测定饲料蛋白质含量的一种新方法

本文介绍一种测定各种饲料蛋白质含量的新方法—蛋白质水解茚三酮法。将标准蛋白和几种饲料样品加3％H_2SO_4,直接加热6小时,通过蛋白质水解产生的氨基酸与茚三酮反应的光吸收值,计算总蛋白量;与未水解的标样及饲料样品的甲醇提取液的茚三酮反应吸收值之差计算去游离氨基酸的纯蛋白质量。本法与凯氏氮素定量法无显著差异,与DAVID L·MARKKS报导的密封水解24小时的效果相同。     

Ferric chloride-catalyzed decarboxylative alkylation of β-keto acids with benzylic alcohols

β-Keto acids are unstable to heat,acids,and bases,and have rarely been employed as carbon nucleophiles for the formation of carbon-carbon bonds.In this context,an efficient decarboxylative alkylation reaction of β-keto acids with benzylic alcohols has been developed,for the first time,through sequential cleavage of carbon-oxygen and carbon-carbon bonds.In the presence of 10 mol% of ferric chloride,a range of β-keto acids smoothly undergo decarboxylative alkylation with benzylic alcohols to give structurally diverse unsymmetric ketones in moderate to excellent yields and with extremely high regioselectivity.Preliminary mechanistic studies indicate that the reaction proceeds through an SN1 alkylation followed by decarboxylation.     

Chemical composition and antioxidant activity of essential oil from Magnolia grandiflora L. seed

The chemical composition and antioxidant activity of Magnolia grandiflora L.seed essential oil were examined.By combining gas chromatography and mass spectrometry (GC-MS),16 types of compounds were identified,including 40.91% oxygen-containing terpene derivatives,19.51% terpenes,13.97% esters,13.05% nitrogenous compounds,and 3.64% acids.Its capability of removing hydroxyl free radical was lower than that of V c,but it was closer to V c with increasing concentration.In cell experiment,all essential oil concentration (6.9,13.8,27.7,55.5,111.0,and 222.0 g/mL) groups increased cell proliferation by 26% or more (26.0%,38.8%,44.8%,40.2%,35.8%,and 30.4%,respectively).In rat experiment,the SD rats group showed an at least 38% rise (38.62%,61.68%,and 62.86%,respectively) in glutathione-peroxisome (GSH-Px)activity,which is more than 24% reduction (29.56%,24.30%,and 36.93%) in malondialdehyde (MDA) content,and no significant difference in SOD activity was found.The results show that the essential oil had strong antioxidant activity,without dose effect within the concentration range.     

石香薷挥发油化学成分研究

本文用气相色谱、气相色谱-质谱-计算机联用仪、红外光谱、核磁共振谱等方法研究了石香薷挥发油的化学成分,在已分析的36个成分中鉴定了其中的31个化合物,占挥发油总量的95.46％。它们是:α—蒎烯、异戊酸异丁酯,α—菲兰烯,对—伞花烃,γ—萜品烯,萜品—4—醇,百里香酚,香荆芥酚,甲基丁子香酚,甲基黑椒酚,α—反式—香柠檬烯,瑟林烯,橙花叔醇,β—红没药烯等.其中百里香酚含量为24.56％,香荆芥酚的含量达43.22％。     

氨基酸螯合铁的研究及应用现状

对氨基酸螯合铁的吸收机制、吸收作用的特点、化学和生物化学制备方法及其在饲料、食品中的应用现状进行了综述,提出了目前氨基酸螯合铁研究及应用中存在的主要问题和今后发展的方向.     

氨基化纳米二氧化钛的热稳定性分析

以基于赖氨酸原位修饰法制备的氨基化纳米二氧化钛进行不同煅烧温度下的热稳定性分析。用 SEM和FT-IR表征手段分析了在不同煅烧温度下氨基化纳米二氧化钛的形貌及结构,用 DTA-TG测量了它们的热失重曲线。结果表明：500℃以下的煅烧不会对材料的形貌结构产生太大的影响,氨基基团仍然存在;并且经过300℃的高温处理后,它的稳定性也有一定程度的提高。     

抗性淀粉的生物学功效及在食品加工中的应用

抗性淀粉是一种具有多种生物学功效的新型膳食纤维,且兼具类似于淀粉的优良加工特征,适合于开发品种多样的高膳食纤维功能性食品。抗性淀粉的研究与应用目前已成为国内外食品行业的热点,介绍了抗性淀粉的分类,及其在糖代谢、脂代谢、体重控制,作为益生元和防治直肠癌方面的生物学功效;分析了抗性淀粉在面包糕点、油炸食品、面条、益生菌类食品加工领域中的应用。     

羧酸类有机锡化合物合成及结构研究概况

羧酸类有机锡化合物的合成规律和结构特点,是目前此类化合物研究的热点问题之一。概述了一烃基锡羧酸酯、二烃基锡羧酸酯和三烃基锡羧酸酯合成及其结构的研究现况。     

“文艺等对象的本质是意识形态论”考辨

"文艺等对象的本质是意识形态论"是国内学界权威、主流的提法,这个命题在逻辑上存在着迷误。首先,马克思没有作出过这样的判断;其次,意识形态是法律、政治、宗教、艺术和哲学的特有属性,但不全是它们的本质属性。这个命题的迷误可能源于苏联学者的迷误和国内学者不恰当的翻译。