ直接酰化合成美欧卡霉素Ｃ具有工艺简便的特点．但用吡啶、Ｎ,Ｎ二乙基苯胺等普通催化剂,难以获得良好的效果．采用高效酰化催化剂——４二甲胺基吡啶（ＤＭＡＰ）催化直接酰化过程,反应在较低温度下完成,避免高温引起的分子内异构化,结果令人满意     

Alopecia induced in young mice by exposure to excess dietary zinc

Summary Second generation mice were exposed to normal (50 ppm, Group I) or excess (2000 ppm, Group II) zinc in the maternal diet during gestation and lactation, then weaned and continued on the mother's diet until sacrifice at 8 weeks. Tibia zinc reflected dietary intake. Group II had reduced plasma copper, body weight, and hematocrit; the second coat of hair appeared late and was lighter in color than Group I, possibly as an effect of copper and pigmentation development and hair growth.     

在不同水硬度下铜对草鱼、鲢和大鳞泥鳅的急性毒性

实验以草鱼、鲢和大鳞泥鳅的鱼苗为材料,测定了水硬度对铜的急性毒性的影响,水硬度在255、141、37和14mg/L(以 CaCO_3计)时铜对草鱼的48小时 LC_(50)分别是519、354、91和76μg/L,96小时 LC_(50)则分别为460、307、67和39μg/L.在同样的硬度条件下,对鲢的48小时 LC_(50)是452、393、71和40μg/L,96小时 LC_(50)分别为452、296、41和31μg/L.大鲢泥鳅鱼苗在硬度260、137、36和10μg/L(以 CaCO_3计)条件下,铜的48小时 LC_(50)为369、305、1113和67μg/L,而96小时 LC_(50)则分别是226、135、67和18μg/L.铜的急性毒性和水硬度之间的关系可用下列方程来描述:草鱼 ln96小时■_(50)=1.1345+0.9051ln 硬度 r=0.99ln96小时■_(50)=2.2118+0.7220ln 硬度 r=0.97鲢 ln96小时■_(50)=0.4564+1.0207ln 硬度 r=0.97ln96小时■_(50)=1.1371+0.9232ln 硬度 r=0.98大鳞泥鳅ln96小时■_(50)=1.2823+0.7506ln 硬度 r=0.99ln96小时■_(50)=2.8635+0.5563ln 硬度 r=0.99     

Simultaneously catalytic removal of NO<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript> and particulate matter on diesel particulate filter

Diesel engines combine a high fuel economy with high durability and low maintenance costs and are, there-fore, used on a large scale for transportation purposes.However, the environmental pollution by diesel-engine exhausts has become more and more serious in the lastdecade, and currently the regulation of diesel emissions becomes tightened especially with respect to nitrogen ox-ides (NOx) and particulate matters (PM). Since the reduc-tion of both NOx and PM to the admitted level cannot be …     

超稳Y-沸石催化合成乙酰乙酸乙酯缩酮

用脱铝超稳Ｙ－沸石作催化剂合成了乙酰乙酸乙酯与乙二醇缩酮和丙二醇缩酮,其产率可达到８０％和９６％,考察了催化剂组成和反应时间对反应的影响规律,发现产物比反应物更易在催化剂表面吸附,对反应机理作了讨论。     

宋代铜冶业研究

宋代的铜冶业发展成效显著,矿税量激增,产地扩大,新的炼铜法得到推广。由生产力的迅速发展带来的经营方式的不断变革对铜冶业的发展也产生了重要的影响。宋室南渡后,铜冶业走上了衰落的道路。其原因主要在于战乱、国土沦丧、政府对坑冶剥削的加重以及长期胡乱开采造成的环境恶化等。     

纳米ZnO光催化有机磷农药降解的研究

研究纳米氧化锌对三种有机磷农药的降解情况，考查了催化剂及其用量、光照时间、pH值的影响，结果表明纳米氧化锌能使有机磷农药发生降解。实验结果还表明不同形貌的氧化锌在降解有机磷农药时其效果不一样，网状比粒状所需要时间要短，这可能因为网状的粒径比较小，与降解体系接触空间更大。     

Enatioselective[2 2 2] Cycloaddition as A Synthetic Tool

1 Results Transition metal-catalyzed [2 2 2] cycloaddition is one of the most efficient protocols for the construction of six-membered ring system.Our group has comprehensively studied various types of highly enantioselective [2 2 2] cycloaddition for the synthesis of chiral cycloadducts; we already reported an iridium-catalyzed intermolecular [2 2 2] cycloaddition between α,ω-diynes,having various tethers and substituents on the alkyne termini,and monoalkynes,possessing oxygen or/and nitrogen functiona...